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(+)-(2R,3R,6S)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-3-ol

(+)-(2R,3R,6S)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-3-ol

CAS号：1370254-47-9

英文名：(+)-(2R,3R,6S)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-3-ol

分子式：C22H40O3Si

分子量：380.637

合成路线

(-)-(2R,3R,6S,E)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylhept-4-en-3-ol

(-)-(2R,3R,6S,E)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylhept-4-en-3-ol

(+)-(2R,3R,6S)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-3-ol

(+)-(2R,3R,6S)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-3-ol

dimethyl (-)-(R)-4-(benzyloxy)-3-methyl-2-oxobutylphosphonate

dimethyl (-)-(R)-4-(benzyloxy)-3-methyl-2-oxobutylphosphonate

(+)-(2R,3R,6S)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-3-ol

(+)-(2R,3R,6S)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-3-ol

(-)-(2R,6S,E)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylhept-4-en-3-one

(-)-(2R,6S,E)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylhept-4-en-3-one

(+)-(2R,3R,6S)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-3-ol

(+)-(2R,3R,6S)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-3-ol

上游原料

(-)-(2R,3R,6S,E)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylhept-4-en-3-ol dimethyl (-)-(R)-4-(benzyloxy)-3-methyl-2-oxobutylphosphonate (-)-(2R,6S,E)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylhept-4-en-3-one

下游产品

ethyl (-)-(S)-2-{(2S,3S,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}propanoate ethyl (+)-(R)-2-{(2S,3S,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}propanoate ethyl (-)-(4S,7R,8R,E)-9-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,4,8-trimethylnon-2-enoate (+)-(2S,5R,6R)-7-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2,6-dimethylheptanal ethyl (+)-(S)-2-{(2S,3S,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}-2-iodopropanoate (-)-(2S,5R,6R)-7-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-1-ol ethyl (+)-(4S,7R,8R,E)-9-(benzyloxy)-7-hydroxy-2,4,8-trimethylnon-2-enoate