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(+)-(2R,3S,6R)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-3-ol

(+)-(2R,3S,6R)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-3-ol

CAS号：1370254-48-0

英文名：(+)-(2R,3S,6R)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-3-ol

分子式：C22H40O3Si

分子量：380.637

合成路线

(-)-(2R,3S,6R,E)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylhept-4-en-3-ol

(-)-(2R,3S,6R,E)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylhept-4-en-3-ol

(+)-(2R,3S,6R)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-3-ol

(+)-(2R,3S,6R)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-3-ol

dimethyl (-)-(R)-4-(benzyloxy)-3-methyl-2-oxobutylphosphonate

dimethyl (-)-(R)-4-(benzyloxy)-3-methyl-2-oxobutylphosphonate

(+)-(2R,3S,6R)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-3-ol

(+)-(2R,3S,6R)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-3-ol

(+)-(2R,6R,E)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylhept-4-en-3-one

(+)-(2R,6R,E)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylhept-4-en-3-one

(+)-(2R,3S,6R)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-3-ol

(+)-(2R,3S,6R)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-3-ol

上游原料

(-)-(2R,3S,6R,E)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylhept-4-en-3-ol dimethyl (-)-(R)-4-(benzyloxy)-3-methyl-2-oxobutylphosphonate (+)-(2R,6R,E)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylhept-4-en-3-one

下游产品

(2R,5S,6R)-7-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2,6-dimethylheptanal ethyl (-)-(R)-2-{(2R,3R,6S)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}-2-iodopropanoate ethyl (-)-(4R,7S,8R,E)-9-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,4,8-trimethylnon-2-enoate ethyl (-)-(4R,7S,8R,E)-9-(benzyloxy)-7-hydroxy-2,4,8-trimethylnon-2-enoate (+)-(2R,5S,6R)-7-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-1-ol ethyl (+)-(R)-2-{(2R,3R,6S)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}propanoate ethyl (-)-(S)-2-{(2R,3R,6S)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}propanoate