百科

(6aR,8S,9S,9aR)-9-(benzyloxy)-8-(((2R,3R,4S,5S)-3,4-bis(benzyloxy)-5-(pent-4-en-1-yloxy)tetrahydrofuran-2-yl)methoxy)-2,2,4,4-tetraisopropyltetrahydro-6H-furo[3,2-f][1,3,5,2,4]trioxadisilocine

CAS号：1431370-78-3

英文名：(6aR,8S,9S,9aR)-9-(benzyloxy)-8-(((2R,3R,4S,5S)-3,4-bis(benzyloxy)-5-(pent-4-en-1-yloxy)tetrahydrofuran-2-yl)methoxy)-2,2,4,4-tetraisopropyltetrahydro-6H-furo[3,2-f][1,3,5,2,4]trioxadisilocine

分子式：C48H70O10Si2

分子量：863.234

合成路线

1431370-34-1

3,5-di-O-benzoyl-β-D-arabinofuranoside prop-2-ynyl-1,2-orthobenzoate

1431370-78-3

(6aR,8S,9S,9aR)-9-(benzyloxy)-8-(((2R,3R,4S,5S)-3,4-bis(benzyloxy)-5-(pent-4-en-1-yloxy)tetrahydrofuran-2-yl)methoxy)-2,2,4,4-tetraisopropyltetrahydro-6H-furo[3,2-f][1,3,5,2,4]trioxadisilocine

1431370-75-0

(2R,3S,4S,5S)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-5-(pent-4-en-1-yloxy)tetrahydrofuran-3,4-diol

1431370-78-3

(6aR,8S,9S,9aR)-9-(benzyloxy)-8-(((2R,3R,4S,5S)-3,4-bis(benzyloxy)-5-(pent-4-en-1-yloxy)tetrahydrofuran-2-yl)methoxy)-2,2,4,4-tetraisopropyltetrahydro-6H-furo[3,2-f][1,3,5,2,4]trioxadisilocine

1431370-60-3

pent-4-enyl 2,3-di-O-benzyl-5-O-(2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)-α-D-arabinofuranoside

1431370-78-3

(6aR,8S,9S,9aR)-9-(benzyloxy)-8-(((2R,3R,4S,5S)-3,4-bis(benzyloxy)-5-(pent-4-en-1-yloxy)tetrahydrofuran-2-yl)methoxy)-2,2,4,4-tetraisopropyltetrahydro-6H-furo[3,2-f][1,3,5,2,4]trioxadisilocine

1431370-61-4

pent-4-enyl 2,3-di-O-benzyl-5-O-(α-D-arabinofuranosyl)-α-D-arabinofuranoside

1431370-78-3

(6aR,8S,9S,9aR)-9-(benzyloxy)-8-(((2R,3R,4S,5S)-3,4-bis(benzyloxy)-5-(pent-4-en-1-yloxy)tetrahydrofuran-2-yl)methoxy)-2,2,4,4-tetraisopropyltetrahydro-6H-furo[3,2-f][1,3,5,2,4]trioxadisilocine

131064-98-7

1431370-78-3

(6aR,8S,9S,9aR)-9-(benzyloxy)-8-(((2R,3R,4S,5S)-3,4-bis(benzyloxy)-5-(pent-4-en-1-yloxy)tetrahydrofuran-2-yl)methoxy)-2,2,4,4-tetraisopropyltetrahydro-6H-furo[3,2-f][1,3,5,2,4]trioxadisilocine

120964-98-9

methyl 2,3,5-tri-O-benzoyl-αβ-D-xylbofuranoside

1431370-78-3

(6aR,8S,9S,9aR)-9-(benzyloxy)-8-(((2R,3R,4S,5S)-3,4-bis(benzyloxy)-5-(pent-4-en-1-yloxy)tetrahydrofuran-2-yl)methoxy)-2,2,4,4-tetraisopropyltetrahydro-6H-furo[3,2-f][1,3,5,2,4]trioxadisilocine

上游原料

methyl 2,3,5-tri-O-benzoyl-αβ-D-xylbofuranoside 3,5-di-O-benzoyl-β-D-arabinofuranoside prop-2-ynyl-1,2-orthobenzoate pent-4-enyl 2,3-di-O-benzyl-5-O-(α-D-arabinofuranosyl)-α-D-arabinofuranoside pent-4-enyl 2,3-di-O-benzyl-5-O-(2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)-α-D-arabinofuranoside (2R,3S,4S,5S)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-5-(pent-4-en-1-yloxy)tetrahydrofuran-3,4-diol

下游产品

pent-4-enyl 2,3-di-O-benzyl-5-O-(2-O-benzyl-α-D-arabinofuranosyl)-α-D-arabinofuranoside