百科

(1R,3R,4S,9R)-3'-[3,4-dihydroxy-5,8-dimethoxy-9-methyl-1,2,3,4-tetrahydro-1,4-(epoxymethano)naphthalen-6-yl]-3 -methoxy-4 ,5 ,6 ,7 -tetrahydro-2 -benzofuran-1 (3H)-one

(1R,3R,4S,9R)-3'-[3,4-dihydroxy-5,8-dimethoxy-9-methyl-1,2,3,4-tetrahydro-1,4-(epoxymethano)naphthalen-6-yl]-3 -methoxy-4 ,5 ,6 ,7 -tetrahydro-2 -benzofuran-1 (3H)-one

CAS号：1431633-18-9

英文名：(1R,3R,4S,9R)-3'-[3,4-dihydroxy-5,8-dimethoxy-9-methyl-1,2,3,4-tetrahydro-1,4-(epoxymethano)naphthalen-6-yl]-3 -methoxy-4 ,5 ,6 ,7 -tetrahydro-2 -benzofuran-1 (3H)-one

分子式：C23H28O8

分子量：432.464

合成路线

1-[(3aR,9bS)-8-bromo-6,9-dimethoxy-2,2-dimethyl-4,5-dihydronaphtho[1,2-d][1,3]dioxol-9b(3aH)-yl]ethanone

1-[(3aR,9bS)-8-bromo-6,9-dimethoxy-2,2-dimethyl-4,5-dihydronaphtho[1,2-d][1,3]dioxol-9b(3aH)-yl]ethanone

(1R,3R,4S,9R)-3'-[3,4-dihydroxy-5,8-dimethoxy-9-methyl-1,2,3,4-tetrahydro-1,4-(epoxymethano)naphthalen-6-yl]-3 -methoxy-4 ,5 ,6 ,7 -tetrahydro-2 -benzofuran-1 (3H)-one

(1R,3R,4S,9R)-3'-[3,4-dihydroxy-5,8-dimethoxy-9-methyl-1,2,3,4-tetrahydro-1,4-(epoxymethano)naphthalen-6-yl]-3 -methoxy-4 ,5 ,6 ,7 -tetrahydro-2 -benzofuran-1 (3H)-one

1-(7-bromo-5,8-dimethoxy-1,4-dihydronaphthalen-1-yl)ethanone

1-(7-bromo-5,8-dimethoxy-1,4-dihydronaphthalen-1-yl)ethanone

(1R,3R,4S,9R)-3'-[3,4-dihydroxy-5,8-dimethoxy-9-methyl-1,2,3,4-tetrahydro-1,4-(epoxymethano)naphthalen-6-yl]-3 -methoxy-4 ,5 ,6 ,7 -tetrahydro-2 -benzofuran-1 (3H)-one

(1R,3R,4S,9R)-3'-[3,4-dihydroxy-5,8-dimethoxy-9-methyl-1,2,3,4-tetrahydro-1,4-(epoxymethano)naphthalen-6-yl]-3 -methoxy-4 ,5 ,6 ,7 -tetrahydro-2 -benzofuran-1 (3H)-one

1'-[(1S,2R)-7-bromo-1,2-dihydroxy-5,8-dimethoxy-1,2,3,4-tetrahydronaphthalen-1-yl]ethanone

1'-[(1S,2R)-7-bromo-1,2-dihydroxy-5,8-dimethoxy-1,2,3,4-tetrahydronaphthalen-1-yl]ethanone

(1R,3R,4S,9R)-3'-[3,4-dihydroxy-5,8-dimethoxy-9-methyl-1,2,3,4-tetrahydro-1,4-(epoxymethano)naphthalen-6-yl]-3 -methoxy-4 ,5 ,6 ,7 -tetrahydro-2 -benzofuran-1 (3H)-one

(1R,3R,4S,9R)-3'-[3,4-dihydroxy-5,8-dimethoxy-9-methyl-1,2,3,4-tetrahydro-1,4-(epoxymethano)naphthalen-6-yl]-3 -methoxy-4 ,5 ,6 ,7 -tetrahydro-2 -benzofuran-1 (3H)-one

上游原料

1'-[(1S,2R)-7-bromo-1,2-dihydroxy-5,8-dimethoxy-1,2,3,4-tetrahydronaphthalen-1-yl]ethanone 1-[(3aR,9bS)-8-bromo-6,9-dimethoxy-2,2-dimethyl-4,5-dihydronaphtho[1,2-d][1,3]dioxol-9b(3aH)-yl]ethanone 1-(7-bromo-5,8-dimethoxy-1,4-dihydronaphthalen-1-yl)ethanone

下游产品

1,6,11-trihydroxy-7,8,9,10-tetrahydrotetracene-5,12-dione (1R,3R,4S,13R)-4,5,12-trihydroxy-13-methyl-6,11-dioxo-1,2,3,4,6,7,8,9,10,11-decahydro-1,4-(epoxymethano)tetracen-3-yl acetate