百科

(1R,3R,4R,9R)-6-(1-acetoxy-3-oxo-1,3,4,5,6,7-hexahydroisobenzofuran-1-yl)-4-hydroxy-5,8-dimethoxy-9-methyl-1,2,3,4-tetrahydro-1,4-(epoxymethano)naphthalen-3-yl acetate

(1R,3R,4R,9R)-6-(1-acetoxy-3-oxo-1,3,4,5,6,7-hexahydroisobenzofuran-1-yl)-4-hydroxy-5,8-dimethoxy-9-methyl-1,2,3,4-tetrahydro-1,4-(epoxymethano)naphthalen-3-yl acetate

CAS号：1431633-22-5

英文名：(1R,3R,4R,9R)-6-(1-acetoxy-3-oxo-1,3,4,5,6,7-hexahydroisobenzofuran-1-yl)-4-hydroxy-5,8-dimethoxy-9-methyl-1,2,3,4-tetrahydro-1,4-(epoxymethano)naphthalen-3-yl acetate

分子式：C26H30O10

分子量：502.51

合成路线

1-[(3aR,9bS)-8-bromo-6,9-dimethoxy-2,2-dimethyl-4,5-dihydronaphtho[1,2-d][1,3]dioxol-9b(3aH)-yl]ethanone

1-[(3aR,9bS)-8-bromo-6,9-dimethoxy-2,2-dimethyl-4,5-dihydronaphtho[1,2-d][1,3]dioxol-9b(3aH)-yl]ethanone

(1R,3R,4R,9R)-6-(1-acetoxy-3-oxo-1,3,4,5,6,7-hexahydroisobenzofuran-1-yl)-4-hydroxy-5,8-dimethoxy-9-methyl-1,2,3,4-tetrahydro-1,4-(epoxymethano)naphthalen-3-yl acetate

(1R,3R,4R,9R)-6-(1-acetoxy-3-oxo-1,3,4,5,6,7-hexahydroisobenzofuran-1-yl)-4-hydroxy-5,8-dimethoxy-9-methyl-1,2,3,4-tetrahydro-1,4-(epoxymethano)naphthalen-3-yl acetate

1-(7-bromo-5,8-dimethoxy-1,4-dihydronaphthalen-1-yl)ethanone

1-(7-bromo-5,8-dimethoxy-1,4-dihydronaphthalen-1-yl)ethanone

(1R,3R,4R,9R)-6-(1-acetoxy-3-oxo-1,3,4,5,6,7-hexahydroisobenzofuran-1-yl)-4-hydroxy-5,8-dimethoxy-9-methyl-1,2,3,4-tetrahydro-1,4-(epoxymethano)naphthalen-3-yl acetate

(1R,3R,4R,9R)-6-(1-acetoxy-3-oxo-1,3,4,5,6,7-hexahydroisobenzofuran-1-yl)-4-hydroxy-5,8-dimethoxy-9-methyl-1,2,3,4-tetrahydro-1,4-(epoxymethano)naphthalen-3-yl acetate

1'-[(1S,2R)-7-bromo-1,2-dihydroxy-5,8-dimethoxy-1,2,3,4-tetrahydronaphthalen-1-yl]ethanone

1'-[(1S,2R)-7-bromo-1,2-dihydroxy-5,8-dimethoxy-1,2,3,4-tetrahydronaphthalen-1-yl]ethanone

(1R,3R,4R,9R)-6-(1-acetoxy-3-oxo-1,3,4,5,6,7-hexahydroisobenzofuran-1-yl)-4-hydroxy-5,8-dimethoxy-9-methyl-1,2,3,4-tetrahydro-1,4-(epoxymethano)naphthalen-3-yl acetate

(1R,3R,4R,9R)-6-(1-acetoxy-3-oxo-1,3,4,5,6,7-hexahydroisobenzofuran-1-yl)-4-hydroxy-5,8-dimethoxy-9-methyl-1,2,3,4-tetrahydro-1,4-(epoxymethano)naphthalen-3-yl acetate

上游原料

1'-[(1S,2R)-7-bromo-1,2-dihydroxy-5,8-dimethoxy-1,2,3,4-tetrahydronaphthalen-1-yl]ethanone 1-[(3aR,9bS)-8-bromo-6,9-dimethoxy-2,2-dimethyl-4,5-dihydronaphtho[1,2-d][1,3]dioxol-9b(3aH)-yl]ethanone 1-(7-bromo-5,8-dimethoxy-1,4-dihydronaphthalen-1-yl)ethanone

下游产品

(1R,3R,4S,13R)-4,5,12-trihydroxy-13-methyl-6,11-dioxo-1,2,3,4,6,7,8,9,10,11-decahydro-1,4-(epoxymethano)tetracen-3-yl acetate