百科

(E)-ethyl 4-((1R,5S,7R)-1-((R)-1-(tert-butyldiphenylsilyloxy)propan-2-yl)-6-oxaspiro[4.5]decan-7-yl)-2-methylbut-2-enoate

(E)-ethyl 4-((1R,5S,7R)-1-((R)-1-(tert-butyldiphenylsilyloxy)propan-2-yl)-6-oxaspiro[4.5]decan-7-yl)-2-methylbut-2-enoate

CAS号：1437785-12-0

英文名：(E)-ethyl 4-((1R,5S,7R)-1-((R)-1-(tert-butyldiphenylsilyloxy)propan-2-yl)-6-oxaspiro[4.5]decan-7-yl)-2-methylbut-2-enoate

分子式：C35H50O4Si

分子量：562.855

合成路线

(+)-(R)-tert-butyl((2-methylbut-3-yn-1-yl)oxy)diphenylsilane

(+)-(R)-tert-butyl((2-methylbut-3-yn-1-yl)oxy)diphenylsilane

(E)-ethyl 4-((1R,5S,7R)-1-((R)-1-(tert-butyldiphenylsilyloxy)propan-2-yl)-6-oxaspiro[4.5]decan-7-yl)-2-methylbut-2-enoate

(E)-ethyl 4-((1R,5S,7R)-1-((R)-1-(tert-butyldiphenylsilyloxy)propan-2-yl)-6-oxaspiro[4.5]decan-7-yl)-2-methylbut-2-enoate

(1R,2R)-2-((R)-1-(tert-butyldiphenylsilyloxy)propan-2-yl)-1-(furan-2-yl)-cyclopentanol

(1R,2R)-2-((R)-1-(tert-butyldiphenylsilyloxy)propan-2-yl)-1-(furan-2-yl)-cyclopentanol

(E)-ethyl 4-((1R,5S,7R)-1-((R)-1-(tert-butyldiphenylsilyloxy)propan-2-yl)-6-oxaspiro[4.5]decan-7-yl)-2-methylbut-2-enoate

(E)-ethyl 4-((1R,5S,7R)-1-((R)-1-(tert-butyldiphenylsilyloxy)propan-2-yl)-6-oxaspiro[4.5]decan-7-yl)-2-methylbut-2-enoate

(1R,5R,7S)-7-allyl-1-((R)-1-(tert-butyldiphenylsilyloxy)propan-2-yl)-6-oxaspiro[4.5]dec-8-en-10-one

(1R,5R,7S)-7-allyl-1-((R)-1-(tert-butyldiphenylsilyloxy)propan-2-yl)-6-oxaspiro[4.5]dec-8-en-10-one

(E)-ethyl 4-((1R,5S,7R)-1-((R)-1-(tert-butyldiphenylsilyloxy)propan-2-yl)-6-oxaspiro[4.5]decan-7-yl)-2-methylbut-2-enoate

(E)-ethyl 4-((1R,5S,7R)-1-((R)-1-(tert-butyldiphenylsilyloxy)propan-2-yl)-6-oxaspiro[4.5]decan-7-yl)-2-methylbut-2-enoate

(1R,5R,7R)-7-allyl-1-((R)-1-(tert-butyldiphenylsilyloxy)propan-2-yl)-6-oxaspiro[4.5]decan-10-one

(1R,5R,7R)-7-allyl-1-((R)-1-(tert-butyldiphenylsilyloxy)propan-2-yl)-6-oxaspiro[4.5]decan-10-one

(E)-ethyl 4-((1R,5S,7R)-1-((R)-1-(tert-butyldiphenylsilyloxy)propan-2-yl)-6-oxaspiro[4.5]decan-7-yl)-2-methylbut-2-enoate

(E)-ethyl 4-((1R,5S,7R)-1-((R)-1-(tert-butyldiphenylsilyloxy)propan-2-yl)-6-oxaspiro[4.5]decan-7-yl)-2-methylbut-2-enoate

(R)-2-(1-(tert-butyldiphenylsilyloxy)propan-2-yl)cyclopent-2-enone

(R)-2-(1-(tert-butyldiphenylsilyloxy)propan-2-yl)cyclopent-2-enone

(E)-ethyl 4-((1R,5S,7R)-1-((R)-1-(tert-butyldiphenylsilyloxy)propan-2-yl)-6-oxaspiro[4.5]decan-7-yl)-2-methylbut-2-enoate

(E)-ethyl 4-((1R,5S,7R)-1-((R)-1-(tert-butyldiphenylsilyloxy)propan-2-yl)-6-oxaspiro[4.5]decan-7-yl)-2-methylbut-2-enoate

(R)-2-((R)-1-(tert-butyldiphenylsilyloxy)propan-2-yl)cyclopentanone

(R)-2-((R)-1-(tert-butyldiphenylsilyloxy)propan-2-yl)cyclopentanone

(E)-ethyl 4-((1R,5S,7R)-1-((R)-1-(tert-butyldiphenylsilyloxy)propan-2-yl)-6-oxaspiro[4.5]decan-7-yl)-2-methylbut-2-enoate

(E)-ethyl 4-((1R,5S,7R)-1-((R)-1-(tert-butyldiphenylsilyloxy)propan-2-yl)-6-oxaspiro[4.5]decan-7-yl)-2-methylbut-2-enoate

上游原料

(1R,2R)-2-((R)-1-(tert-butyldiphenylsilyloxy)propan-2-yl)-1-(furan-2-yl)-cyclopentanol (+)-(R)-tert-butyl((2-methylbut-3-yn-1-yl)oxy)diphenylsilane (1R,5R,7S)-7-allyl-1-((R)-1-(tert-butyldiphenylsilyloxy)propan-2-yl)-6-oxaspiro[4.5]dec-8-en-10-one (R)-2-(1-(tert-butyldiphenylsilyloxy)propan-2-yl)cyclopent-2-enone (1R,5R,7R)-7-allyl-1-((R)-1-(tert-butyldiphenylsilyloxy)propan-2-yl)-6-oxaspiro[4.5]decan-10-one (R)-2-((R)-1-(tert-butyldiphenylsilyloxy)propan-2-yl)cyclopentanone

下游产品

ethyl (2E)-4-[(1R,5S,7R)-1-[(2S)-but-3-en-2-yl]-6-oxaspiro[4.5]decan-7-yl]-2-methylbut-2-enoate ethyl (2E)-4-[(1R,5S,7R)-1-[(2R)-1-hydroxypropan-2-yl]-6-oxaspiro[4.5]decan-7-yl]-2-methylbut-2-enoate