百科

methyl 4-((2R,3R)-3-((E)-((1S,2R,5S)-2-((Z)-oct-2-en-1-yl)-4-oxo-6-oxabicyclo[3.1.0]hexan-3-ylidene)methyl)oxiran-2-yl)butanoate

methyl 4-((2R,3R)-3-((E)-((1S,2R,5S)-2-((Z)-oct-2-en-1-yl)-4-oxo-6-oxabicyclo[3.1.0]hexan-3-ylidene)methyl)oxiran-2-yl)butanoate

CAS号：1439373-82-6

英文名：methyl 4-((2R,3R)-3-((E)-((1S,2R,5S)-2-((Z)-oct-2-en-1-yl)-4-oxo-6-oxabicyclo[3.1.0]hexan-3-ylidene)methyl)oxiran-2-yl)butanoate

分子式：C21H30O5

分子量：362.46

合成路线

(R,Z)-4-(non-3-en-1-yl)oxetan-2-one

(R,Z)-4-(non-3-en-1-yl)oxetan-2-one

methyl 4-((2R,3R)-3-((E)-((1S,2R,5S)-2-((Z)-oct-2-en-1-yl)-4-oxo-6-oxabicyclo[3.1.0]hexan-3-ylidene)methyl)oxiran-2-yl)butanoate

methyl 4-((2R,3R)-3-((E)-((1S,2R,5S)-2-((Z)-oct-2-en-1-yl)-4-oxo-6-oxabicyclo[3.1.0]hexan-3-ylidene)methyl)oxiran-2-yl)butanoate

(R,Z)-methyl 5-hydroxy-3-oxotetradec-8-enoate

(R,Z)-methyl 5-hydroxy-3-oxotetradec-8-enoate

methyl 4-((2R,3R)-3-((E)-((1S,2R,5S)-2-((Z)-oct-2-en-1-yl)-4-oxo-6-oxabicyclo[3.1.0]hexan-3-ylidene)methyl)oxiran-2-yl)butanoate

methyl 4-((2R,3R)-3-((E)-((1S,2R,5S)-2-((Z)-oct-2-en-1-yl)-4-oxo-6-oxabicyclo[3.1.0]hexan-3-ylidene)methyl)oxiran-2-yl)butanoate

(R,Z)-methyl 2-diazo-5-hydroxy-3-oxotetradec-8-enoate

(R,Z)-methyl 2-diazo-5-hydroxy-3-oxotetradec-8-enoate

methyl 4-((2R,3R)-3-((E)-((1S,2R,5S)-2-((Z)-oct-2-en-1-yl)-4-oxo-6-oxabicyclo[3.1.0]hexan-3-ylidene)methyl)oxiran-2-yl)butanoate

methyl 4-((2R,3R)-3-((E)-((1S,2R,5S)-2-((Z)-oct-2-en-1-yl)-4-oxo-6-oxabicyclo[3.1.0]hexan-3-ylidene)methyl)oxiran-2-yl)butanoate

(R.Z)-methyl 2-diazo-3-oxo-5-((triethylsilyl)oxyl)tetradec-8-enoate

(R.Z)-methyl 2-diazo-3-oxo-5-((triethylsilyl)oxyl)tetradec-8-enoate

methyl 4-((2R,3R)-3-((E)-((1S,2R,5S)-2-((Z)-oct-2-en-1-yl)-4-oxo-6-oxabicyclo[3.1.0]hexan-3-ylidene)methyl)oxiran-2-yl)butanoate

methyl 4-((2R,3R)-3-((E)-((1S,2R,5S)-2-((Z)-oct-2-en-1-yl)-4-oxo-6-oxabicyclo[3.1.0]hexan-3-ylidene)methyl)oxiran-2-yl)butanoate

(1R,2R,3S)-methyl 2-((Z)-oct-2-en-1-yl)-5-oxo-3-((triethylsilyl)oxy)cyclopentanecarboxylate

(1R,2R,3S)-methyl 2-((Z)-oct-2-en-1-yl)-5-oxo-3-((triethylsilyl)oxy)cyclopentanecarboxylate

methyl 4-((2R,3R)-3-((E)-((1S,2R,5S)-2-((Z)-oct-2-en-1-yl)-4-oxo-6-oxabicyclo[3.1.0]hexan-3-ylidene)methyl)oxiran-2-yl)butanoate

methyl 4-((2R,3R)-3-((E)-((1S,2R,5S)-2-((Z)-oct-2-en-1-yl)-4-oxo-6-oxabicyclo[3.1.0]hexan-3-ylidene)methyl)oxiran-2-yl)butanoate

上游原料

(R,Z)-methyl 2-diazo-5-hydroxy-3-oxotetradec-8-enoate (R.Z)-methyl 2-diazo-3-oxo-5-((triethylsilyl)oxyl)tetradec-8-enoate (1R,2R,3S)-methyl 2-((Z)-oct-2-en-1-yl)-5-oxo-3-((triethylsilyl)oxy)cyclopentanecarboxylate (R,Z)-4-(non-3-en-1-yl)oxetan-2-one (R,Z)-methyl 5-hydroxy-3-oxotetradec-8-enoate

下游产品

methyl 4-((2R,3R)-3-((E)-((2R,3R)-3-hydroxy-2-((Z)-oct-2-en-1-yl)-5-oxocyclopentylidene)methyl)oxiran-2-yl)butanoate 4-((2R,3R)-3-((E)-((1S,2R,5S)-2-((Z)-oct-2-en-1-yl)-4-oxo-6-oxabicyclo[3.1,0]hexan-3-ylidene)methyl)oxiran-2-yl)butanoic acid