百科

(3R,4R,E)-6-iodo-4-methylhex-5-en-3-yl (2R,3S,4R,5R,6S,8R)-3-((tert-butyldimethylsilyl)oxy)-9-((tert-butyldiphenylsilyl)oxy)-5-((4-methoxybenzyl)oxy)-2,4,6,8-tetramethylnonanoate

CAS号：1443051-52-2

英文名：(3R,4R,E)-6-iodo-4-methylhex-5-en-3-yl (2R,3S,4R,5R,6S,8R)-3-((tert-butyldimethylsilyl)oxy)-9-((tert-butyldiphenylsilyl)oxy)-5-((4-methoxybenzyl)oxy)-2,4,6,8-tetramethylnonanoate

分子式：C50H77IO6Si2

分子量：957.218

合成路线

1443051-53-3

(2R,3S,4R,5R,6S,8R)-3-((tert-butyldimethylsilyl)oxy)-9-((tert-butyldiphenylsilyl)oxy)-5-((4-methoxybenzyl)oxy)-2,4,6,8-tetramethylnonanoic acid

216493-79-7

(E)-(3R,4R)-6-iodo-4-methyl-5-hexen-3-ol

1443051-52-2

(3R,4R,E)-6-iodo-4-methylhex-5-en-3-yl (2R,3S,4R,5R,6S,8R)-3-((tert-butyldimethylsilyl)oxy)-9-((tert-butyldiphenylsilyl)oxy)-5-((4-methoxybenzyl)oxy)-2,4,6,8-tetramethylnonanoate

1443051-56-6

(2S,3R,4S,6R)-7-((tert-butyldiphenylsilyl)oxy)-3-((4-methoxybenzyl)oxy)-2,4,6-trimethylheptan-1-ol

1443051-52-2

(3R,4R,E)-6-iodo-4-methylhex-5-en-3-yl (2R,3S,4R,5R,6S,8R)-3-((tert-butyldimethylsilyl)oxy)-9-((tert-butyldiphenylsilyl)oxy)-5-((4-methoxybenzyl)oxy)-2,4,6,8-tetramethylnonanoate

1443051-57-7

(2R,3S,4S,5R,6S,8R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-9-((tert-butyldiphenylsilyl)oxy)-3-hydroxy-5-((4-methoxybenzyl)oxy)-2,4,6,8-tetramethylnonan-1-one

1443051-52-2

(3R,4R,E)-6-iodo-4-methylhex-5-en-3-yl (2R,3S,4R,5R,6S,8R)-3-((tert-butyldimethylsilyl)oxy)-9-((tert-butyldiphenylsilyl)oxy)-5-((4-methoxybenzyl)oxy)-2,4,6,8-tetramethylnonanoate

1443051-58-8

(2R,3S,4R,5R,6S,8R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-3-((tert-butyldimethylsilyl)oxy)-9-((tert-butyldiphenylsilyl)oxy)-5-((4-methoxybenzyl)oxy)-2,4,6,8-tetramethylnonan-1-one

1443051-52-2

(3R,4R,E)-6-iodo-4-methylhex-5-en-3-yl (2R,3S,4R,5R,6S,8R)-3-((tert-butyldimethylsilyl)oxy)-9-((tert-butyldiphenylsilyl)oxy)-5-((4-methoxybenzyl)oxy)-2,4,6,8-tetramethylnonanoate

1443051-59-9

(2S,3R,4R,5R,6S,8R)-3-((tert-butyldimethylsilyl)oxy)-9-((tert-butyldiphenylsilyl)oxy)-5-((4-methoxybenzyl)oxy)-2,4,6,8-tetramethylnonan-1-ol

1443051-52-2

(3R,4R,E)-6-iodo-4-methylhex-5-en-3-yl (2R,3S,4R,5R,6S,8R)-3-((tert-butyldimethylsilyl)oxy)-9-((tert-butyldiphenylsilyl)oxy)-5-((4-methoxybenzyl)oxy)-2,4,6,8-tetramethylnonanoate

1443051-54-4

(2R,4S)-4-((4R,5S)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)-2-methylpentan-1-ol

1443051-52-2

(3R,4R,E)-6-iodo-4-methylhex-5-en-3-yl (2R,3S,4R,5R,6S,8R)-3-((tert-butyldimethylsilyl)oxy)-9-((tert-butyldiphenylsilyl)oxy)-5-((4-methoxybenzyl)oxy)-2,4,6,8-tetramethylnonanoate

1443051-55-5

tert-butyl(((2R,4S)-4-((4R,5S)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)-2-methylpentyl)oxy)diphenylsilane

1443051-52-2

(3R,4R,E)-6-iodo-4-methylhex-5-en-3-yl (2R,3S,4R,5R,6S,8R)-3-((tert-butyldimethylsilyl)oxy)-9-((tert-butyldiphenylsilyl)oxy)-5-((4-methoxybenzyl)oxy)-2,4,6,8-tetramethylnonanoate

上游原料

(2R,3S,4R,5R,6S,8R)-3-((tert-butyldimethylsilyl)oxy)-9-((tert-butyldiphenylsilyl)oxy)-5-((4-methoxybenzyl)oxy)-2,4,6,8-tetramethylnonanoic acid (2R,3S,4R,5R,6S,8R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-3-((tert-butyldimethylsilyl)oxy)-9-((tert-butyldiphenylsilyl)oxy)-5-((4-methoxybenzyl)oxy)-2,4,6,8-tetramethylnonan-1-one (E)-(3R,4R)-6-iodo-4-methyl-5-hexen-3-ol (2S,3R,4R,5R,6S,8R)-3-((tert-butyldimethylsilyl)oxy)-9-((tert-butyldiphenylsilyl)oxy)-5-((4-methoxybenzyl)oxy)-2,4,6,8-tetramethylnonan-1-ol (2S,3R,4S,6R)-7-((tert-butyldiphenylsilyl)oxy)-3-((4-methoxybenzyl)oxy)-2,4,6-trimethylheptan-1-ol (2R,3S,4S,5R,6S,8R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-9-((tert-butyldiphenylsilyl)oxy)-3-hydroxy-5-((4-methoxybenzyl)oxy)-2,4,6,8-tetramethylnonan-1-one (2R,4S)-4-((4R,5S)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)-2-methylpentan-1-ol tert-butyl(((2R,4S)-4-((4R,5S)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)-2-methylpentyl)oxy)diphenylsilane

下游产品

(3R,4R,5E)-6-iodo-4-methylhex-5-en-3-yl (2R,3S,4S,5R,6S,8R)-3,9-dihydroxy-5-(4-methoxybenzyloxy)-2,4,6,8-tetramethylnonanoate