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4-O-(tert-butyldimethylsilyl)-α-L-rhodinopyranosyl-(1→4)-2,3-di-O-benzoyl-1-O-benzyl-α-L-rhamnopyranoside

4-O-(tert-butyldimethylsilyl)-α-L-rhodinopyranosyl-(1→4)-2,3-di-O-benzoyl-1-O-benzyl-α-L-rhamnopyranoside

CAS号：1443651-40-8

英文名：4-O-(tert-butyldimethylsilyl)-α-L-rhodinopyranosyl-(1→4)-2,3-di-O-benzoyl-1-O-benzyl-α-L-rhamnopyranoside

分子式：C39H50O9Si

分子量：690.894

合成路线

benzyl 4-O-(4-methoxybenzyl)-α-L-rhamnopyranoside

benzyl 4-O-(4-methoxybenzyl)-α-L-rhamnopyranoside

4-O-(tert-butyldimethylsilyl)-α-L-rhodinopyranosyl-(1→4)-2,3-di-O-benzoyl-1-O-benzyl-α-L-rhamnopyranoside

4-O-(tert-butyldimethylsilyl)-α-L-rhodinopyranosyl-(1→4)-2,3-di-O-benzoyl-1-O-benzyl-α-L-rhamnopyranoside

benzyl 2,3-O-isopropylidene-4-O-(4-methoxybenzyl)-α-L-rhamnopyranoside

benzyl 2,3-O-isopropylidene-4-O-(4-methoxybenzyl)-α-L-rhamnopyranoside

4-O-(tert-butyldimethylsilyl)-α-L-rhodinopyranosyl-(1→4)-2,3-di-O-benzoyl-1-O-benzyl-α-L-rhamnopyranoside

4-O-(tert-butyldimethylsilyl)-α-L-rhodinopyranosyl-(1→4)-2,3-di-O-benzoyl-1-O-benzyl-α-L-rhamnopyranoside

benzyl 2,3-O-isopropylidene-α-L-rhamnopyranoside

benzyl 2,3-O-isopropylidene-α-L-rhamnopyranoside

4-O-(tert-butyldimethylsilyl)-α-L-rhodinopyranosyl-(1→4)-2,3-di-O-benzoyl-1-O-benzyl-α-L-rhamnopyranoside

4-O-(tert-butyldimethylsilyl)-α-L-rhodinopyranosyl-(1→4)-2,3-di-O-benzoyl-1-O-benzyl-α-L-rhamnopyranoside

(3aR,4R,6S,7S,7aR)-4-(benzyloxy)-7-((4-methoxybenzyl)oxy)-6-methyltetrahydro-4H-[1,3]dioxolo[4,5-c]pyran-2-one

(3aR,4R,6S,7S,7aR)-4-(benzyloxy)-7-((4-methoxybenzyl)oxy)-6-methyltetrahydro-4H-[1,3]dioxolo[4,5-c]pyran-2-one

4-O-(tert-butyldimethylsilyl)-α-L-rhodinopyranosyl-(1→4)-2,3-di-O-benzoyl-1-O-benzyl-α-L-rhamnopyranoside

4-O-(tert-butyldimethylsilyl)-α-L-rhodinopyranosyl-(1→4)-2,3-di-O-benzoyl-1-O-benzyl-α-L-rhamnopyranoside

benzyl 2,3-O-carboxy-α-L-rhamnopyranoside

benzyl 2,3-O-carboxy-α-L-rhamnopyranoside

4-O-(tert-butyldimethylsilyl)-α-L-rhodinopyranosyl-(1→4)-2,3-di-O-benzoyl-1-O-benzyl-α-L-rhamnopyranoside

4-O-(tert-butyldimethylsilyl)-α-L-rhodinopyranosyl-(1→4)-2,3-di-O-benzoyl-1-O-benzyl-α-L-rhamnopyranoside

4-O-(tert-butyldimethylsilyl)-α-L-rhodinopyranosyl-(1→4)-2,3-O-carboxy-1-O-benzyl-α-L-rhamnopyranoside

4-O-(tert-butyldimethylsilyl)-α-L-rhodinopyranosyl-(1→4)-2,3-O-carboxy-1-O-benzyl-α-L-rhamnopyranoside

4-O-(tert-butyldimethylsilyl)-α-L-rhodinopyranosyl-(1→4)-2,3-di-O-benzoyl-1-O-benzyl-α-L-rhamnopyranoside

4-O-(tert-butyldimethylsilyl)-α-L-rhodinopyranosyl-(1→4)-2,3-di-O-benzoyl-1-O-benzyl-α-L-rhamnopyranoside

上游原料

benzyl 4-O-(4-methoxybenzyl)-α-L-rhamnopyranoside (3aR,4R,6S,7S,7aR)-4-(benzyloxy)-7-((4-methoxybenzyl)oxy)-6-methyltetrahydro-4H-[1,3]dioxolo[4,5-c]pyran-2-one 4-O-(tert-butyldimethylsilyl)-α-L-rhodinopyranosyl-(1→4)-2,3-O-carboxy-1-O-benzyl-α-L-rhamnopyranoside benzyl 2,3-O-isopropylidene-4-O-(4-methoxybenzyl)-α-L-rhamnopyranoside benzyl 2,3-O-carboxy-α-L-rhamnopyranoside benzyl 2,3-O-isopropylidene-α-L-rhamnopyranoside

下游产品

4-O-acetyl-3-O-tert-butyldimethylsilyl-2-thiophenyl-6-O-tosyl-β-D-glycopyranosyl-(1→4)-α-L-rhodinopyranosyl-(1→4)-2,3-di-O-benzoyl-1-O-benzyl-α-L-rhamnopyranoside 4-O-acetyl-3-O-tert-butyldimethylsilyl-2-thiophenyl-6-O-tosyl-α-D-glycopyranosyl-(1→4)-α-L-rhodinopyranosyl-(1→4)-2,3-di-O-benzoyl-1-O-benzyl-α-L-rhamnopyranoside α-L-rhodinopyranosyl-(1→4)-2,3-di-O-benzoyl-1-O-benzyl-α-L-rhamnopyranoside