百科

S-((7R)-7-((tert-butyldimethylsilyl)oxy)-1-((3S,6R,9S,14aR)-6,9-dibenzyl-6-methyl-1,4,7,10-tetraoxotetradecahydropyrrolo[1,2-a][1,4,7,10]tetraazacyclododecin-3-yl)-6-oxooctan-3-yl) O-ethyl carbonodithioate

CAS号：1445578-67-5

英文名：S-((7R)-7-((tert-butyldimethylsilyl)oxy)-1-((3S,6R,9S,14aR)-6,9-dibenzyl-6-methyl-1,4,7,10-tetraoxotetradecahydropyrrolo[1,2-a][1,4,7,10]tetraazacyclododecin-3-yl)-6-oxooctan-3-yl) O-ethyl carbonodithioate

分子式：C43H62N4O7S2Si

分子量：839.19

合成路线

92136-57-7

methyl 2-[(tert-butoxycarbonyl)amino]hex-5-enoate

1445578-67-5

S-((7R)-7-((tert-butyldimethylsilyl)oxy)-1-((3S,6R,9S,14aR)-6,9-dibenzyl-6-methyl-1,4,7,10-tetraoxotetradecahydropyrrolo[1,2-a][1,4,7,10]tetraazacyclododecin-3-yl)-6-oxooctan-3-yl) O-ethyl carbonodithioate

1037074-43-3

(-)-(2S,4R)-3-benzoyl-4-benzyl-4-methyl-2-phenyl-1,3-oxazolidin-5-one

84120-87-6

上游原料

H-L-Ala-D-Pro-OtBu methyl 2-[(tert-butoxycarbonyl)amino]hex-5-enoate (-)-(2S,4R)-3-benzoyl-4-benzyl-4-methyl-2-phenyl-1,3-oxazolidin-5-one

下游产品

(3S,6R,9S,14aR)-6,9-dibenzyl-3-((R)-7-((tert-butyldimethylsilyl)oxy)-6-oxooctyl)-6-methyldecahydropyrrolo[1,2-a][1,4,7,10]tetraazacyclododecine-1,4,7,10-tetraone (-)-(3S,6R,9S,14aR)-6,9-dibenzyl-3-[(R)-7-hydroxy-6-oxooctyl]-6-methyldecahydropyrrolo[1,2-a][1,4,7,10]tetraazacyclododecine-1,4,7,10-tetraone