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3-((4R,5S)-5-(benzyloxymethyl)-2,2,4-trimethyl-1,3-dioxolan-4-yl)propanal

3-((4R,5S)-5-(benzyloxymethyl)-2,2,4-trimethyl-1,3-dioxolan-4-yl)propanal

CAS号：1446120-13-3

英文名：3-((4R,5S)-5-(benzyloxymethyl)-2,2,4-trimethyl-1,3-dioxolan-4-yl)propanal

分子式：C17H24O4

分子量：292.37

合成路线

(4R,5S)-5-(benzyloxymethyl)-2,2,4-trimethyl-4-(4-methylpent-3-enyl)-1,3-dioxolane

(4R,5S)-5-(benzyloxymethyl)-2,2,4-trimethyl-4-(4-methylpent-3-enyl)-1,3-dioxolane

3-((4R,5S)-5-(benzyloxymethyl)-2,2,4-trimethyl-1,3-dioxolan-4-yl)propanal

3-((4R,5S)-5-(benzyloxymethyl)-2,2,4-trimethyl-1,3-dioxolan-4-yl)propanal

(2S,3R)-1-(benzyloxy)-3,7-dimethyloct-6-ene-2,3-diol

(2S,3R)-1-(benzyloxy)-3,7-dimethyloct-6-ene-2,3-diol

3-((4R,5S)-5-(benzyloxymethyl)-2,2,4-trimethyl-1,3-dioxolan-4-yl)propanal

3-((4R,5S)-5-(benzyloxymethyl)-2,2,4-trimethyl-1,3-dioxolan-4-yl)propanal

上游原料

(2S,3R)-1-(benzyloxy)-3,7-dimethyloct-6-ene-2,3-diol (4R,5S)-5-(benzyloxymethyl)-2,2,4-trimethyl-4-(4-methylpent-3-enyl)-1,3-dioxolane

下游产品

((4S,5R)-5-((R)-3,5-bis(tert-butyldimethylsilyloxy)pentyl)-2,2,5-tri-methyl-1,3-dioxolan-4-yl)methanol (2S,3S,6S,7R,10R,E)-7,10-dihydroxy-3,7-dimethyl-12-oxo-2-phenyloxa cyclododec-4-en-6-yl acetate (4R,7R,8S,11S,12S,E)-12-(4-fluorophenyl)-4,7,8-trihydroxy-7,11-dimethyloxacyclododec-9-en-2-one (R)-5-(2-((4R,5S)-5-(benzyloxymethyl)-2,2,4-trimethyl-1,3-dioxolan-4-yl)ethyl)-2,2,3,3,8,8,9,9-octamethyl-4,7-dioxa-3,8-disiladecane (4R,7R,8S,11S,12S,E)-4,7,8-trihydroxy-7,11-dimethyl-12-phenyl-oxacyclododec-9-en-2-one (R)-((1S,2S)-1-(4-fluorophenyl)-2-methylbut-3-enyl)-3-(tert-butyl-dimethylsilyloxy)-5-((4R,5S)-2,2,4-trimethyl-5-vinyl-1,3-dioxolan-4-yl)pentanoate (R)-2,2,3,3,9,9,10,10-octamethyl-5-(2-((4R,5S)-2,2,4-trimethyl-5-vinyl-1,3-dioxolan-4-yl)ethyl)-4,8-dioxa-3,9-disilaundecane pladienoldie B (R)-((1S,2S)-2-methyl-1-p-tolylbut-3-enyl)-3-(tert-butyldimethylsilyl-oxy)-5-((4R,5S)-2,2,4-trimethyl-5-vinyl-1,3-dioxolan-4-yl)pentanoate (4R,7R,8S,11S,12S,E)-4,7,8-trihydroxy-7,11-dimethyl-12-p-tolyl-oxacyclododec-9-en-2-one (3R,6R,7S)-((1S,2S)-2-methyl-1-phenylbut-3-enyl) 3,6,7-trihydroxy-6-methylnon-8-enoate (4R,7R,8S,11S,12S,E)-4,7,8-trihydroxy-12-((E)-1-iodoprop-1-en-2-yl)-7,11-dimethyloxacyclododec-9-en-2-one (4R,7R,8S,11RS12S,E)-4,7,8-trihydroxy-12-(4-methoxyphenyl)-7,11-dimethyloxacyclododec-9-en-2-one (R)-((1S,2S)-1-(4-methoxyphenyl)-2-methylbut-3-enyl) 3-(tert-butyl dimethylsilyloxy)-5-((4R,5S)-2,2,4-trimethyl-5-vinyl-1,3-dioxolan-4-yl)pentanoate ((2R,3R)-3-(2-((4R,5S)-5-(benzyloxymethyl)-2,2,4-trimethyl-1,3-dioxolan-4-yl)ethyl)oxiran-2-yl)methanol (2S,3S,6S,7R,10R,E)-2-(4-fluorophenyl)-7,10-dihydroxy-3,7-dimethyl-12-oxooxacyclododec-4-en-6-yl acetate (R)-3-(tert-butyldimethylsilyloxy)-5-((4R,5S)-2,2,4-trimethyl-5-vinyl-1,3-dioxolan-4-yl)pentan-1-ol (3R,6R,7S)-((3S,4S,E)-1-iodo-2,4-dimethylhexa-1,5-dien-3-yl) 3,6,7-trihydroxy-6-methylnon-8-enoate (3R,6R,7S)-((1S,2S)-2-methyl-1-p-tolylbut-3-enyl) 3,6,7-trihydroxy-6-methylnon-8-enoate (E)-5-((4R,5S)-5-(benzyloxymethyl)-2,2,4-trimethyl-1,3-dioxolan-4-yl)pent-2-en-1-ol (R)-((3S,4S,E)-1-iodo-2,4-dimethylhexa-1,5-dien-3-yl) 3-(tert-butyl-dimethylsilyloxy)-5-((4R,5S)-2,2,4-trimethyl-5-vinyl-1,3-dioxolan-4-yl)pentanoate (R)-5-((4R,5S)-5-(benzyloxymethyl)-2,2,4-trimethyl-1,3-dioxolan-4-yl)pentane-1,3-diol (3R,6R,7S)-((1S,2S)-1-(4-fluorophenyl)-2-methylbut-3-enyl)-3,6,7-trihydroxy-6-methylnon-8-enoate (R)-((1S,2S)-2-methyl-1-phenylbut-3-enyl)-3-(tert-butyldimethylsilyloxy)-5-((4R,5S)-2,2,4-trimethyl-5-vinyl-1,3-dioxolan-4-yl)pentanoate (3R,6R,7S)-((1S,2S)-1-(4-methoxyphenyl)-2-methylbut-3-enyl) 3,6,7-tri-hydroxy-6-methylnon-8-enoate (2S,3S,6S,7R,10R,E)-7,10-dihydroxy-3,7-dimethyl-12-oxo-2-p-tolyl-oxacyclododec-4-en-6-yl acetate (R)-3-(tert-butyldimethylsilyloxy)-5-((4R,5S)-2,2,4-trimethyl-5-vinyl-1,3-dioxolan-4-yl)pentanoic acid (2S,3S,6S,7R,10R,E)-7,10-dihydroxy-2-(4-methoxyphenyl)-3,7-dimethyl-12-oxooxacyclododec-4-en-6-yl acetate