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tert-butyl((3S,4S,E)-1-iodo-2,4-dimethylhexa-1,5-dien-3-yloxy)dimethylsilane

tert-butyl((3S,4S,E)-1-iodo-2,4-dimethylhexa-1,5-dien-3-yloxy)dimethylsilane

CAS号：1446120-60-0

英文名：tert-butyl((3S,4S,E)-1-iodo-2,4-dimethylhexa-1,5-dien-3-yloxy)dimethylsilane

分子式：C14H27IOSi

分子量：366.354

合成路线

(S)-4-benzyl-3-((2S,3S,E)-3-hydroxy-5-iodo-4-methyl-2-vinylpent-4-enoyl)oxazolidin-2-one

(S)-4-benzyl-3-((2S,3S,E)-3-hydroxy-5-iodo-4-methyl-2-vinylpent-4-enoyl)oxazolidin-2-one

tert-butyl((3S,4S,E)-1-iodo-2,4-dimethylhexa-1,5-dien-3-yloxy)dimethylsilane

tert-butyl((3S,4S,E)-1-iodo-2,4-dimethylhexa-1,5-dien-3-yloxy)dimethylsilane

(2R,3S,E)-3-(tert-butyldimethylsilyloxy)-5-iodo-4-methyl-2-vinylpent-4-en-1-ol

(2R,3S,E)-3-(tert-butyldimethylsilyloxy)-5-iodo-4-methyl-2-vinylpent-4-en-1-ol

tert-butyl((3S,4S,E)-1-iodo-2,4-dimethylhexa-1,5-dien-3-yloxy)dimethylsilane

tert-butyl((3S,4S,E)-1-iodo-2,4-dimethylhexa-1,5-dien-3-yloxy)dimethylsilane

(S)-4-benzyl-3-((2S,3S,E)-3-(tert-butyldimethylsilyloxy)-5-iodo-4-methyl-2-vinylpent-4-enoyl)oxazolidin-2-one

(S)-4-benzyl-3-((2S,3S,E)-3-(tert-butyldimethylsilyloxy)-5-iodo-4-methyl-2-vinylpent-4-enoyl)oxazolidin-2-one

tert-butyl((3S,4S,E)-1-iodo-2,4-dimethylhexa-1,5-dien-3-yloxy)dimethylsilane

tert-butyl((3S,4S,E)-1-iodo-2,4-dimethylhexa-1,5-dien-3-yloxy)dimethylsilane

上游原料

(2R,3S,E)-3-(tert-butyldimethylsilyloxy)-5-iodo-4-methyl-2-vinylpent-4-en-1-ol (S)-4-benzyl-3-((2S,3S,E)-3-hydroxy-5-iodo-4-methyl-2-vinylpent-4-enoyl)oxazolidin-2-one (S)-4-benzyl-3-((2S,3S,E)-3-(tert-butyldimethylsilyloxy)-5-iodo-4-methyl-2-vinylpent-4-enoyl)oxazolidin-2-one

下游产品

(3R,6R,7S)-((3S,4S,E)-1-iodo-2,4-dimethylhexa-1,5-dien-3-yl) 3,6,7-trihydroxy-6-methylnon-8-enoate (R)-((3S,4S,E)-1-iodo-2,4-dimethylhexa-1,5-dien-3-yl) 3-(tert-butyl-dimethylsilyloxy)-5-((4R,5S)-2,2,4-trimethyl-5-vinyl-1,3-dioxolan-4-yl)pentanoate pladienoldie B (4R,7R,8S,11S,12S,E)-4,7,8-trihydroxy-12-((E)-1-iodoprop-1-en-2-yl)-7,11-dimethyloxacyclododec-9-en-2-one