百科

tert-butyl((3S,4S,8S,E)-10,10-dibromo-4,8-dimethyldeca-5,9-dien-3-yloxy)dimethylsilane

tert-butyl((3S,4S,8S,E)-10,10-dibromo-4,8-dimethyldeca-5,9-dien-3-yloxy)dimethylsilane

CAS号：1446121-13-6

英文名：tert-butyl((3S,4S,8S,E)-10,10-dibromo-4,8-dimethyldeca-5,9-dien-3-yloxy)dimethylsilane

分子式：C18H34Br2OSi

分子量：454.355

合成路线

((2S,3S)-3-ethyl-2-methyloxiran-2-yl)methanol

((2S,3S)-3-ethyl-2-methyloxiran-2-yl)methanol

tert-butyl((3S,4S,8S,E)-10,10-dibromo-4,8-dimethyldeca-5,9-dien-3-yloxy)dimethylsilane

tert-butyl((3S,4S,8S,E)-10,10-dibromo-4,8-dimethyldeca-5,9-dien-3-yloxy)dimethylsilane

(3S,4S,5S)-5-(tert-butyldimethylsilyloxy)-4-methylhept-1-en-3-ol

(3S,4S,5S)-5-(tert-butyldimethylsilyloxy)-4-methylhept-1-en-3-ol

tert-butyl((3S,4S,8S,E)-10,10-dibromo-4,8-dimethyldeca-5,9-dien-3-yloxy)dimethylsilane

tert-butyl((3S,4S,8S,E)-10,10-dibromo-4,8-dimethyldeca-5,9-dien-3-yloxy)dimethylsilane

(4S,5S)-5-{[tert-butyl(dimethyl)silyl]oxy}-4-methylhept-1-en-3-ol

(4S,5S)-5-{[tert-butyl(dimethyl)silyl]oxy}-4-methylhept-1-en-3-ol

tert-butyl((3S,4S,8S,E)-10,10-dibromo-4,8-dimethyldeca-5,9-dien-3-yloxy)dimethylsilane

tert-butyl((3S,4S,8S,E)-10,10-dibromo-4,8-dimethyldeca-5,9-dien-3-yloxy)dimethylsilane

(4R,5S)-5-(tert-butyldimethylsilyloxy)-4-methylhept-1-en-3-one

(4R,5S)-5-(tert-butyldimethylsilyloxy)-4-methylhept-1-en-3-one

tert-butyl((3S,4S,8S,E)-10,10-dibromo-4,8-dimethyldeca-5,9-dien-3-yloxy)dimethylsilane

tert-butyl((3S,4S,8S,E)-10,10-dibromo-4,8-dimethyldeca-5,9-dien-3-yloxy)dimethylsilane

(3S,4S,5S)-5-(tert-butyldimethylsilyloxy)-4-methylhept-1-en-3-yl propionate

(3S,4S,5S)-5-(tert-butyldimethylsilyloxy)-4-methylhept-1-en-3-yl propionate

tert-butyl((3S,4S,8S,E)-10,10-dibromo-4,8-dimethyldeca-5,9-dien-3-yloxy)dimethylsilane

tert-butyl((3S,4S,8S,E)-10,10-dibromo-4,8-dimethyldeca-5,9-dien-3-yloxy)dimethylsilane

(2S,6S,7S,E)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylnon-4-enoic acid

(2S,6S,7S,E)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylnon-4-enoic acid

tert-butyl((3S,4S,8S,E)-10,10-dibromo-4,8-dimethyldeca-5,9-dien-3-yloxy)dimethylsilane

tert-butyl((3S,4S,8S,E)-10,10-dibromo-4,8-dimethyldeca-5,9-dien-3-yloxy)dimethylsilane

上游原料

(3S,4S,5S)-5-(tert-butyldimethylsilyloxy)-4-methylhept-1-en-3-ol (2S,6S,7S,E)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylnon-4-enoic acid (4S,5S)-5-{[tert-butyl(dimethyl)silyl]oxy}-4-methylhept-1-en-3-ol ((2S,3S)-3-ethyl-2-methyloxiran-2-yl)methanol (3S,4S,5S)-5-(tert-butyldimethylsilyloxy)-4-methylhept-1-en-3-yl propionate (4R,5S)-5-(tert-butyldimethylsilyloxy)-4-methylhept-1-en-3-one

下游产品

(3S,4S,8S,E)-4,8-dimethyldec-5-en-9-yn-3-ol (2R,3S)-2-{(2R,3R)-3-[(2S)-2-methylbut-3-ynyl]oxiran-2-yl}pentan-3-ol pladienoldie B (3S,4S,5E,8S)-3-{[tert-butyl(dimethyl)silyl]oxy}-4,8-dimethyldec-5-en-9-yne