百科

N-((2R,3S,4S,5R,6R,7E,9E)-3-((tert-butyldimethylsilyl)oxy)-4,6,9-trimethyl-10-((1R,6R)-6-methyl-6-((triethylsilyl)ethynyl)cyclohex-2-en-1-yl)-5-((triethylsilyl)oxy)deca-7,9-dien-2-yl)acetamide

CAS号：1448446-18-1

英文名：N-((2R,3S,4S,5R,6R,7E,9E)-3-((tert-butyldimethylsilyl)oxy)-4,6,9-trimethyl-10-((1R,6R)-6-methyl-6-((triethylsilyl)ethynyl)cyclohex-2-en-1-yl)-5-((triethylsilyl)oxy)deca-7,9-dien-2-yl)acetamide

分子式：C42H79NO3Si3

分子量：730.338

合成路线

1448446-08-9

N-((2R,3S,4S,5R,6R,E)-3-((tert-butyldimethylsilyl)oxy)-4,6-dimethyl-8-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-5-((triethylsilyl)oxy)oct-7-en-2-yl)acetamide

1448446-18-1

N-((2R,3S,4S,5R,6R,7E,9E)-3-((tert-butyldimethylsilyl)oxy)-4,6,9-trimethyl-10-((1R,6R)-6-methyl-6-((triethylsilyl)ethynyl)cyclohex-2-en-1-yl)-5-((triethylsilyl)oxy)deca-7,9-dien-2-yl)acetamide

1448446-09-0

(3aS,7aR)-7a-methyl-3a,6,7,7a-tetrahydroisobenzofuran-1(3H)-one

1448446-18-1

N-((2R,3S,4S,5R,6R,7E,9E)-3-((tert-butyldimethylsilyl)oxy)-4,6,9-trimethyl-10-((1R,6R)-6-methyl-6-((triethylsilyl)ethynyl)cyclohex-2-en-1-yl)-5-((triethylsilyl)oxy)deca-7,9-dien-2-yl)acetamide

1448446-12-5

((1S,6R)-6-ethynyl-6-methylcyclohex-2-en-1-yl)methanol

1448446-18-1

N-((2R,3S,4S,5R,6R,7E,9E)-3-((tert-butyldimethylsilyl)oxy)-4,6,9-trimethyl-10-((1R,6R)-6-methyl-6-((triethylsilyl)ethynyl)cyclohex-2-en-1-yl)-5-((triethylsilyl)oxy)deca-7,9-dien-2-yl)acetamide

1448446-13-6

triethyl(((1R,2S)-1-methyl-2-(((triethylsilyl)oxy)methyl)cyclohex-3-en-1-yl)ethynyl)silane

1448446-18-1

N-((2R,3S,4S,5R,6R,7E,9E)-3-((tert-butyldimethylsilyl)oxy)-4,6,9-trimethyl-10-((1R,6R)-6-methyl-6-((triethylsilyl)ethynyl)cyclohex-2-en-1-yl)-5-((triethylsilyl)oxy)deca-7,9-dien-2-yl)acetamide

1448446-14-7

((1S,6R)-6-methyl-6-((triethylsilyl)ethynyl)cyclohex-2-en-1-yl)methanol

1448446-18-1

N-((2R,3S,4S,5R,6R,7E,9E)-3-((tert-butyldimethylsilyl)oxy)-4,6,9-trimethyl-10-((1R,6R)-6-methyl-6-((triethylsilyl)ethynyl)cyclohex-2-en-1-yl)-5-((triethylsilyl)oxy)deca-7,9-dien-2-yl)acetamide

1448446-15-8

(1S,6R)-6-methyl-6-((triethylsilyl)ethynyl)cyclohex-2-ene-1-carbaldehyde

1448446-18-1

N-((2R,3S,4S,5R,6R,7E,9E)-3-((tert-butyldimethylsilyl)oxy)-4,6,9-trimethyl-10-((1R,6R)-6-methyl-6-((triethylsilyl)ethynyl)cyclohex-2-en-1-yl)-5-((triethylsilyl)oxy)deca-7,9-dien-2-yl)acetamide

1448446-16-9

(((1R,2R)-2-(2,2-dibromovinyl)-1-methylcyclohex-3-en-1-yl)ethynyl)triethylsilane

1448446-18-1

N-((2R,3S,4S,5R,6R,7E,9E)-3-((tert-butyldimethylsilyl)oxy)-4,6,9-trimethyl-10-((1R,6R)-6-methyl-6-((triethylsilyl)ethynyl)cyclohex-2-en-1-yl)-5-((triethylsilyl)oxy)deca-7,9-dien-2-yl)acetamide

344796-40-3

N-[(1R,2S,3S,4R,5R)-2-(tert-Butyl-dimethyl-silanyloxy)-1,3,5-trimethyl-4-triethylsilanyloxy-hept-6-enyl]-acetamide

1448446-18-1

N-((2R,3S,4S,5R,6R,7E,9E)-3-((tert-butyldimethylsilyl)oxy)-4,6,9-trimethyl-10-((1R,6R)-6-methyl-6-((triethylsilyl)ethynyl)cyclohex-2-en-1-yl)-5-((triethylsilyl)oxy)deca-7,9-dien-2-yl)acetamide

上游原料

N-[(1R,2S,3S,4R,5R)-2-(tert-Butyl-dimethyl-silanyloxy)-1,3,5-trimethyl-4-triethylsilanyloxy-hept-6-enyl]-acetamide (3aS,7aR)-7a-methyl-3a,6,7,7a-tetrahydroisobenzofuran-1(3H)-one ((1S,6R)-6-ethynyl-6-methylcyclohex-2-en-1-yl)methanol triethyl(((1R,2S)-1-methyl-2-(((triethylsilyl)oxy)methyl)cyclohex-3-en-1-yl)ethynyl)silane ((1S,6R)-6-methyl-6-((triethylsilyl)ethynyl)cyclohex-2-en-1-yl)methanol N-((2R,3S,4S,5R,6R,E)-3-((tert-butyldimethylsilyl)oxy)-4,6-dimethyl-8-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-5-((triethylsilyl)oxy)oct-7-en-2-yl)acetamide (1S,6R)-6-methyl-6-((triethylsilyl)ethynyl)cyclohex-2-ene-1-carbaldehyde (((1R,2R)-2-(2,2-dibromovinyl)-1-methylcyclohex-3-en-1-yl)ethynyl)triethylsilane

下游产品

N-((2R,3S,4S,5R,6R,7E,9E)-3,5-dihydroxy-4,6,9-trimethyl-10-((1R,6R)-6-methyl-6-((E)-2-(tributylstannyl)vinyl)cyclohex-2-en-1-yl)deca-7,9-dien-2-yl)acetamide N-((2R,3S,4S,5R,6R,7E,9E)-10-((1R,6R)-6-ethynyl-6-methylcyclohex-2-en-1-yl)-3,5-dihydroxy-4,6,9-trimethyldeca-7,9-dien-2-yl)acetamide