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(1S,3R,5R,9R,13R)-3-(4-(3-(benzyloxy)phenyl)butyl)-9-(methoxymethyl)-16,16-dimethyl-2,6,10,17-tetraoxatricyclo[11.3.1.11,5]octadecane-7,11-dione

(1S,3R,5R,9R,13R)-3-(4-(3-(benzyloxy)phenyl)butyl)-9-(methoxymethyl)-16,16-dimethyl-2,6,10,17-tetraoxatricyclo[11.3.1.11,5]octadecane-7,11-dione

CAS号：1449419-44-6

英文名：(1S,3R,5R,9R,13R)-3-(4-(3-(benzyloxy)phenyl)butyl)-9-(methoxymethyl)-16,16-dimethyl-2,6,10,17-tetraoxatricyclo[11.3.1.11,5]octadecane-7,11-dione

分子式：C35H46O8

分子量：594.735

合成路线

(R)-4-Methoxy-3-(4-methoxy-benzyloxy)-butyraldehyde

(R)-4-Methoxy-3-(4-methoxy-benzyloxy)-butyraldehyde

(1S,3R,5R,9R,13R)-3-(4-(3-(benzyloxy)phenyl)butyl)-9-(methoxymethyl)-16,16-dimethyl-2,6,10,17-tetraoxatricyclo[11.3.1.11,5]octadecane-7,11-dione

(1S,3R,5R,9R,13R)-3-(4-(3-(benzyloxy)phenyl)butyl)-9-(methoxymethyl)-16,16-dimethyl-2,6,10,17-tetraoxatricyclo[11.3.1.11,5]octadecane-7,11-dione

2-((2R,6S,8R,10R)-8-(4-(3-(benzyloxy)phenyl)butyl)-10-(((R)-3-hydroxy-4-methoxybutanoyl)oxy)-5,5-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl)acetic acid

2-((2R,6S,8R,10R)-8-(4-(3-(benzyloxy)phenyl)butyl)-10-(((R)-3-hydroxy-4-methoxybutanoyl)oxy)-5,5-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl)acetic acid

(1S,3R,5R,9R,13R)-3-(4-(3-(benzyloxy)phenyl)butyl)-9-(methoxymethyl)-16,16-dimethyl-2,6,10,17-tetraoxatricyclo[11.3.1.11,5]octadecane-7,11-dione

(1S,3R,5R,9R,13R)-3-(4-(3-(benzyloxy)phenyl)butyl)-9-(methoxymethyl)-16,16-dimethyl-2,6,10,17-tetraoxatricyclo[11.3.1.11,5]octadecane-7,11-dione

(2R,4R,6R,8R)-8-allyl-2-(4-(3-(benzyloxy)phenyl)butyl)-11,11-dimethyl-1,7-dioxaspiro[5.5]undecan-4-yl (R)-3-hydroxy-4-methoxybutanoate

(2R,4R,6R,8R)-8-allyl-2-(4-(3-(benzyloxy)phenyl)butyl)-11,11-dimethyl-1,7-dioxaspiro[5.5]undecan-4-yl (R)-3-hydroxy-4-methoxybutanoate

(1S,3R,5R,9R,13R)-3-(4-(3-(benzyloxy)phenyl)butyl)-9-(methoxymethyl)-16,16-dimethyl-2,6,10,17-tetraoxatricyclo[11.3.1.11,5]octadecane-7,11-dione

(1S,3R,5R,9R,13R)-3-(4-(3-(benzyloxy)phenyl)butyl)-9-(methoxymethyl)-16,16-dimethyl-2,6,10,17-tetraoxatricyclo[11.3.1.11,5]octadecane-7,11-dione

(2R,4R,6R,8R)-8-allyl-2-(4-(3-(benzyloxy)phenyl)butyl)-11,11-dimethyl-1,7-dioxaspiro[5.5]undecan-4-yl (R)-4-methoxy-3-((triethylsilyl)oxy)butanoate

(2R,4R,6R,8R)-8-allyl-2-(4-(3-(benzyloxy)phenyl)butyl)-11,11-dimethyl-1,7-dioxaspiro[5.5]undecan-4-yl (R)-4-methoxy-3-((triethylsilyl)oxy)butanoate

(1S,3R,5R,9R,13R)-3-(4-(3-(benzyloxy)phenyl)butyl)-9-(methoxymethyl)-16,16-dimethyl-2,6,10,17-tetraoxatricyclo[11.3.1.11,5]octadecane-7,11-dione

(1S,3R,5R,9R,13R)-3-(4-(3-(benzyloxy)phenyl)butyl)-9-(methoxymethyl)-16,16-dimethyl-2,6,10,17-tetraoxatricyclo[11.3.1.11,5]octadecane-7,11-dione

(R)-4-methoxy-3-((4-methoxybenzyl)oxy)butanoic acid

(R)-4-methoxy-3-((4-methoxybenzyl)oxy)butanoic acid

(1S,3R,5R,9R,13R)-3-(4-(3-(benzyloxy)phenyl)butyl)-9-(methoxymethyl)-16,16-dimethyl-2,6,10,17-tetraoxatricyclo[11.3.1.11,5]octadecane-7,11-dione

(1S,3R,5R,9R,13R)-3-(4-(3-(benzyloxy)phenyl)butyl)-9-(methoxymethyl)-16,16-dimethyl-2,6,10,17-tetraoxatricyclo[11.3.1.11,5]octadecane-7,11-dione

(2R,4R,6R,8R)-8-allyl-2-(4-(3-(benzyloxy)phenyl)butyl)-11,11-dimethyl-1,7-dioxaspiro[5.5]undecan-4-yl (R)-4-methoxy-3-((4-methoxybenzyl)oxy)butanoate

(2R,4R,6R,8R)-8-allyl-2-(4-(3-(benzyloxy)phenyl)butyl)-11,11-dimethyl-1,7-dioxaspiro[5.5]undecan-4-yl (R)-4-methoxy-3-((4-methoxybenzyl)oxy)butanoate

(1S,3R,5R,9R,13R)-3-(4-(3-(benzyloxy)phenyl)butyl)-9-(methoxymethyl)-16,16-dimethyl-2,6,10,17-tetraoxatricyclo[11.3.1.11,5]octadecane-7,11-dione

(1S,3R,5R,9R,13R)-3-(4-(3-(benzyloxy)phenyl)butyl)-9-(methoxymethyl)-16,16-dimethyl-2,6,10,17-tetraoxatricyclo[11.3.1.11,5]octadecane-7,11-dione

2-((2R,6S,8R,10R)-8-(4-(3-(benzyloxy)phenyl)butyl)-10-(((R)-4-methoxy-3-((triethylsilyl)oxy)butanoyl)oxy)-5,5-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl)acetic acid

2-((2R,6S,8R,10R)-8-(4-(3-(benzyloxy)phenyl)butyl)-10-(((R)-4-methoxy-3-((triethylsilyl)oxy)butanoyl)oxy)-5,5-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl)acetic acid

(1S,3R,5R,9R,13R)-3-(4-(3-(benzyloxy)phenyl)butyl)-9-(methoxymethyl)-16,16-dimethyl-2,6,10,17-tetraoxatricyclo[11.3.1.11,5]octadecane-7,11-dione

(1S,3R,5R,9R,13R)-3-(4-(3-(benzyloxy)phenyl)butyl)-9-(methoxymethyl)-16,16-dimethyl-2,6,10,17-tetraoxatricyclo[11.3.1.11,5]octadecane-7,11-dione

上游原料

(2R,4R,6R,8R)-8-allyl-2-(4-(3-(benzyloxy)phenyl)butyl)-11,11-dimethyl-1,7-dioxaspiro[5.5]undecan-4-yl (R)-3-hydroxy-4-methoxybutanoate (R)-4-methoxy-3-((4-methoxybenzyl)oxy)butanoic acid (R)-4-Methoxy-3-(4-methoxy-benzyloxy)-butyraldehyde (2R,4R,6R,8R)-8-allyl-2-(4-(3-(benzyloxy)phenyl)butyl)-11,11-dimethyl-1,7-dioxaspiro[5.5]undecan-4-yl (R)-4-methoxy-3-((triethylsilyl)oxy)butanoate (2R,4R,6R,8R)-8-allyl-2-(4-(3-(benzyloxy)phenyl)butyl)-11,11-dimethyl-1,7-dioxaspiro[5.5]undecan-4-yl (R)-4-methoxy-3-((4-methoxybenzyl)oxy)butanoate 2-((2R,6S,8R,10R)-8-(4-(3-(benzyloxy)phenyl)butyl)-10-(((R)-4-methoxy-3-((triethylsilyl)oxy)butanoyl)oxy)-5,5-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl)acetic acid 2-((2R,6S,8R,10R)-8-(4-(3-(benzyloxy)phenyl)butyl)-10-(((R)-3-hydroxy-4-methoxybutanoyl)oxy)-5,5-dimethyl-1,7-dioxaspiro[5.5]undecan-2-yl)acetic acid

下游产品

(1S,3R,5R,9R,13R)-3-(4-(3-hydroxyphenyl)butyl)-9-(methoxymethyl)-16,16-dimethyl-2,6,10,17-tetraoxatricyclo[11.3.1.11,5]octadecane-7,11-dione