百科

(5S)-3-((R)-2-((tert-butyldimethylsilyl)oxy)-7-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)heptyl)-5-methyl-3-(phenylthio)dihydrofuran-2(3H)-one

(5S)-3-((R)-2-((tert-butyldimethylsilyl)oxy)-7-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)heptyl)-5-methyl-3-(phenylthio)dihydrofuran-2(3H)-one

CAS号：1449472-02-9

英文名：(5S)-3-((R)-2-((tert-butyldimethylsilyl)oxy)-7-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)heptyl)-5-methyl-3-(phenylthio)dihydrofuran-2(3H)-one

分子式：C29H49BO5SSi

分子量：548.658

合成路线

(R)-1-iodohept-6-en-2-ol

(R)-1-iodohept-6-en-2-ol

(5S)-3-((R)-2-((tert-butyldimethylsilyl)oxy)-7-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)heptyl)-5-methyl-3-(phenylthio)dihydrofuran-2(3H)-one

(5S)-3-((R)-2-((tert-butyldimethylsilyl)oxy)-7-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)heptyl)-5-methyl-3-(phenylthio)dihydrofuran-2(3H)-one

(5S)-5-methyl-3-phenylsulfanyl-4,5-dihydrofuran-2(3H)-one

(5S)-5-methyl-3-phenylsulfanyl-4,5-dihydrofuran-2(3H)-one

(5S)-3-((R)-2-((tert-butyldimethylsilyl)oxy)-7-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)heptyl)-5-methyl-3-(phenylthio)dihydrofuran-2(3H)-one

(5S)-3-((R)-2-((tert-butyldimethylsilyl)oxy)-7-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)heptyl)-5-methyl-3-(phenylthio)dihydrofuran-2(3H)-one

(R)-tert-butyl((1-iodohept-6-en-2-yl)oxy)dimethylsilane

(R)-tert-butyl((1-iodohept-6-en-2-yl)oxy)dimethylsilane

(5S)-3-((R)-2-((tert-butyldimethylsilyl)oxy)-7-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)heptyl)-5-methyl-3-(phenylthio)dihydrofuran-2(3H)-one

(5S)-3-((R)-2-((tert-butyldimethylsilyl)oxy)-7-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)heptyl)-5-methyl-3-(phenylthio)dihydrofuran-2(3H)-one

上游原料

(R)-1-iodohept-6-en-2-ol (5S)-5-methyl-3-phenylsulfanyl-4,5-dihydrofuran-2(3H)-one (R)-tert-butyl((1-iodohept-6-en-2-yl)oxy)dimethylsilane

下游产品

(5S)-3-((2R)-2-((tert-butyldimethylsilyl)oxy)-8-hydroxy-10-phenyldecyl)-5-methyl-3-(phenylthio)dihydrofuran-2(3H)-one