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(7S,13R,Z)-13-((tert-butyldimethylsilyl)oxy)-1-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)-14-iodotetradec-3-en-7-ol

(7S,13R,Z)-13-((tert-butyldimethylsilyl)oxy)-1-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)-14-iodotetradec-3-en-7-ol

CAS号：1449472-07-4

英文名：(7S,13R,Z)-13-((tert-butyldimethylsilyl)oxy)-1-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)-14-iodotetradec-3-en-7-ol

分子式：C39H77IO4Si

分子量：765.016

合成路线

(Z)-7-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)hept-4-en-1-yl diisopropylcarbamate

(Z)-7-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)hept-4-en-1-yl diisopropylcarbamate

(R)-tert-butyl(1-iodo-7-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)heptan-2-yloxy) dimethylsilane

(R)-tert-butyl(1-iodo-7-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)heptan-2-yloxy) dimethylsilane

(7S,13R,Z)-13-((tert-butyldimethylsilyl)oxy)-1-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)-14-iodotetradec-3-en-7-ol

(7S,13R,Z)-13-((tert-butyldimethylsilyl)oxy)-1-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)-14-iodotetradec-3-en-7-ol

3-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)propan-1-ol

3-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)propan-1-ol

(7S,13R,Z)-13-((tert-butyldimethylsilyl)oxy)-1-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)-14-iodotetradec-3-en-7-ol

(7S,13R,Z)-13-((tert-butyldimethylsilyl)oxy)-1-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)-14-iodotetradec-3-en-7-ol

(3-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)propyl)triphenyl phosphonium iodide

(3-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)propyl)triphenyl phosphonium iodide

(7S,13R,Z)-13-((tert-butyldimethylsilyl)oxy)-1-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)-14-iodotetradec-3-en-7-ol

(7S,13R,Z)-13-((tert-butyldimethylsilyl)oxy)-1-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)-14-iodotetradec-3-en-7-ol

(R)-1-iodohept-6-en-2-ol

(R)-1-iodohept-6-en-2-ol

(7S,13R,Z)-13-((tert-butyldimethylsilyl)oxy)-1-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)-14-iodotetradec-3-en-7-ol

(7S,13R,Z)-13-((tert-butyldimethylsilyl)oxy)-1-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)-14-iodotetradec-3-en-7-ol

(R)-5-((R)-1-hydroxypentadecyl)-dihydrofuran-2(3H)-one

(R)-5-((R)-1-hydroxypentadecyl)-dihydrofuran-2(3H)-one

(7S,13R,Z)-13-((tert-butyldimethylsilyl)oxy)-1-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)-14-iodotetradec-3-en-7-ol

(7S,13R,Z)-13-((tert-butyldimethylsilyl)oxy)-1-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)-14-iodotetradec-3-en-7-ol

(R)-tert-butyl((1-iodohept-6-en-2-yl)oxy)dimethylsilane

(R)-tert-butyl((1-iodohept-6-en-2-yl)oxy)dimethylsilane

(7S,13R,Z)-13-((tert-butyldimethylsilyl)oxy)-1-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)-14-iodotetradec-3-en-7-ol

(7S,13R,Z)-13-((tert-butyldimethylsilyl)oxy)-1-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)-14-iodotetradec-3-en-7-ol

(4R,5R)-nonadecane-1,4,5-triol

(4R,5R)-nonadecane-1,4,5-triol

(7S,13R,Z)-13-((tert-butyldimethylsilyl)oxy)-1-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)-14-iodotetradec-3-en-7-ol

(7S,13R,Z)-13-((tert-butyldimethylsilyl)oxy)-1-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)-14-iodotetradec-3-en-7-ol

heptadec-1-en-3-ol

heptadec-1-en-3-ol

(7S,13R,Z)-13-((tert-butyldimethylsilyl)oxy)-1-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)-14-iodotetradec-3-en-7-ol

(7S,13R,Z)-13-((tert-butyldimethylsilyl)oxy)-1-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)-14-iodotetradec-3-en-7-ol

上游原料

(R)-tert-butyl(1-iodo-7-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)heptan-2-yloxy) dimethylsilane heptadec-1-en-3-ol (R)-1-iodohept-6-en-2-ol (Z)-7-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)hept-4-en-1-yl diisopropylcarbamate (3-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)propyl)triphenyl phosphonium iodide 3-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)propan-1-ol (R)-tert-butyl((1-iodohept-6-en-2-yl)oxy)dimethylsilane (4R,5R)-nonadecane-1,4,5-triol (R)-5-((R)-1-hydroxypentadecyl)-dihydrofuran-2(3H)-one

下游产品

(S)-3-((2R,8S,Z)-2,8-bis((tert-butyldimethylsilyl)oxy)-14-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)tetradec-11-en-1-yl)-5-methylfuran-2(5H)-one (S)-5-methyl-3-((2R,8S,15R,16R,Z)-2,8,15,16-tetrahydroxytriacont-11-en-1-yl)furan-2(5H)-one