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(5R,11R)-5-((Z)-6-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)hex-3-en-1-yl)-11-(iodomethyl)-2,2,3,3,13,13,14,14-octamethyl-4,12-dioxa-3,13-disilapentadecane

CAS号：1449472-08-5

英文名：(5R,11R)-5-((Z)-6-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)hex-3-en-1-yl)-11-(iodomethyl)-2,2,3,3,13,13,14,14-octamethyl-4,12-dioxa-3,13-disilapentadecane

分子式：C45H91IO4Si2

分子量：879.277

合成路线

1449471-84-4

3-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)propan-1-ol

1449472-08-5

(5R,11R)-5-((Z)-6-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)hex-3-en-1-yl)-11-(iodomethyl)-2,2,3,3,13,13,14,14-octamethyl-4,12-dioxa-3,13-disilapentadecane

1449471-82-2

(3-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)propyl)triphenyl phosphonium iodide

1449472-08-5

(5R,11R)-5-((Z)-6-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)hex-3-en-1-yl)-11-(iodomethyl)-2,2,3,3,13,13,14,14-octamethyl-4,12-dioxa-3,13-disilapentadecane

1449471-79-7

(Z)-7-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)hept-4-en-1-yl diisopropylcarbamate

1449472-08-5

(5R,11R)-5-((Z)-6-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)hex-3-en-1-yl)-11-(iodomethyl)-2,2,3,3,13,13,14,14-octamethyl-4,12-dioxa-3,13-disilapentadecane

1449471-90-2

(R)-1-iodohept-6-en-2-ol

1449472-08-5

(5R,11R)-5-((Z)-6-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)hex-3-en-1-yl)-11-(iodomethyl)-2,2,3,3,13,13,14,14-octamethyl-4,12-dioxa-3,13-disilapentadecane

909270-40-2

(R)-5-((R)-1-hydroxypentadecyl)-dihydrofuran-2(3H)-one

1449472-08-5

(5R,11R)-5-((Z)-6-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)hex-3-en-1-yl)-11-(iodomethyl)-2,2,3,3,13,13,14,14-octamethyl-4,12-dioxa-3,13-disilapentadecane

1449471-83-3

(R)-tert-butyl((1-iodohept-6-en-2-yl)oxy)dimethylsilane

1449472-08-5

(5R,11R)-5-((Z)-6-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)hex-3-en-1-yl)-11-(iodomethyl)-2,2,3,3,13,13,14,14-octamethyl-4,12-dioxa-3,13-disilapentadecane

1449471-88-8

(R)-tert-butyl(1-iodo-7-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)heptan-2-yloxy) dimethylsilane

1449472-08-5

(5R,11R)-5-((Z)-6-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)hex-3-en-1-yl)-11-(iodomethyl)-2,2,3,3,13,13,14,14-octamethyl-4,12-dioxa-3,13-disilapentadecane

1449471-85-5

(4R,5R)-nonadecane-1,4,5-triol

1449472-08-5

(5R,11R)-5-((Z)-6-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)hex-3-en-1-yl)-11-(iodomethyl)-2,2,3,3,13,13,14,14-octamethyl-4,12-dioxa-3,13-disilapentadecane

131248-35-6

heptadec-1-en-3-ol

1449472-08-5

(5R,11R)-5-((Z)-6-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)hex-3-en-1-yl)-11-(iodomethyl)-2,2,3,3,13,13,14,14-octamethyl-4,12-dioxa-3,13-disilapentadecane

上游原料

(R)-tert-butyl(1-iodo-7-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)heptan-2-yloxy) dimethylsilane heptadec-1-en-3-ol (R)-1-iodohept-6-en-2-ol (Z)-7-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)hept-4-en-1-yl diisopropylcarbamate (3-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)propyl)triphenyl phosphonium iodide 3-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)propan-1-ol (R)-tert-butyl((1-iodohept-6-en-2-yl)oxy)dimethylsilane (4R,5R)-nonadecane-1,4,5-triol (R)-5-((R)-1-hydroxypentadecyl)-dihydrofuran-2(3H)-one

下游产品

(S)-3-((2R,8R,Z)-2,8-bis((tert-butyldimethylsilyl)oxy)-14-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)tetradec-11-en-1-yl)-5-methylfuran-2(5H)-one