百科

(4S,6R,8S,9R)-6-(tert-butyldimethylsilyloxy)-8-methoxy-9-methyltetradec-1-en-4-ol

(4S,6R,8S,9R)-6-(tert-butyldimethylsilyloxy)-8-methoxy-9-methyltetradec-1-en-4-ol

CAS号：1450838-79-5

英文名：(4S,6R,8S,9R)-6-(tert-butyldimethylsilyloxy)-8-methoxy-9-methyltetradec-1-en-4-ol

分子式：C22H46O3Si

分子量：386.684

合成路线

(2R,3S)-3-methoxy-2-methylhex-5-enyl p-toluenesulfonate

(2R,3S)-3-methoxy-2-methylhex-5-enyl p-toluenesulfonate

(4S,6R,8S,9R)-6-(tert-butyldimethylsilyloxy)-8-methoxy-9-methyltetradec-1-en-4-ol

(4S,6R,8S,9R)-6-(tert-butyldimethylsilyloxy)-8-methoxy-9-methyltetradec-1-en-4-ol

(4S,5R)-4-methoxy-5-methyldec-1-ene

(4S,5R)-4-methoxy-5-methyldec-1-ene

(4S,6R,8S,9R)-6-(tert-butyldimethylsilyloxy)-8-methoxy-9-methyltetradec-1-en-4-ol

(4S,6R,8S,9R)-6-(tert-butyldimethylsilyloxy)-8-methoxy-9-methyltetradec-1-en-4-ol

(4R,6S,7R)-6-methoxy-7-methyldodec-1-en-4-ol

(4R,6S,7R)-6-methoxy-7-methyldodec-1-en-4-ol

(4S,6R,8S,9R)-6-(tert-butyldimethylsilyloxy)-8-methoxy-9-methyltetradec-1-en-4-ol

(4S,6R,8S,9R)-6-(tert-butyldimethylsilyloxy)-8-methoxy-9-methyltetradec-1-en-4-ol

tert-butyl [(4R,6S,7R)-6-methoxy-7-methyldodec-1-en-4-yloxy]dimethylsilane

tert-butyl [(4R,6S,7R)-6-methoxy-7-methyldodec-1-en-4-yloxy]dimethylsilane

(4S,6R,8S,9R)-6-(tert-butyldimethylsilyloxy)-8-methoxy-9-methyltetradec-1-en-4-ol

(4S,6R,8S,9R)-6-(tert-butyldimethylsilyloxy)-8-methoxy-9-methyltetradec-1-en-4-ol

tert-butyl [(2R,3S)-3-methoxy-2-methylhex-5-enyloxy] diphenylsilane

tert-butyl [(2R,3S)-3-methoxy-2-methylhex-5-enyloxy] diphenylsilane

(4S,6R,8S,9R)-6-(tert-butyldimethylsilyloxy)-8-methoxy-9-methyltetradec-1-en-4-ol

(4S,6R,8S,9R)-6-(tert-butyldimethylsilyloxy)-8-methoxy-9-methyltetradec-1-en-4-ol

(2R,3S)-3-methoxy-2-methylhex-5-en-1-ol

(2R,3S)-3-methoxy-2-methylhex-5-en-1-ol

(4S,6R,8S,9R)-6-(tert-butyldimethylsilyloxy)-8-methoxy-9-methyltetradec-1-en-4-ol

(4S,6R,8S,9R)-6-(tert-butyldimethylsilyloxy)-8-methoxy-9-methyltetradec-1-en-4-ol

上游原料

(2R,3S)-3-methoxy-2-methylhex-5-enyl p-toluenesulfonate (4S,5R)-4-methoxy-5-methyldec-1-ene (4R,6S,7R)-6-methoxy-7-methyldodec-1-en-4-ol tert-butyl [(4R,6S,7R)-6-methoxy-7-methyldodec-1-en-4-yloxy]dimethylsilane tert-butyl [(2R,3S)-3-methoxy-2-methylhex-5-enyloxy] diphenylsilane (2R,3S)-3-methoxy-2-methylhex-5-en-1-ol

下游产品

(6S)-6-[(2R,4S,5R)-2-(tert-butyldimethylsilyloxy)-4-methoxy-5-methyldecyl]-5,6-dihydro-2H-pyran-2-one (6S)-6-[(2R,4S,5R)-2-hydroxy-4-methoxy-5-methyldecyl]-5,6-dihydro-2H-pyran-2-one