百科

(4S,6R,8S,9S)-6-(tert-butyldimethylsilyloxy)-8-methoxy-9-methyltetradec-1-en-4-ol

(4S,6R,8S,9S)-6-(tert-butyldimethylsilyloxy)-8-methoxy-9-methyltetradec-1-en-4-ol

CAS号：1450838-87-5

英文名：(4S,6R,8S,9S)-6-(tert-butyldimethylsilyloxy)-8-methoxy-9-methyltetradec-1-en-4-ol

分子式：C22H46O3Si

分子量：386.684

合成路线

(4R)-4-benzyl-3-[(2R,3S,5R)-5-(tert-butyldimethylsilyloxy)-3-methoxy-2-methyloct-7-enoyl]oxazolidin-2-one

(4R)-4-benzyl-3-[(2R,3S,5R)-5-(tert-butyldimethylsilyloxy)-3-methoxy-2-methyloct-7-enoyl]oxazolidin-2-one

(4S,6R,8S,9S)-6-(tert-butyldimethylsilyloxy)-8-methoxy-9-methyltetradec-1-en-4-ol

(4S,6R,8S,9S)-6-(tert-butyldimethylsilyloxy)-8-methoxy-9-methyltetradec-1-en-4-ol

(2S,3S,5R)-5-(tert-butyldimethylsilyloxy)-3-methoxy-2-methyloct-7-en-1-ol

(2S,3S,5R)-5-(tert-butyldimethylsilyloxy)-3-methoxy-2-methyloct-7-en-1-ol

(4S,6R,8S,9S)-6-(tert-butyldimethylsilyloxy)-8-methoxy-9-methyltetradec-1-en-4-ol

(4S,6R,8S,9S)-6-(tert-butyldimethylsilyloxy)-8-methoxy-9-methyltetradec-1-en-4-ol

(2S,3S,5R)-5-(tert-butyldimethylsilyloxy)-3-methoxy-2-methyloct-7-enyl p-toluenesulfonate

(2S,3S,5R)-5-(tert-butyldimethylsilyloxy)-3-methoxy-2-methyloct-7-enyl p-toluenesulfonate

(4S,6R,8S,9S)-6-(tert-butyldimethylsilyloxy)-8-methoxy-9-methyltetradec-1-en-4-ol

(4S,6R,8S,9S)-6-(tert-butyldimethylsilyloxy)-8-methoxy-9-methyltetradec-1-en-4-ol

tert-butyl [(4R,6S,7S)-6-methoxy-7-methyldodec-1-en-4-yloxy]dimethylsilane

tert-butyl [(4R,6S,7S)-6-methoxy-7-methyldodec-1-en-4-yloxy]dimethylsilane

(4S,6R,8S,9S)-6-(tert-butyldimethylsilyloxy)-8-methoxy-9-methyltetradec-1-en-4-ol

(4S,6R,8S,9S)-6-(tert-butyldimethylsilyloxy)-8-methoxy-9-methyltetradec-1-en-4-ol

上游原料

(2S,3S,5R)-5-(tert-butyldimethylsilyloxy)-3-methoxy-2-methyloct-7-enyl p-toluenesulfonate tert-butyl [(4R,6S,7S)-6-methoxy-7-methyldodec-1-en-4-yloxy]dimethylsilane (4R)-4-benzyl-3-[(2R,3S,5R)-5-(tert-butyldimethylsilyloxy)-3-methoxy-2-methyloct-7-enoyl]oxazolidin-2-one (2S,3S,5R)-5-(tert-butyldimethylsilyloxy)-3-methoxy-2-methyloct-7-en-1-ol

下游产品

(6S)-6-[(2R,4S,5S)-2-hydroxy-4-methoxy-5-methyldecyl]-5,6-dihydro-2H-pyran-2-one (6S)-6-[(2R,4S,5S)-2-(tert-butyldimethylsilyloxy)-4-methoxy-5-methyldecyl]-5,6-dihydro-2H-pyran-2-one