百科

(3aS,6aR,7R,8R,9R,9aR,10aR,12R,12aS)-8-((tert-butyldimethylsilyl)oxy)-2,7,10,10,12-pentamethyl-6a,7,9,9a,10,10a,12,12-octahydro-3H,8H-9,12a-methanocyclopenta[1,10]cyclopropa[6,7]cyclodeca[1,2-d][1,3]dioxole-5,13-dione

CAS号：1453221-96-9

英文名：(3aS,6aR,7R,8R,9R,9aR,10aR,12R,12aS)-8-((tert-butyldimethylsilyl)oxy)-2,7,10,10,12-pentamethyl-6a,7,9,9a,10,10a,12,12-octahydro-3H,8H-9,12a-methanocyclopenta[1,10]cyclopropa[6,7]cyclodeca[1,2-d][1,3]dioxole-5,13-dione

分子式：C27H42O5Si

分子量：474.705

上游原料

1453221-98-1

(R)-2-methylpenta-3,4-dien-1-al

1453221-99-2

(1S,3R,6R)-4-chloro-7,7-dimethylbicyclo[4.1.0]heptan-3-one

1453222-01-9

(1R,2R,3R,4R,6R)-3-ethynyl-2-((1R,2R)-1-hydroxy-2-methyl-penta-3,4-dien-1-yl)-4,7,7-trimethylbicyclo[4.1.0]heptan-3-ol

上游原料

(R)-2-methylpenta-3,4-dien-1-al (1S,3R,6R)-4-chloro-7,7-dimethylbicyclo[4.1.0]heptan-3-one (1R,2R,3R,4R,6R)-3-ethynyl-2-((1R,2R)-1-hydroxy-2-methyl-penta-3,4-dien-1-yl)-4,7,7-trimethylbicyclo[4.1.0]heptan-3-ol

下游产品

巨大戟萜醇 (3aR,6aR,7S,8R,8aR,8bR,9aR,11R,11aR,11bR)-11a-hydroxy-2,7,9,9,11-pentamethyl-6a,7,8,8a,8b,9,9a,10,11,11a-decahydro-3H-8,11b-epoxycyclopropa[5',6']benzo[1',2':7,8]azuleno[3a,4-d][1,3]dioxol-5-one (3S,3aS,6aR,7R,8R,9R,9aR,10aR,12R,12aS)-2,7,10,10,12-pentamethyl-5,13-dioxo-8-(((trifluoromethyl)sulfonyl)oxy)-6a,7,9,9a,10,10a,11,12-octahydro-3H,8H-9,12a-methanocyclopenta[1,10]cyclopropa[6,7]cyclodeca[1,2-d][1,3]dioxol-3-yl acetate