百科

(4R,5S)-6-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-4-methylhexan-1-ol

(4R,5S)-6-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-4-methylhexan-1-ol

CAS号：1459835-03-0

英文名：(4R,5S)-6-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-4-methylhexan-1-ol

分子式：C20H36O3Si

分子量：352.584

合成路线

<2S,3S>-3-<<(1,1-dimethylethyl)dimethylsilyl>oxy>-2-methyl-4-(phenylmethoxy)butanal

<2S,3S>-3-<<(1,1-dimethylethyl)dimethylsilyl>oxy>-2-methyl-4-(phenylmethoxy)butanal

(4R,5S)-6-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-4-methylhexan-1-ol

(4R,5S)-6-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-4-methylhexan-1-ol

<2S,3S>-3-<<<(1,1-dimethylethyl)dimethylsilyl>oxy>-N-methoxy>-N,2-dimethyl-4-phenylmethoxybutanamide

<2S,3S>-3-<<<(1,1-dimethylethyl)dimethylsilyl>oxy>-N-methoxy>-N,2-dimethyl-4-phenylmethoxybutanamide

(4R,5S)-6-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-4-methylhexan-1-ol

(4R,5S)-6-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-4-methylhexan-1-ol

(2S,3S)-4-(benzyloxy)-3-hydroxy-N-methoxy-N,2-dimethylbutanamide

(2S,3S)-4-(benzyloxy)-3-hydroxy-N-methoxy-N,2-dimethylbutanamide

(4R,5S)-6-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-4-methylhexan-1-ol

(4R,5S)-6-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-4-methylhexan-1-ol

上游原料

(2S,3S)-4-(benzyloxy)-3-hydroxy-N-methoxy-N,2-dimethylbutanamide <2S,3S>-3-<<(1,1-dimethylethyl)dimethylsilyl>oxy>-2-methyl-4-(phenylmethoxy)butanal <2S,3S>-3-<<<(1,1-dimethylethyl)dimethylsilyl>oxy>-N-methoxy>-N,2-dimethyl-4-phenylmethoxybutanamide

下游产品

((2S,3S,5R,6S)-2-(azidomethyl)-6-(benzyloxymethyl)-5-methyltetrahydro-2H-pyran-3-yloxy)(tert-butyl)dimethylsilane (3R,5R,6S)-7-(benzyloxy)-6-(tert-butyldimethylsilyloxy)-5-methylhept-1-en-3-ol ((2R,3R,5R,6S)-2-(azidomethyl)-6-(benzyloxymethyl)-5-methyltetrahydro-2H-pyran-3-yloxy)(tert-butyl)dimethylsilane (2S,3S,5R,6S)-2-(azidomethyl)-6-(benzyloxymethyl)-5-methyltetrahydro-2H-pyran-3-ol ((2S,3R)-1-(benzyloxy)-3-methyl-4-((S)-oxiran-2-yl)butan-2-yloxy)-(tert-butyl)dimethylsilane (2R,3S,5R,6S)-6-(benzyloxymethyl)-2-(iodomethyl)-5-methyltetrahydro-2-pyran-3-ol ((2S,3R)-1-(benzyloxy)-3-methyl-4-((R)-oxiran-2-yl)butan-2-yloxy)-(tert-butyl)dimethylsilane (2S,3R,5S)-1-(benzyloxy)-3-methylhept-6-ene-2,5-diol N-(((2S,3R,5R,6S)-3-(tert-butyldimethylsilyloxy)-6-(hydroxymethyl)-5-methyltetrahydro-2H-pyran-2-yl)methyl)acetamide ((3R,5R,6S)-6-((benzyloxy)methyl)tetrahydro-5-methyl-2-methylene-2H-pyran-3-yloxy)(tert-butyl)dimethylsilane (2R,3R,5R,6S)-2-(azidomethyl)-6-(benzyloxymethyl)-5-methyltetrahydro-2H-pyran-3-ol ((2S,3R,5R,6S)-6-((benzyloxy)methyl)tetrahydro-2-(iodomethyl)-5-methyl-2H-pyran-3-yloxy)(tert-butyl)dimethylsilane (2S,3R,5R,6S)-6-((benzyloxy)methyl)tetrahydro-2-(iodomethyl)-5-methyl-2H-pyran-3-ol N-(((2S,3S,5R,6S)-3-(tert-butyldimethylsilyloxy)-6-(hydroxymethyl)-5-methyltetrahydro-2H-pyran-2-yl)methyl)acetamide (2S,3R,5R)-1-(benzyloxy)-3-methylhept-6-ene-2,5-diol ((2S,3R,5R,6S)-6-(benzyloxymethyl)-3-(tert-butyldimethylsilyloxy)-5-methyltetrahydro-2H-pyran-2-yl)methanol ((2R,3R,5R,6S)-2-(azidomethyl)-6-((benzyloxy)methyl)tetrahydro-5-methyl-2H-pyran-3-yloxy)(tert-butyl)dimethylsilane (3S,5R,6S)-7-(benzyloxy)-6-(tert-butyldimethylsilyloxy)-5-methylhept-1-en-3-ol N-(((2R,3R,5R,6S)-3-(tert-butyldimethylsilyloxy)-6-(hydroxymethyl)-5-methyltetrahydro-2H-pyran-2-yl)methyl)acetamide