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((2S,3S,5R,6S)-2-(azidomethyl)-6-(benzyloxymethyl)-5-methyltetrahydro-2H-pyran-3-yloxy)(tert-butyl)dimethylsilane

((2S,3S,5R,6S)-2-(azidomethyl)-6-(benzyloxymethyl)-5-methyltetrahydro-2H-pyran-3-yloxy)(tert-butyl)dimethylsilane

CAS号：1459835-16-5

英文名：((2S,3S,5R,6S)-2-(azidomethyl)-6-(benzyloxymethyl)-5-methyltetrahydro-2H-pyran-3-yloxy)(tert-butyl)dimethylsilane

分子式：C21H35N3O3Si

分子量：405.606

合成路线

(4R,5S)-6-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-4-methylhexan-1-ol

(4R,5S)-6-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-4-methylhexan-1-ol

((2S,3S,5R,6S)-2-(azidomethyl)-6-(benzyloxymethyl)-5-methyltetrahydro-2H-pyran-3-yloxy)(tert-butyl)dimethylsilane

((2S,3S,5R,6S)-2-(azidomethyl)-6-(benzyloxymethyl)-5-methyltetrahydro-2H-pyran-3-yloxy)(tert-butyl)dimethylsilane

((2S,3R)-1-(benzyloxy)-3-methyl-4-((R)-oxiran-2-yl)butan-2-yloxy)-(tert-butyl)dimethylsilane

((2S,3R)-1-(benzyloxy)-3-methyl-4-((R)-oxiran-2-yl)butan-2-yloxy)-(tert-butyl)dimethylsilane

((2S,3S,5R,6S)-2-(azidomethyl)-6-(benzyloxymethyl)-5-methyltetrahydro-2H-pyran-3-yloxy)(tert-butyl)dimethylsilane

((2S,3S,5R,6S)-2-(azidomethyl)-6-(benzyloxymethyl)-5-methyltetrahydro-2H-pyran-3-yloxy)(tert-butyl)dimethylsilane

<2S,3S>-3-<<(1,1-dimethylethyl)dimethylsilyl>oxy>-2-methyl-4-(phenylmethoxy)butanal

<2S,3S>-3-<<(1,1-dimethylethyl)dimethylsilyl>oxy>-2-methyl-4-(phenylmethoxy)butanal

((2S,3S,5R,6S)-2-(azidomethyl)-6-(benzyloxymethyl)-5-methyltetrahydro-2H-pyran-3-yloxy)(tert-butyl)dimethylsilane

((2S,3S,5R,6S)-2-(azidomethyl)-6-(benzyloxymethyl)-5-methyltetrahydro-2H-pyran-3-yloxy)(tert-butyl)dimethylsilane

<2S,3S>-3-<<<(1,1-dimethylethyl)dimethylsilyl>oxy>-N-methoxy>-N,2-dimethyl-4-phenylmethoxybutanamide

<2S,3S>-3-<<<(1,1-dimethylethyl)dimethylsilyl>oxy>-N-methoxy>-N,2-dimethyl-4-phenylmethoxybutanamide

((2S,3S,5R,6S)-2-(azidomethyl)-6-(benzyloxymethyl)-5-methyltetrahydro-2H-pyran-3-yloxy)(tert-butyl)dimethylsilane

((2S,3S,5R,6S)-2-(azidomethyl)-6-(benzyloxymethyl)-5-methyltetrahydro-2H-pyran-3-yloxy)(tert-butyl)dimethylsilane

(3S,5R,6S)-7-(benzyloxy)-6-(tert-butyldimethylsilyloxy)-5-methylhept-1-en-3-ol

(3S,5R,6S)-7-(benzyloxy)-6-(tert-butyldimethylsilyloxy)-5-methylhept-1-en-3-ol

((2S,3S,5R,6S)-2-(azidomethyl)-6-(benzyloxymethyl)-5-methyltetrahydro-2H-pyran-3-yloxy)(tert-butyl)dimethylsilane

((2S,3S,5R,6S)-2-(azidomethyl)-6-(benzyloxymethyl)-5-methyltetrahydro-2H-pyran-3-yloxy)(tert-butyl)dimethylsilane

(2S,3R,5S)-1-(benzyloxy)-3-methylhept-6-ene-2,5-diol

(2S,3R,5S)-1-(benzyloxy)-3-methylhept-6-ene-2,5-diol

((2S,3S,5R,6S)-2-(azidomethyl)-6-(benzyloxymethyl)-5-methyltetrahydro-2H-pyran-3-yloxy)(tert-butyl)dimethylsilane

((2S,3S,5R,6S)-2-(azidomethyl)-6-(benzyloxymethyl)-5-methyltetrahydro-2H-pyran-3-yloxy)(tert-butyl)dimethylsilane

(2R,3S,5R,6S)-6-(benzyloxymethyl)-2-(iodomethyl)-5-methyltetrahydro-2-pyran-3-ol

(2R,3S,5R,6S)-6-(benzyloxymethyl)-2-(iodomethyl)-5-methyltetrahydro-2-pyran-3-ol

((2S,3S,5R,6S)-2-(azidomethyl)-6-(benzyloxymethyl)-5-methyltetrahydro-2H-pyran-3-yloxy)(tert-butyl)dimethylsilane

((2S,3S,5R,6S)-2-(azidomethyl)-6-(benzyloxymethyl)-5-methyltetrahydro-2H-pyran-3-yloxy)(tert-butyl)dimethylsilane

(2S,3S)-4-(benzyloxy)-3-hydroxy-N-methoxy-N,2-dimethylbutanamide

(2S,3S)-4-(benzyloxy)-3-hydroxy-N-methoxy-N,2-dimethylbutanamide

((2S,3S,5R,6S)-2-(azidomethyl)-6-(benzyloxymethyl)-5-methyltetrahydro-2H-pyran-3-yloxy)(tert-butyl)dimethylsilane

((2S,3S,5R,6S)-2-(azidomethyl)-6-(benzyloxymethyl)-5-methyltetrahydro-2H-pyran-3-yloxy)(tert-butyl)dimethylsilane

上游原料

(2S,3S)-4-(benzyloxy)-3-hydroxy-N-methoxy-N,2-dimethylbutanamide <2S,3S>-3-<<(1,1-dimethylethyl)dimethylsilyl>oxy>-2-methyl-4-(phenylmethoxy)butanal (2R,3S,5R,6S)-6-(benzyloxymethyl)-2-(iodomethyl)-5-methyltetrahydro-2-pyran-3-ol ((2S,3R)-1-(benzyloxy)-3-methyl-4-((R)-oxiran-2-yl)butan-2-yloxy)-(tert-butyl)dimethylsilane <2S,3S>-3-<<<(1,1-dimethylethyl)dimethylsilyl>oxy>-N-methoxy>-N,2-dimethyl-4-phenylmethoxybutanamide (2S,3R,5S)-1-(benzyloxy)-3-methylhept-6-ene-2,5-diol (4R,5S)-6-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-4-methylhexan-1-ol (3S,5R,6S)-7-(benzyloxy)-6-(tert-butyldimethylsilyloxy)-5-methylhept-1-en-3-ol

下游产品

N-(((2S,3S,5R,6S)-3-(tert-butyldimethylsilyloxy)-6-(hydroxymethyl)-5-methyltetrahydro-2H-pyran-2-yl)methyl)acetamide