百科

N6-benzoyl-3'-(<(tert-butyl)diphenylsilyloxy>methyl)-2',3',5'-trideoxy-5'-<(tritylthio)methyl>-1'a-carbaadenosine

N6-benzoyl-3'-(<(tert-butyl)diphenylsilyloxy>methyl)-2',3',5'-trideoxy-5'-<(tritylthio)methyl>-1'a-carbaadenosine

CAS号：149551-10-0

英文名：N6-benzoyl-3'-(<(tert-butyl)diphenylsilyloxy>methyl)-2',3',5'-trideoxy-5'-<(tritylthio)methyl>-1'a-carbaadenosine

分子式：C55H55N5O2SSi

分子量：878.208

合成路线

5-降冰片烯-2-甲醇

5-降冰片烯-2-甲醇

N6-benzoyl-3'-(<(tert-butyl)diphenylsilyloxy>methyl)-2',3',5'-trideoxy-5'-<(tritylthio)methyl>-1'a-carbaadenosine

N6-benzoyl-3'-(<(tert-butyl)diphenylsilyloxy>methyl)-2',3',5'-trideoxy-5'-<(tritylthio)methyl>-1'a-carbaadenosine

methyl (1R,2S,4S)-2-(<(tert-butyl)diphenylsilyloxy>methyl)-4-hydroxycyclopentaneacetate

methyl (1R,2S,4S)-2-(<(tert-butyl)diphenylsilyloxy>methyl)-4-hydroxycyclopentaneacetate

N6-benzoyl-3'-(<(tert-butyl)diphenylsilyloxy>methyl)-2',3',5'-trideoxy-5'-<(tritylthio)methyl>-1'a-carbaadenosine

N6-benzoyl-3'-(<(tert-butyl)diphenylsilyloxy>methyl)-2',3',5'-trideoxy-5'-<(tritylthio)methyl>-1'a-carbaadenosine

(1R,4R,5S)-5-(<(tert-butyl)diphenylsilyloxy>methyl)bicyclo<2.2.1>heptan-2-one

(1R,4R,5S)-5-(<(tert-butyl)diphenylsilyloxy>methyl)bicyclo<2.2.1>heptan-2-one

N6-benzoyl-3'-(<(tert-butyl)diphenylsilyloxy>methyl)-2',3',5'-trideoxy-5'-<(tritylthio)methyl>-1'a-carbaadenosine

N6-benzoyl-3'-(<(tert-butyl)diphenylsilyloxy>methyl)-2',3',5'-trideoxy-5'-<(tritylthio)methyl>-1'a-carbaadenosine

(1R,5R,6S)-6-(<(tert-butyl)diphenylsilyloxy>methyl)-2-oxabicyclo<3.2.1>octan-3-one

(1R,5R,6S)-6-(<(tert-butyl)diphenylsilyloxy>methyl)-2-oxabicyclo<3.2.1>octan-3-one

N6-benzoyl-3'-(<(tert-butyl)diphenylsilyloxy>methyl)-2',3',5'-trideoxy-5'-<(tritylthio)methyl>-1'a-carbaadenosine

N6-benzoyl-3'-(<(tert-butyl)diphenylsilyloxy>methyl)-2',3',5'-trideoxy-5'-<(tritylthio)methyl>-1'a-carbaadenosine

methyl (1R,2S,4S)-2-(<(tert-butyl)diphenylsilyloxy>methyl)-4-(formyloxy)cyclopentaneacetate

methyl (1R,2S,4S)-2-(<(tert-butyl)diphenylsilyloxy>methyl)-4-(formyloxy)cyclopentaneacetate

N6-benzoyl-3'-(<(tert-butyl)diphenylsilyloxy>methyl)-2',3',5'-trideoxy-5'-<(tritylthio)methyl>-1'a-carbaadenosine

N6-benzoyl-3'-(<(tert-butyl)diphenylsilyloxy>methyl)-2',3',5'-trideoxy-5'-<(tritylthio)methyl>-1'a-carbaadenosine

methyl (1R,2S,4R)-2-(<(tert-butyl)diphenylsilyloxy>methyl)-4-hydroxycyclopentaneacetate

methyl (1R,2S,4R)-2-(<(tert-butyl)diphenylsilyloxy>methyl)-4-hydroxycyclopentaneacetate

N6-benzoyl-3'-(<(tert-butyl)diphenylsilyloxy>methyl)-2',3',5'-trideoxy-5'-<(tritylthio)methyl>-1'a-carbaadenosine

N6-benzoyl-3'-(<(tert-butyl)diphenylsilyloxy>methyl)-2',3',5'-trideoxy-5'-<(tritylthio)methyl>-1'a-carbaadenosine

上游原料

methyl (1R,2S,4R)-2-(<(tert-butyl)diphenylsilyloxy>methyl)-4-hydroxycyclopentaneacetate (1R,4R,5S)-5-(<(tert-butyl)diphenylsilyloxy>methyl)bicyclo<2.2.1>heptan-2-one methyl (1R,2S,4S)-2-(<(tert-butyl)diphenylsilyloxy>methyl)-4-(formyloxy)cyclopentaneacetate methyl (1R,2S,4S)-2-(<(tert-butyl)diphenylsilyloxy>methyl)-4-hydroxycyclopentaneacetate 5-降冰片烯-2-甲醇 (1R,5R,6S)-6-(<(tert-butyl)diphenylsilyloxy>methyl)-2-oxabicyclo<3.2.1>octan-3-one

下游产品

N6-benzoyl-2',3',5'-trideoxy-3'-(hydroxymethyl)-5'-<(tritylthio)methyl>-1'a-carbaadenosine N6-benzoyl-2',3',5'-trideoxy-3'-<(methylsulfonyloxy)methyl>-5'-<(tritylthio)methyl>-1'a-carbaadenosine