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methyl (6S,7S,10R)-(2E,4E)-7-(-tert-butyldimethylsilyloxy)-4,6,10-trimethyl-2,4-dodecadienoate

methyl (6S,7S,10R)-(2E,4E)-7-(-tert-butyldimethylsilyloxy)-4,6,10-trimethyl-2,4-dodecadienoate

CAS号：150338-65-1

英文名：methyl (6S,7S,10R)-(2E,4E)-7-(-tert-butyldimethylsilyloxy)-4,6,10-trimethyl-2,4-dodecadienoate

分子式：C22H42O3Si

分子量：382.653

合成路线

(R)-(-)-2,6-dimethyl-2-octen-1-ol

(R)-(-)-2,6-dimethyl-2-octen-1-ol

methyl (6S,7S,10R)-(2E,4E)-7-(-tert-butyldimethylsilyloxy)-4,6,10-trimethyl-2,4-dodecadienoate

methyl (6S,7S,10R)-(2E,4E)-7-(-tert-butyldimethylsilyloxy)-4,6,10-trimethyl-2,4-dodecadienoate

(2S,3S,6R)-2,3-epoxy-2,6-dimethyloctan-1-ol

(2S,3S,6R)-2,3-epoxy-2,6-dimethyloctan-1-ol

methyl (6S,7S,10R)-(2E,4E)-7-(-tert-butyldimethylsilyloxy)-4,6,10-trimethyl-2,4-dodecadienoate

methyl (6S,7S,10R)-(2E,4E)-7-(-tert-butyldimethylsilyloxy)-4,6,10-trimethyl-2,4-dodecadienoate

ethyl (4S,5S,8R)-(E)-5-hydroxy-2,4,8-trimethyl-2-decenoate

ethyl (4S,5S,8R)-(E)-5-hydroxy-2,4,8-trimethyl-2-decenoate

methyl (6S,7S,10R)-(2E,4E)-7-(-tert-butyldimethylsilyloxy)-4,6,10-trimethyl-2,4-dodecadienoate

methyl (6S,7S,10R)-(2E,4E)-7-(-tert-butyldimethylsilyloxy)-4,6,10-trimethyl-2,4-dodecadienoate

(2S,3S,6R)-2,3-epoxy-2,6-dimethyloctanal

(2S,3S,6R)-2,3-epoxy-2,6-dimethyloctanal

methyl (6S,7S,10R)-(2E,4E)-7-(-tert-butyldimethylsilyloxy)-4,6,10-trimethyl-2,4-dodecadienoate

methyl (6S,7S,10R)-(2E,4E)-7-(-tert-butyldimethylsilyloxy)-4,6,10-trimethyl-2,4-dodecadienoate

ethyl (4S,5S,8R)-(E)-4,5-epoxy-2,4,8-trimethyl-2-decenoate

ethyl (4S,5S,8R)-(E)-4,5-epoxy-2,4,8-trimethyl-2-decenoate

methyl (6S,7S,10R)-(2E,4E)-7-(-tert-butyldimethylsilyloxy)-4,6,10-trimethyl-2,4-dodecadienoate

methyl (6S,7S,10R)-(2E,4E)-7-(-tert-butyldimethylsilyloxy)-4,6,10-trimethyl-2,4-dodecadienoate

ethyl (4S,5S,8R)-(E)-5-(tert-butyldimethylsilyloxy)-2,4,8-trimethyl-2-decenoate

ethyl (4S,5S,8R)-(E)-5-(tert-butyldimethylsilyloxy)-2,4,8-trimethyl-2-decenoate

methyl (6S,7S,10R)-(2E,4E)-7-(-tert-butyldimethylsilyloxy)-4,6,10-trimethyl-2,4-dodecadienoate

methyl (6S,7S,10R)-(2E,4E)-7-(-tert-butyldimethylsilyloxy)-4,6,10-trimethyl-2,4-dodecadienoate

(4S,5S,8R)-(E)-5-(tert-butyldimethylsilyloxy)-2,4,8-trimethyl-2-decen-1-ol

(4S,5S,8R)-(E)-5-(tert-butyldimethylsilyloxy)-2,4,8-trimethyl-2-decen-1-ol

methyl (6S,7S,10R)-(2E,4E)-7-(-tert-butyldimethylsilyloxy)-4,6,10-trimethyl-2,4-dodecadienoate

methyl (6S,7S,10R)-(2E,4E)-7-(-tert-butyldimethylsilyloxy)-4,6,10-trimethyl-2,4-dodecadienoate

上游原料

ethyl (4S,5S,8R)-(E)-4,5-epoxy-2,4,8-trimethyl-2-decenoate ethyl (4S,5S,8R)-(E)-5-hydroxy-2,4,8-trimethyl-2-decenoate (4S,5S,8R)-(E)-5-(tert-butyldimethylsilyloxy)-2,4,8-trimethyl-2-decen-1-ol (2S,3S,6R)-2,3-epoxy-2,6-dimethyloctan-1-ol (2S,3S,6R)-2,3-epoxy-2,6-dimethyloctanal (R)-(-)-2,6-dimethyl-2-octen-1-ol ethyl (4S,5S,8R)-(E)-5-(tert-butyldimethylsilyloxy)-2,4,8-trimethyl-2-decenoate

下游产品

(6S,7S,10R)-(2E,4E)-7-(-tert-butyldimethylsilyloxy)-4,6,10-trimethyl-2,4-dodecadien-1-ol