百科

(2R,3S,4S,5S)-2,3-Bis-(tert-butyl-dimethyl-silanyloxy)-5-[(4S,5S)-5-(tert-butyl-dimethyl-silanyloxymethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-4,5-dihydroxy-pentanal

(2R,3S,4S,5S)-2,3-Bis-(tert-butyl-dimethyl-silanyloxy)-5-[(4S,5S)-5-(tert-butyl-dimethyl-silanyloxymethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-4,5-dihydroxy-pentanal

CAS号：151265-97-3

英文名：(2R,3S,4S,5S)-2,3-Bis-(tert-butyl-dimethyl-silanyloxy)-5-[(4S,5S)-5-(tert-butyl-dimethyl-silanyloxymethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-4,5-dihydroxy-pentanal

分子式：C29H62O8Si3

分子量：623.054

合成路线

(2R,3S,4S,5R,6R,7R,8R,9S)-4,5,10-Tris<(tert-butyldimethylsilyl)oxy>-8,9-O-(1-methylethylidene)-2,3,6,7-decanetetrol

(2R,3S,4S,5R,6R,7R,8R,9S)-4,5,10-Tris<(tert-butyldimethylsilyl)oxy>-8,9-O-(1-methylethylidene)-2,3,6,7-decanetetrol

(2R,3S,4S,5S)-2,3-Bis-(tert-butyl-dimethyl-silanyloxy)-5-[(4S,5S)-5-(tert-butyl-dimethyl-silanyloxymethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-4,5-dihydroxy-pentanal

(2R,3S,4S,5S)-2,3-Bis-(tert-butyl-dimethyl-silanyloxy)-5-[(4S,5S)-5-(tert-butyl-dimethyl-silanyloxymethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-4,5-dihydroxy-pentanal

(E)-(4S,5S)-Ethyl 6-<(tert-butyldimethylsilyl)oxy>-4,5-O-(1-methylethylidene)-2-hexenoate

(E)-(4S,5S)-Ethyl 6-<(tert-butyldimethylsilyl)oxy>-4,5-O-(1-methylethylidene)-2-hexenoate

(2R,3S,4S,5S)-2,3-Bis-(tert-butyl-dimethyl-silanyloxy)-5-[(4S,5S)-5-(tert-butyl-dimethyl-silanyloxymethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-4,5-dihydroxy-pentanal

(2R,3S,4S,5S)-2,3-Bis-(tert-butyl-dimethyl-silanyloxy)-5-[(4S,5S)-5-(tert-butyl-dimethyl-silanyloxymethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-4,5-dihydroxy-pentanal

(E)-(4S,5S)-6-<(tert-Butyldimethylsilyl)oxy>-4,5-O-(1-methylethylidene)-2-hexenal

(E)-(4S,5S)-6-<(tert-Butyldimethylsilyl)oxy>-4,5-O-(1-methylethylidene)-2-hexenal

(2R,3S,4S,5S)-2,3-Bis-(tert-butyl-dimethyl-silanyloxy)-5-[(4S,5S)-5-(tert-butyl-dimethyl-silanyloxymethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-4,5-dihydroxy-pentanal

(2R,3S,4S,5S)-2,3-Bis-(tert-butyl-dimethyl-silanyloxy)-5-[(4S,5S)-5-(tert-butyl-dimethyl-silanyloxymethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-4,5-dihydroxy-pentanal

上游原料

(E)-(4S,5S)-Ethyl 6-<(tert-butyldimethylsilyl)oxy>-4,5-O-(1-methylethylidene)-2-hexenoate (2R,3S,4S,5R,6R,7R,8R,9S)-4,5,10-Tris<(tert-butyldimethylsilyl)oxy>-8,9-O-(1-methylethylidene)-2,3,6,7-decanetetrol (E)-(4S,5S)-6-<(tert-Butyldimethylsilyl)oxy>-4,5-O-(1-methylethylidene)-2-hexenal

下游产品

(2R,3S,4S,5R,6R,7S)-2,3,8-Tris<(tert-butyldimethylsilyl)oxy>-6,7-O-(1-methylethylidene)-5-hydroxyoctanoic acid γ-lactone