百科

(E)-(3S,4S,7S,8R)-1,8-Bis-(tert-butyl-diphenyl-silanyloxy)-4-(4-methoxy-benzyloxy)-3,7,9-trimethyl-undec-9-en-5-one

(E)-(3S,4S,7S,8R)-1,8-Bis-(tert-butyl-diphenyl-silanyloxy)-4-(4-methoxy-benzyloxy)-3,7,9-trimethyl-undec-9-en-5-one

CAS号：152300-65-7

英文名：(E)-(3S,4S,7S,8R)-1,8-Bis-(tert-butyl-diphenyl-silanyloxy)-4-(4-methoxy-benzyloxy)-3,7,9-trimethyl-undec-9-en-5-one

分子式：C54H70O5Si2

分子量：855.302

合成路线

(4R,5S,2'R,3'R,4'E)-3-(2',4'-dimethyl-3'-hydroxy-1'-oxo-4'-hexenyl)-4-methyl-5-phenyl-2-oxazolidinone

(4R,5S,2'R,3'R,4'E)-3-(2',4'-dimethyl-3'-hydroxy-1'-oxo-4'-hexenyl)-4-methyl-5-phenyl-2-oxazolidinone

(E)-(3S,4S,7S,8R)-1,8-Bis-(tert-butyl-diphenyl-silanyloxy)-4-(4-methoxy-benzyloxy)-3,7,9-trimethyl-undec-9-en-5-one

(E)-(3S,4S,7S,8R)-1,8-Bis-(tert-butyl-diphenyl-silanyloxy)-4-(4-methoxy-benzyloxy)-3,7,9-trimethyl-undec-9-en-5-one

(2S,3S)-5-(tert-Butyl-diphenyl-silanyloxy)-2-(4-methoxy-benzyloxy)-3-methyl-pentan-1-ol

(2S,3S)-5-(tert-Butyl-diphenyl-silanyloxy)-2-(4-methoxy-benzyloxy)-3-methyl-pentan-1-ol

(E)-(3S,4S,7S,8R)-1,8-Bis-(tert-butyl-diphenyl-silanyloxy)-4-(4-methoxy-benzyloxy)-3,7,9-trimethyl-undec-9-en-5-one

(E)-(3S,4S,7S,8R)-1,8-Bis-(tert-butyl-diphenyl-silanyloxy)-4-(4-methoxy-benzyloxy)-3,7,9-trimethyl-undec-9-en-5-one

[(E)-(R)-1-((R)-2-Benzenesulfonyl-1-methyl-ethyl)-2-methyl-but-2-enyloxy]-tert-butyl-diphenyl-silane

[(E)-(R)-1-((R)-2-Benzenesulfonyl-1-methyl-ethyl)-2-methyl-but-2-enyloxy]-tert-butyl-diphenyl-silane

(E)-(3S,4S,7S,8R)-1,8-Bis-(tert-butyl-diphenyl-silanyloxy)-4-(4-methoxy-benzyloxy)-3,7,9-trimethyl-undec-9-en-5-one

(E)-(3S,4S,7S,8R)-1,8-Bis-(tert-butyl-diphenyl-silanyloxy)-4-(4-methoxy-benzyloxy)-3,7,9-trimethyl-undec-9-en-5-one

上游原料

(4R,5S,2'R,3'R,4'E)-3-(2',4'-dimethyl-3'-hydroxy-1'-oxo-4'-hexenyl)-4-methyl-5-phenyl-2-oxazolidinone (2S,3S)-5-(tert-Butyl-diphenyl-silanyloxy)-2-(4-methoxy-benzyloxy)-3-methyl-pentan-1-ol [(E)-(R)-1-((R)-2-Benzenesulfonyl-1-methyl-ethyl)-2-methyl-but-2-enyloxy]-tert-butyl-diphenyl-silane

下游产品

[(E)-(1R,2S,5S,6S)-8-Benzenesulfonyl-5-(4-methoxy-benzyloxy)-2,4,6-trimethyl-1-((E)-1-methyl-propenyl)-oct-3-enyloxy]-tert-butyl-diphenyl-silane (5E,9E)-(3S,4S,7S,8R)-8-(tert-Butyl-diphenyl-silanyloxy)-4-(4-methoxy-benzyloxy)-3,5,7,9-tetramethyl-undeca-5,9-dien-1-ol 1-{(2E,6E)-(1S,4S,5R)-5-(tert-Butyl-diphenyl-silanyloxy)-1-[(S)-3-(tert-butyl-diphenyl-silanyloxy)-1-methyl-propyl]-2,4,6-trimethyl-octa-2,6-dienyloxymethyl}-4-methoxy-benzene