百科

Acetic acid (2S,3R,4R,5S,6S)-4-allyloxy-5-benzyloxy-2-((2R,3R,4S,5R,6R)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-4-yloxy)-6-methyl-tetrahydro-pyran-3-yl ester

Acetic acid (2S,3R,4R,5S,6S)-4-allyloxy-5-benzyloxy-2-((2R,3R,4S,5R,6R)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-4-yloxy)-6-methyl-tetrahydro-pyran-3-yl ester

CAS号：152338-98-2

英文名：Acetic acid (2S,3R,4R,5S,6S)-4-allyloxy-5-benzyloxy-2-((2R,3R,4S,5R,6R)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-4-yloxy)-6-methyl-tetrahydro-pyran-3-yl ester

分子式：C46H54O11

分子量：782.914

合成路线

1,2-di-O-acetyl-3-O-allyl-4-O-benzyl-α-L-rhamnopyranose

1,2-di-O-acetyl-3-O-allyl-4-O-benzyl-α-L-rhamnopyranose

Acetic acid (2S,3R,4R,5S,6S)-4-allyloxy-5-benzyloxy-2-((2R,3R,4S,5R,6R)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-4-yloxy)-6-methyl-tetrahydro-pyran-3-yl ester

Acetic acid (2S,3R,4R,5S,6S)-4-allyloxy-5-benzyloxy-2-((2R,3R,4S,5R,6R)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-4-yloxy)-6-methyl-tetrahydro-pyran-3-yl ester

Acetic acid (2R,3R,4R,5S,6S)-4-allyloxy-5-benzyloxy-2-hydroxy-6-methyl-tetrahydro-pyran-3-yl ester

Acetic acid (2R,3R,4R,5S,6S)-4-allyloxy-5-benzyloxy-2-hydroxy-6-methyl-tetrahydro-pyran-3-yl ester

Acetic acid (2S,3R,4R,5S,6S)-4-allyloxy-5-benzyloxy-2-((2R,3R,4S,5R,6R)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-4-yloxy)-6-methyl-tetrahydro-pyran-3-yl ester

Acetic acid (2S,3R,4R,5S,6S)-4-allyloxy-5-benzyloxy-2-((2R,3R,4S,5R,6R)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-4-yloxy)-6-methyl-tetrahydro-pyran-3-yl ester

上游原料

Acetic acid (2R,3R,4R,5S,6S)-4-allyloxy-5-benzyloxy-2-hydroxy-6-methyl-tetrahydro-pyran-3-yl ester 1,2-di-O-acetyl-3-O-allyl-4-O-benzyl-α-L-rhamnopyranose

下游产品

methyl 3-O-(3-O-β-D-glucopyranosyl-α-L-rhamnopyranosyl)-β-D-glucopyranoside (2S,3R,4S,5S,6R)-2-[(2S,3R,4R,5S,6S)-3,5-Bis-benzyloxy-2-((2R,3R,4S,5R,6R)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-4-yloxy)-6-methyl-tetrahydro-pyran-4-yloxy]-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol methyl 2,4,6-tri-O-benzyl-3-O-(2,4-di-O-benzyl-α-L-rhamnopyranosyl)-β-D-glucopyranoside