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(2S,3R,7S,8S)-8-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-3,5,7-trimethyl-decane-4,6-dione

(2S,3R,7S,8S)-8-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-3,5,7-trimethyl-decane-4,6-dione

CAS号：152428-79-0

英文名：(2S,3R,7S,8S)-8-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-3,5,7-trimethyl-decane-4,6-dione

分子式：C26H44O4Si

分子量：448.711

合成路线

(2S,3R,4S)-4-Benzyloxy-3-methyl-hexan-2-ol

(2S,3R,4S)-4-Benzyloxy-3-methyl-hexan-2-ol

(2S,3R,7S,8S)-8-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-3,5,7-trimethyl-decane-4,6-dione

(2S,3R,7S,8S)-8-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-3,5,7-trimethyl-decane-4,6-dione

((1S,2S,3S)-3-Benzyloxy-1,2-dimethyl-pentyloxy)-tert-butyl-dimethyl-silane

((1S,2S,3S)-3-Benzyloxy-1,2-dimethyl-pentyloxy)-tert-butyl-dimethyl-silane

(2S,3R,7S,8S)-8-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-3,5,7-trimethyl-decane-4,6-dione

(2S,3R,7S,8S)-8-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-3,5,7-trimethyl-decane-4,6-dione

(4R,5S)-5-t-butyldimethylsilyloxy-4-methylhexan-3-one

(4R,5S)-5-t-butyldimethylsilyloxy-4-methylhexan-3-one

(2S,3R,7S,8S)-8-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-3,5,7-trimethyl-decane-4,6-dione

(2S,3R,7S,8S)-8-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-3,5,7-trimethyl-decane-4,6-dione

(3S,4S,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-hexan-3-ol

(3S,4S,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-hexan-3-ol

(2S,3R,7S,8S)-8-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-3,5,7-trimethyl-decane-4,6-dione

(2S,3R,7S,8S)-8-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-3,5,7-trimethyl-decane-4,6-dione

上游原料

(4R,5S)-5-t-butyldimethylsilyloxy-4-methylhexan-3-one (2S,3R,4S)-4-Benzyloxy-3-methyl-hexan-2-ol ((1S,2S,3S)-3-Benzyloxy-1,2-dimethyl-pentyloxy)-tert-butyl-dimethyl-silane (3S,4S,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-hexan-3-ol

下游产品

(2S,3R,1'S)-epi-stegobinone (2S,3R,1'R,2'R)-stegobiol O-Benzylstegobiol