百科

2,4-dideoxy-3-O-<(1,1-dimethylethyl)diphenylsilyl>-5-O-<(4-methoxyphenyl)methyl>-2-methyl-6,7-O-(1-methylethylidene)-D-allo-heptaldonic acid

2,4-dideoxy-3-O-<(1,1-dimethylethyl)diphenylsilyl>-5-O-<(4-methoxyphenyl)methyl>-2-methyl-6,7-O-(1-methylethylidene)-D-allo-heptaldonic acid

CAS号：152453-77-5

英文名：2,4-dideoxy-3-O-<(1,1-dimethylethyl)diphenylsilyl>-5-O-<(4-methoxyphenyl)methyl>-2-methyl-6,7-O-(1-methylethylidene)-D-allo-heptaldonic acid

分子式：C35H46O7Si

分子量：606.821

合成路线

<4R-<4R*<S*(1R*,2S*)>>>-<<1-<2-(2,2-dimethyl-1,3-dioxolan-4-yl)-2-<(4-methoxyphenyl)methoxy>ethyl>-2-methyl-3-butenyl>oxy>(1,1-dimethylethyl)diphenylsilane

<4R-<4R*<S*(1R*,2S*)>>>-<<1-<2-(2,2-dimethyl-1,3-dioxolan-4-yl)-2-<(4-methoxyphenyl)methoxy>ethyl>-2-methyl-3-butenyl>oxy>(1,1-dimethylethyl)diphenylsilane

2,4-dideoxy-3-O-<(1,1-dimethylethyl)diphenylsilyl>-5-O-<(4-methoxyphenyl)methyl>-2-methyl-6,7-O-(1-methylethylidene)-D-allo-heptaldonic acid

2,4-dideoxy-3-O-<(1,1-dimethylethyl)diphenylsilyl>-5-O-<(4-methoxyphenyl)methyl>-2-methyl-6,7-O-(1-methylethylidene)-D-allo-heptaldonic acid

2,4-dideoxy-3-O-<(1,1-dimethylethyl)diphenylsilyl>-5-O-<(4-methoxyphenyl)methyl>-2-methyl-6,7-O-(1-methylethylidene)-D-allo-heptose

2,4-dideoxy-3-O-<(1,1-dimethylethyl)diphenylsilyl>-5-O-<(4-methoxyphenyl)methyl>-2-methyl-6,7-O-(1-methylethylidene)-D-allo-heptose

2,4-dideoxy-3-O-<(1,1-dimethylethyl)diphenylsilyl>-5-O-<(4-methoxyphenyl)methyl>-2-methyl-6,7-O-(1-methylethylidene)-D-allo-heptaldonic acid

2,4-dideoxy-3-O-<(1,1-dimethylethyl)diphenylsilyl>-5-O-<(4-methoxyphenyl)methyl>-2-methyl-6,7-O-(1-methylethylidene)-D-allo-heptaldonic acid

上游原料

<4R-<4R*<S*(1R*,2S*)>>>-<<1-<2-(2,2-dimethyl-1,3-dioxolan-4-yl)-2-<(4-methoxyphenyl)methoxy>ethyl>-2-methyl-3-butenyl>oxy>(1,1-dimethylethyl)diphenylsilane 2,4-dideoxy-3-O-<(1,1-dimethylethyl)diphenylsilyl>-5-O-<(4-methoxyphenyl)methyl>-2-methyl-6,7-O-(1-methylethylidene)-D-allo-heptose

下游产品

<4R-<4α(2E,4E),4aβ,7α(2S*,3E),8β,8aβ>>-5-<hexahydro-7-<2-<<(1,1-dimethylethyl)dimethylsilyl>oxy>-4-iodo-3-butenyl>-4a,8-dimethyl-2,5-dioxo-2H,5H-pyrano<3,4-e>-1,3-oxazin-4-yl>-4-methyl-2,4-pentadienal <2R-(2R*,3R*,5S*,6E)>-3-<<(1,1-dimethylethyl)diphenylsilyl>oxy>-7-iodo-5-<(4-methoxyphenyl)methoxy>-2-methyl-6-heptenoic acid methyl ester <4R-<4α(2E,4E),4aβ,7α(2S*,3E,5E),8β,8aβ>>-5-<hexahydro-7-<7-chloro-5-methyl-2-<<(1,1-dimethylethyl)dimethylsilyl>oxy>-3,5-heptadienyl>-4a,8-dimethyl-2,5-dioxo-2H,5H-pyrano<3,4-e>-1,3-oxazin-4-yl>-4-methyl-2,4-pentadienal (2R,3R,5S,6R)-3-(tert-Butyl-diphenyl-silanyloxy)-6,7-dihydroxy-5-(4-methoxy-benzyloxy)-2-methyl-heptanoic acid methyl ester