百科

(2R,3R,4R,5S)-4-Formyl-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-<4-(tert-butyldimethylsilyloxy)butyl>tetrahydrofuran

(2R,3R,4R,5S)-4-Formyl-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-<4-(tert-butyldimethylsilyloxy)butyl>tetrahydrofuran

CAS号：152492-06-3

英文名：(2R,3R,4R,5S)-4-Formyl-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-<4-(tert-butyldimethylsilyloxy)butyl>tetrahydrofuran

分子式：C23H42O7Si

分子量：458.661

合成路线

(2R,3R,4R,5S)-4-<(ethoxycarbonyl)methyl>-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-vinyltetrahydrofuran

(2R,3R,4R,5S)-4-<(ethoxycarbonyl)methyl>-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-vinyltetrahydrofuran

(2R,3R,4R,5S)-4-Formyl-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-<4-(tert-butyldimethylsilyloxy)butyl>tetrahydrofuran

(2R,3R,4R,5S)-4-Formyl-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-<4-(tert-butyldimethylsilyloxy)butyl>tetrahydrofuran

上游原料

(2R,3R,4R,5S)-4-<(ethoxycarbonyl)methyl>-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-vinyltetrahydrofuran

下游产品

(3aS,4R,7aR)-4-Methyl-4-<<(tert-butyldiphenylsilyl)oxy>methyl>hexahydrobenzofuran-2(3H)-one (2S,3R)-3-Methyl-2-<2-<(tert-butyldiphenylsilyl)oxy>ethyl>-3-vinylcyclohexanone Formic acid (S)-2-benzyloxy-1-((3aS,4R,7aR)-4-formyl-2-oxo-octahydro-benzofuran-4-yl)-ethyl ester (3aS,4R,7aR)-4-(Hydroxymethyl)hexahydrobenzofuran-2(3H)-one (3aS,4S,7aR)-4-Methyl-4-vinylhexahydrobenzofuran-2(3H)-one (2R,3R,4R,5S)-2,3-(Isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-<(Z)-2-(methoxycarbonyl)ethenyl>-4-(4-oxobutyl)tetrahydrofuran (3aS,4S,7aR)-4-Bis(ethylthio)methyl-4-<<(tert-butyldiphenylsilyl)oxy>methyl>hexahydrobenzofuran-2(3H)-one (2R,3R,4R,5S)-2,3-(Isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-<(Z)-2-(methoxycarbonyl)ethenyl>-4-(4-oxopentyl)tetrahydrofuran (1R,2S,3R)-1,3-Dimethyl-2-<2-<(tert-butyldiphenylsilyl)oxy>ethyl>-3-vinylcyclohexanol (3aS,4S,7aR)-4-<(1S)-1,2-Dihydroxyethyl>-4-<<(tert-butyldiphenylsilyl)oxy>methyl>hexahydrobenzofuran-2(3H)-one (2R,3R,4R,5S)-4-<(E)-2-(Ethoxycarbonyl)ethenyl>-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-(4-oxopentyl)tetrahydrofuran (3aS,4S,7aR)-4-Methyl-2-oxo-octahydro-benzofuran-4-carbaldehyde (1R,2S,3R)-2-(2-Hydroxyethyl)-3-methyl-3-vinylcyclohexanol (2R,3R,4R,5S)-4-(4-Hydroxybutyl)-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-<(Z)-2-(methoxycarbonyl)ethenyl>tetrahydrofuran (3aS,4S,7aR)-4-<(1S)-2-(Benzyloxy)-1-hydroxyethyl>-4-(hydroxymethyl)hexahydrobenzofuran-2(3H)-one (1R,2S,3S)-2-(2-Hydroxyethyl)-3-methyl-3-vinylcyclohexanol (3aS,4R,7aR)-4-Methyl-4-vinylhexahydrobenzofuran-2(3H)-one (1R,2S,3S)-2-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-3-methyl-3-vinyl-cyclohexanol (1R,2S,3S)-1,3-Dimethyl-2-<2-<(tert-butyldiphenylsilyl)oxy>ethyl>-3-vinylcyclohexanol