百科

(3aS,4S,7aR)-4-<(1S)-1,2-Dihydroxyethyl>-4-<<(tert-butyldiphenylsilyl)oxy>methyl>hexahydrobenzofuran-2(3H)-one

(3aS,4S,7aR)-4-<(1S)-1,2-Dihydroxyethyl>-4-<<(tert-butyldiphenylsilyl)oxy>methyl>hexahydrobenzofuran-2(3H)-one

CAS号：152492-23-4

英文名：(3aS,4S,7aR)-4-<(1S)-1,2-Dihydroxyethyl>-4-<<(tert-butyldiphenylsilyl)oxy>methyl>hexahydrobenzofuran-2(3H)-one

分子式：C27H36O5Si

分子量：468.657

合成路线

(2R,3R,4R,5S)-4-Formyl-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-<4-(tert-butyldimethylsilyloxy)butyl>tetrahydrofuran

(2R,3R,4R,5S)-4-Formyl-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-<4-(tert-butyldimethylsilyloxy)butyl>tetrahydrofuran

(3aS,4S,7aR)-4-<(1S)-1,2-Dihydroxyethyl>-4-<<(tert-butyldiphenylsilyl)oxy>methyl>hexahydrobenzofuran-2(3H)-one

(3aS,4S,7aR)-4-<(1S)-1,2-Dihydroxyethyl>-4-<<(tert-butyldiphenylsilyl)oxy>methyl>hexahydrobenzofuran-2(3H)-one

Formic acid (S)-2-benzyloxy-1-((3aS,4R,7aR)-4-formyl-2-oxo-octahydro-benzofuran-4-yl)-ethyl ester

Formic acid (S)-2-benzyloxy-1-((3aS,4R,7aR)-4-formyl-2-oxo-octahydro-benzofuran-4-yl)-ethyl ester

(3aS,4S,7aR)-4-<(1S)-1,2-Dihydroxyethyl>-4-<<(tert-butyldiphenylsilyl)oxy>methyl>hexahydrobenzofuran-2(3H)-one

(3aS,4S,7aR)-4-<(1S)-1,2-Dihydroxyethyl>-4-<<(tert-butyldiphenylsilyl)oxy>methyl>hexahydrobenzofuran-2(3H)-one

(2R,3R,4R,5S)-4-(2-hydroxyethyl)-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-vinyltetrahydrofuran

(2R,3R,4R,5S)-4-(2-hydroxyethyl)-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-vinyltetrahydrofuran

(3aS,4S,7aR)-4-<(1S)-1,2-Dihydroxyethyl>-4-<<(tert-butyldiphenylsilyl)oxy>methyl>hexahydrobenzofuran-2(3H)-one

(3aS,4S,7aR)-4-<(1S)-1,2-Dihydroxyethyl>-4-<<(tert-butyldiphenylsilyl)oxy>methyl>hexahydrobenzofuran-2(3H)-one

上游原料

(2R,3R,4R,5S)-4-(2-hydroxyethyl)-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-vinyltetrahydrofuran (2R,3R,4R,5S)-4-Formyl-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-<4-(tert-butyldimethylsilyloxy)butyl>tetrahydrofuran Formic acid (S)-2-benzyloxy-1-((3aS,4R,7aR)-4-formyl-2-oxo-octahydro-benzofuran-4-yl)-ethyl ester

下游产品

(3aS,4R,7aR)-4-Methyl-4-<<(tert-butyldiphenylsilyl)oxy>methyl>hexahydrobenzofuran-2(3H)-one (3aS,4R,7aR)-4-(Hydroxymethyl)hexahydrobenzofuran-2(3H)-one (1R,2S,3S)-1,3-Dimethyl-2-<2-<(tert-butyldiphenylsilyl)oxy>ethyl>-3-vinylcyclohexanol