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(3R,4S,5R,6S,7S)-4-(tert-Butyl-dimethyl-silanyloxy)-8-hydroxy-6-(4-methoxy-benzyloxy)-3,5,7-trimethyl-octanal

(3R,4S,5R,6S,7S)-4-(tert-Butyl-dimethyl-silanyloxy)-8-hydroxy-6-(4-methoxy-benzyloxy)-3,5,7-trimethyl-octanal

CAS号：152567-31-2

英文名：(3R,4S,5R,6S,7S)-4-(tert-Butyl-dimethyl-silanyloxy)-8-hydroxy-6-(4-methoxy-benzyloxy)-3,5,7-trimethyl-octanal

分子式：C25H44O5Si

分子量：452.699

合成路线

<2S,3S,4R,5S,6R,8E>-2,4,6-trimethyl-9-phenyl-5-((1,1-dimethylethyl)dimethylsiloxy)-3-((4-methoxyphenyl)methoxy)-1-non-8-enol

<2S,3S,4R,5S,6R,8E>-2,4,6-trimethyl-9-phenyl-5-((1,1-dimethylethyl)dimethylsiloxy)-3-((4-methoxyphenyl)methoxy)-1-non-8-enol

(3R,4S,5R,6S,7S)-4-(tert-Butyl-dimethyl-silanyloxy)-8-hydroxy-6-(4-methoxy-benzyloxy)-3,5,7-trimethyl-octanal

(3R,4S,5R,6S,7S)-4-(tert-Butyl-dimethyl-silanyloxy)-8-hydroxy-6-(4-methoxy-benzyloxy)-3,5,7-trimethyl-octanal

<2S,3S,4S,5S,6R,8E>-2,4,6-trimethyl-9-phenyl-non-8-ene-1,3,5-triol

<2S,3S,4S,5S,6R,8E>-2,4,6-trimethyl-9-phenyl-non-8-ene-1,3,5-triol

(3R,4S,5R,6S,7S)-4-(tert-Butyl-dimethyl-silanyloxy)-8-hydroxy-6-(4-methoxy-benzyloxy)-3,5,7-trimethyl-octanal

(3R,4S,5R,6S,7S)-4-(tert-Butyl-dimethyl-silanyloxy)-8-hydroxy-6-(4-methoxy-benzyloxy)-3,5,7-trimethyl-octanal

<2S,4S,4(1R,2S,3R,5E),5S>-2-(4-methoxyphenyl)-5-methyl-4-(2-hydroxy-1,3-dimethyl-6-phenyl-5-hexenyl)-1,3-dioxane

<2S,4S,4(1R,2S,3R,5E),5S>-2-(4-methoxyphenyl)-5-methyl-4-(2-hydroxy-1,3-dimethyl-6-phenyl-5-hexenyl)-1,3-dioxane

(3R,4S,5R,6S,7S)-4-(tert-Butyl-dimethyl-silanyloxy)-8-hydroxy-6-(4-methoxy-benzyloxy)-3,5,7-trimethyl-octanal

(3R,4S,5R,6S,7S)-4-(tert-Butyl-dimethyl-silanyloxy)-8-hydroxy-6-(4-methoxy-benzyloxy)-3,5,7-trimethyl-octanal

<2S,4S,4(1R,2S,3R,5E),5S>-2-(4-methoxyphenyl)-5-methyl-4-(1,3-dimethyl-6-phenyl-2-((1,1-dimethylethyl)dimethylsiloxy)-5-hexenyl)-1,3-dioxane

<2S,4S,4(1R,2S,3R,5E),5S>-2-(4-methoxyphenyl)-5-methyl-4-(1,3-dimethyl-6-phenyl-2-((1,1-dimethylethyl)dimethylsiloxy)-5-hexenyl)-1,3-dioxane

(3R,4S,5R,6S,7S)-4-(tert-Butyl-dimethyl-silanyloxy)-8-hydroxy-6-(4-methoxy-benzyloxy)-3,5,7-trimethyl-octanal

(3R,4S,5R,6S,7S)-4-(tert-Butyl-dimethyl-silanyloxy)-8-hydroxy-6-(4-methoxy-benzyloxy)-3,5,7-trimethyl-octanal

上游原料

<2S,3S,4S,5S,6R,8E>-2,4,6-trimethyl-9-phenyl-non-8-ene-1,3,5-triol <2S,3S,4R,5S,6R,8E>-2,4,6-trimethyl-9-phenyl-5-((1,1-dimethylethyl)dimethylsiloxy)-3-((4-methoxyphenyl)methoxy)-1-non-8-enol <2S,4S,4(1R,2S,3R,5E),5S>-2-(4-methoxyphenyl)-5-methyl-4-(1,3-dimethyl-6-phenyl-2-((1,1-dimethylethyl)dimethylsiloxy)-5-hexenyl)-1,3-dioxane <2S,4S,4(1R,2S,3R,5E),5S>-2-(4-methoxyphenyl)-5-methyl-4-(2-hydroxy-1,3-dimethyl-6-phenyl-5-hexenyl)-1,3-dioxane

下游产品

1,1-dimethylethyl<2E,4S,5R,6S,8R,9S,10R,11R,12R,13S,14R,16E>-17-iodo-4,6,8,10,12,14-hexamethyl-7-oxo-11-((4-methoxyphenyl)methoxy)-5,9,13-tris((1,1-dimethylethyl)dimethylsiloxy)heptadeca-2,16-dienoate 1,1-dimethylethyl (4S,5R,6S,8R,9S,10S,12S,13S,14R)-(2E,16E)-17-iodo-4,6,8,10,12,14-hexamethyl-7,11-dioxo-5,9,13-tri-(tert-butyldimethylsilyloxy)-heptadeca-2,16-dienoate 1,1-dimethylethyl<2E,4S,5R,6S,8R,9S,10R,11R,12R,13S,14R,16E>-11-hydroxy-17-iodo-4,6,8,10,12,14-hexamethyl-7-oxo-5,9,13-tris((1,1-dimethylethyl)dimethylsiloxy)heptadeca-2,16-dienoate <2R,3R,4R,5S,6R,8E>-9-iodo-2,4,6-trimethyl-5-((1,1-dimethylethyl)dimethylsiloxy)-3-((4-methoxyphenyl)methoxy)-8-nonenal