百科

<2S,2'S> 2,2'-dimethyl-3,3',4,4'-tetrahydro-6,6'-bi-2H-pyran

<2S,2'S> 2,2'-dimethyl-3,3',4,4'-tetrahydro-6,6'-bi-2H-pyran

CAS号：153594-99-1

英文名：<2S,2'S> 2,2'-dimethyl-3,3',4,4'-tetrahydro-6,6'-bi-2H-pyran

分子式：C12H18O2

分子量：194.27

合成路线

(4S)-4-(tert-butyldimethylsilyloxy)-1-(1,3-dioxan-2-yl)pentane

(4S)-4-(tert-butyldimethylsilyloxy)-1-(1,3-dioxan-2-yl)pentane

<2S,2'S> 2,2'-dimethyl-3,3',4,4'-tetrahydro-6,6'-bi-2H-pyran

<2S,2'S> 2,2'-dimethyl-3,3',4,4'-tetrahydro-6,6'-bi-2H-pyran

(6S)-6-methyl-2-phenylsulfonyltetrahydro-2H-pyran

(6S)-6-methyl-2-phenylsulfonyltetrahydro-2H-pyran

<2S,2'S> 2,2'-dimethyl-3,3',4,4'-tetrahydro-6,6'-bi-2H-pyran

<2S,2'S> 2,2'-dimethyl-3,3',4,4'-tetrahydro-6,6'-bi-2H-pyran

上游原料

(4S)-4-(tert-butyldimethylsilyloxy)-1-(1,3-dioxan-2-yl)pentane (6S)-6-methyl-2-phenylsulfonyltetrahydro-2H-pyran

下游产品

(2S,2'R,2''R,3S,4S,6'S,6''S)-1-O,4-O,5-O-tribenzyl-2-O,3-O-(6,6'-dimethyl-3,3',4,4',5,5',6,6'-octahydro-2,2'-bi-2H-pyran-2,2'-diyl)-xylitol (2S,6S,7R,9S,14S)-14-Benzyloxymethyl-2,9-dimethyl-1,8,13,16-tetraoxa-dispiro[5.0.5.4]hexadecane (2S,6R,7R,9S,15S)-15-Benzyl-2,9,15-trimethyl-1,8,13,16-tetraoxa-dispiro[5.0.5.4]hexadecan-14-one (2S,2'R,2''R,3S,4S,6'S,6''S)-2-O,3-O-(6,6'-dimethyl-3,3',4,4',5,5',6,6'-octahydro-2,2'-bi-2H-pyran-2,2'-diyl)-xylitol