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(2R,3R,4R,5S,6S)-7-benzyloxy-2,3-epoxy-5-triethylsilyloxy-4,6-dimethyl-1-heptanol

(2R,3R,4R,5S,6S)-7-benzyloxy-2,3-epoxy-5-triethylsilyloxy-4,6-dimethyl-1-heptanol

CAS号：155430-45-8

英文名：(2R,3R,4R,5S,6S)-7-benzyloxy-2,3-epoxy-5-triethylsilyloxy-4,6-dimethyl-1-heptanol

分子式：C22H38O4Si

分子量：394.62

合成路线

(R)-ethyl (Z)-5-benzyloxy-4-methyl-2-pentenoate

(R)-ethyl (Z)-5-benzyloxy-4-methyl-2-pentenoate

(2R,3R,4R,5S,6S)-7-benzyloxy-2,3-epoxy-5-triethylsilyloxy-4,6-dimethyl-1-heptanol

(2R,3R,4R,5S,6S)-7-benzyloxy-2,3-epoxy-5-triethylsilyloxy-4,6-dimethyl-1-heptanol

(Z)-(R)-5-Benzyloxy-4-methyl-pent-2-enoic acid methyl ester

(Z)-(R)-5-Benzyloxy-4-methyl-pent-2-enoic acid methyl ester

(2R,3R,4R,5S,6S)-7-benzyloxy-2,3-epoxy-5-triethylsilyloxy-4,6-dimethyl-1-heptanol

(2R,3R,4R,5S,6S)-7-benzyloxy-2,3-epoxy-5-triethylsilyloxy-4,6-dimethyl-1-heptanol

上游原料

(R)-ethyl (Z)-5-benzyloxy-4-methyl-2-pentenoate (Z)-(R)-5-Benzyloxy-4-methyl-pent-2-enoic acid methyl ester

下游产品

2,2-Dimethyl-propionic acid (3S,4R,5R,6S,7R,8R,9S,10S)-11-benzyloxy-3-hydroxy-4,6,8,10-tetramethyl-5,7,9-tris-triethylsilanyloxy-undecyl ester (R)-2-[(4R,5S,6S)-2,2-Di-tert-butyl-6-((1S,5R,6R,7R)-6-methoxy-1,5,7-trimethyl-4-oxo-9-triisopropylsilanyloxy-nonyl)-5-methyl-[1,3,2]dioxasilinan-4-yl]-propionaldehyde (3S,4R,5R,6S,7R,8R,9S,10S)-11-Benzyloxy-4,6,8,10-tetramethyl-5,7,9-tris-triethylsilanyloxy-undecane-1,3-diol (E)-3-[(2S,3S)-3-((1R,2R,3R,4S,5S)-6-Benzyloxy-2,4-dihydroxy-1,3,5-trimethyl-hexyl)-oxiranyl]-acrylic acid ethyl ester (E)-(4R,5R,6S,7S,8R,9S,10S)-11-Benzyloxy-5,7,9-trihydroxy-4,6,8,10-tetramethyl-undec-2-enoic acid ethyl ester (E)-3-[(2S,3S)-3-((1S,2S,3R,4S,5S)-6-Benzyloxy-1,3,5-trimethyl-2,4-bis-triethylsilanyloxy-hexyl)-oxiranyl]-acrylic acid ethyl ester (2S,3S,4S,5S,6S,9S,10R)-1-Benzyloxy-9-(4-methoxy-benzyloxy)-2,4,6,10-tetramethyl-dodec-11-ene-3,5-diol (3S,4S,5R,6S,9S)-9-[(4S,5S,6S)-6-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2-di-tert-butyl-5-methyl-[1,3,2]dioxasilinan-4-yl]-6-(4-methoxy-benzyloxy)-3,5-dimethyl-dec-1-en-4-ol 2,2-Dimethyl-propionic acid (2S,3S,4S,5S,6S)-7-benzyloxy-3-hydroxy-2,4,6-trimethyl-5-triethylsilanyloxy-heptyl ester (S)-4-[(4S,5S,6S)-6-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-pentanal (4S,5S,6S)-4-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2-di-tert-butyl-6-[(1S,4S,5R)-4-(4-methoxy-benzyloxy)-1,5-dimethyl-hept-6-enyl]-5-methyl-[1,3,2]dioxasilinane (3R,4R,5R,6S,9S)-9-[(4S,5S,6S)-6-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2-di-tert-butyl-5-methyl-[1,3,2]dioxasilinan-4-yl]-6-(4-methoxy-benzyloxy)-3,5-dimethyl-dec-1-en-4-ol (3R,4S,7S)-7-[(4S,5S,6S)-6-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-3-methyl-oct-1-en-4-ol (4S,5S,6S)-4-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2-di-tert-butyl-6-[(1S,4S,5S,6R,7R)-6-methoxy-4-(4-methoxy-benzyloxy)-1,5,7-trimethyl-9-triisopropylsilanyloxy-nonyl]-5-methyl-[1,3,2]dioxasilinane