百科

(E)-(1R,2R,5R)-1-Methoxy-1-((2R,3R,5S,6R)-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-3,5-dimethyl-6-(tetrahydro-pyran-2-yloxy)-hex-3-en-2-ol

(E)-(1R,2R,5R)-1-Methoxy-1-((2R,3R,5S,6R)-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-3,5-dimethyl-6-(tetrahydro-pyran-2-yloxy)-hex-3-en-2-ol

CAS号：156414-54-9

英文名：(E)-(1R,2R,5R)-1-Methoxy-1-((2R,3R,5S,6R)-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-3,5-dimethyl-6-(tetrahydro-pyran-2-yloxy)-hex-3-en-2-ol

分子式：C22H40O6

分子量：400.549

合成路线

(S)-Methoxy-((2R,3R,5S,6R)-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-acetaldehyde

(S)-Methoxy-((2R,3R,5S,6R)-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-acetaldehyde

(E)-(1R,2R,5R)-1-Methoxy-1-((2R,3R,5S,6R)-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-3,5-dimethyl-6-(tetrahydro-pyran-2-yloxy)-hex-3-en-2-ol

(E)-(1R,2R,5R)-1-Methoxy-1-((2R,3R,5S,6R)-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-3,5-dimethyl-6-(tetrahydro-pyran-2-yloxy)-hex-3-en-2-ol

2-((E)-(R)-4-Iodo-2-methyl-pent-3-enyloxy)-tetrahydro-pyran

2-((E)-(R)-4-Iodo-2-methyl-pent-3-enyloxy)-tetrahydro-pyran

(E)-(1R,2R,5R)-1-Methoxy-1-((2R,3R,5S,6R)-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-3,5-dimethyl-6-(tetrahydro-pyran-2-yloxy)-hex-3-en-2-ol

(E)-(1R,2R,5R)-1-Methoxy-1-((2R,3R,5S,6R)-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-3,5-dimethyl-6-(tetrahydro-pyran-2-yloxy)-hex-3-en-2-ol

(E)-(1R,2S,5R)-1-Methoxy-1-((2R,3R,5S,6R)-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-3,5-dimethyl-6-(tetrahydro-pyran-2-yloxy)-hex-3-en-2-ol

(E)-(1R,2S,5R)-1-Methoxy-1-((2R,3R,5S,6R)-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-3,5-dimethyl-6-(tetrahydro-pyran-2-yloxy)-hex-3-en-2-ol

(E)-(1R,2R,5R)-1-Methoxy-1-((2R,3R,5S,6R)-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-3,5-dimethyl-6-(tetrahydro-pyran-2-yloxy)-hex-3-en-2-ol

(E)-(1R,2R,5R)-1-Methoxy-1-((2R,3R,5S,6R)-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-3,5-dimethyl-6-(tetrahydro-pyran-2-yloxy)-hex-3-en-2-ol

上游原料

2-((E)-(R)-4-Iodo-2-methyl-pent-3-enyloxy)-tetrahydro-pyran (S)-Methoxy-((2R,3R,5S,6R)-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-acetaldehyde (E)-(1R,2S,5R)-1-Methoxy-1-((2R,3R,5S,6R)-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-3,5-dimethyl-6-(tetrahydro-pyran-2-yloxy)-hex-3-en-2-ol

下游产品

(2R,3R,5S,6R)-2-[(E)-(1S,2R,5R)-6-Benzenesulfonyl-1-methoxy-2-(4-methoxy-benzyloxy)-3,5-dimethyl-hex-3-enyl]-6-methoxy-3,5-dimethyl-tetrahydro-pyran