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(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-[(2R,6S)-6-((2S,3R)-2-methoxy-3-methyl-4-oxo-butyl)-5,6-dihydro-2H-pyran-2-yl]-2-methyl-hex-2-enoic acid methyl ester
CAS号:157758-41-3
英文名:(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-[(2R,6S)-6-((2S,3R)-2-methoxy-3-methyl-4-oxo-butyl)-5,6-dihydro-2H-pyran-2-yl]-2-methyl-hex-2-enoic acid methyl ester
分子式:C25H44O6Si
分子量:468.699
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合成路线
180592-86-3
(2S,3S)-1-(4-methoxybenzyloxy)-2-methylhex-5-en-3-ol
157758-41-3
(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-[(2R,6S)-6-((2S,3R)-2-methoxy-3-methyl-4-oxo-butyl)-5,6-dihydro-2H-pyran-2-yl]-2-methyl-hex-2-enoic acid methyl ester
157758-38-8
1-[(2S,3S,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-(tert-butyl-diphenyl-silanyloxy)-3-methoxy-2-methyl-hexyloxymethyl]-4-methoxy-benzene
157758-41-3
(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-[(2R,6S)-6-((2S,3R)-2-methoxy-3-methyl-4-oxo-butyl)-5,6-dihydro-2H-pyran-2-yl]-2-methyl-hex-2-enoic acid methyl ester
157758-37-7
(3S,4S,6S)-6-(tert-Butyl-dimethyl-silanyloxy)-7-(tert-butyl-diphenyl-silanyloxy)-3-methyl-hept-1-en-4-ol
157758-41-3
(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-[(2R,6S)-6-((2S,3R)-2-methoxy-3-methyl-4-oxo-butyl)-5,6-dihydro-2H-pyran-2-yl]-2-methyl-hex-2-enoic acid methyl ester
157811-05-7
(E)-(S)-5-Hydroxy-6-{(2R,6S)-6-[(2S,3S)-2-methoxy-4-(4-methoxy-benzyloxy)-3-methyl-butyl]-5,6-dihydro-2H-pyran-2-yl}-2-methyl-hex-2-enoic acid methyl ester
157758-41-3
(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-[(2R,6S)-6-((2S,3R)-2-methoxy-3-methyl-4-oxo-butyl)-5,6-dihydro-2H-pyran-2-yl]-2-methyl-hex-2-enoic acid methyl ester
180592-89-6
(-)-(2S,3S)-4-((2S,6R)-6-allyl-3,6-dihydro-2H-pyran-2-yl)-3-methoxy-2-methylbutan-1-ol
157758-41-3
(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-[(2R,6S)-6-((2S,3R)-2-methoxy-3-methyl-4-oxo-butyl)-5,6-dihydro-2H-pyran-2-yl]-2-methyl-hex-2-enoic acid methyl ester
180592-87-4
(4R,6S)-4-Iodomethyl-6-[(S)-2-(4-methoxy-benzyloxy)-1-methyl-ethyl]-[1,3]dioxan-2-one
157758-41-3
(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-[(2R,6S)-6-((2S,3R)-2-methoxy-3-methyl-4-oxo-butyl)-5,6-dihydro-2H-pyran-2-yl]-2-methyl-hex-2-enoic acid methyl ester
180592-90-9
Benzoic acid (2S,3S)-4-((2S,6R)-6-allyl-3,6-dihydro-2H-pyran-2-yl)-3-methoxy-2-methyl-butyl ester
157758-41-3
(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-[(2R,6S)-6-((2S,3R)-2-methoxy-3-methyl-4-oxo-butyl)-5,6-dihydro-2H-pyran-2-yl]-2-methyl-hex-2-enoic acid methyl ester
180592-91-0
Benzoic acid (2S,3S)-3-methoxy-2-methyl-4-[(2S,6R)-6-(2-oxo-ethyl)-3,6-dihydro-2H-pyran-2-yl]-butyl ester
157758-41-3
(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-[(2R,6S)-6-((2S,3R)-2-methoxy-3-methyl-4-oxo-butyl)-5,6-dihydro-2H-pyran-2-yl]-2-methyl-hex-2-enoic acid methyl ester
180592-94-3
Benzoic acid (2S,3S)-4-{(2S,6R)-6-[(E)-(S)-2-(tert-butyl-dimethyl-silanyloxy)-5-methoxycarbonyl-hex-4-enyl]-3,6-dihydro-2H-pyran-2-yl}-3-methoxy-2-methyl-butyl ester
157758-41-3
(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-[(2R,6S)-6-((2S,3R)-2-methoxy-3-methyl-4-oxo-butyl)-5,6-dihydro-2H-pyran-2-yl]-2-methyl-hex-2-enoic acid methyl ester
157811-04-6
{(2R,6S)-6-[(2S,3S)-2-Methoxy-4-(4-methoxy-benzyloxy)-3-methyl-butyl]-5,6-dihydro-2H-pyran-2-yl}-acetaldehyde
157758-41-3
(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-[(2R,6S)-6-((2S,3R)-2-methoxy-3-methyl-4-oxo-butyl)-5,6-dihydro-2H-pyran-2-yl]-2-methyl-hex-2-enoic acid methyl ester
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上游原料
(S)-5-((2S,3S)-2-methoxy-3-methylpent-4-en-1-yl)-2,2,3,3,9,9-hexamethyl-8,8-diphenyl-4,7-dioxa-3,8-disiladecane
Methanesulfonic acid (1S,3S,4S)-1-(tert-butyl-diphenyl-silanyloxymethyl)-3-methoxy-5-(4-methoxy-benzyloxy)-4-methyl-pentyl ester
(-)-(2S,3S)-4-((2S,6R)-6-allyl-3,6-dihydro-2H-pyran-2-yl)-3-methoxy-2-methylbutan-1-ol
Benzoic acid (2S,3S)-3-methoxy-2-methyl-4-[(2S,6R)-6-(2-oxo-ethyl)-3,6-dihydro-2H-pyran-2-yl]-butyl ester
(E)-(S)-5-Hydroxy-6-{(2R,6S)-6-[(2S,3S)-2-methoxy-4-(4-methoxy-benzyloxy)-3-methyl-butyl]-5,6-dihydro-2H-pyran-2-yl}-2-methyl-hex-2-enoic acid methyl ester
{(2R,6S)-6-[(2S,3S)-2-Methoxy-4-(4-methoxy-benzyloxy)-3-methyl-butyl]-5,6-dihydro-2H-pyran-2-yl}-acetaldehyde
1-[(2S,3S,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-(tert-butyl-diphenyl-silanyloxy)-3-methoxy-2-methyl-hexyloxymethyl]-4-methoxy-benzene
(4R,6S)-4-Iodomethyl-6-[(S)-2-(4-methoxy-benzyloxy)-1-methyl-ethyl]-[1,3]dioxan-2-one
Benzoic acid (2S,3S)-4-{(2S,6R)-6-[(E)-(S)-2-(tert-butyl-dimethyl-silanyloxy)-5-methoxycarbonyl-hex-4-enyl]-3,6-dihydro-2H-pyran-2-yl}-3-methoxy-2-methyl-butyl ester
(3S,4S,6S)-6-(tert-Butyl-dimethyl-silanyloxy)-7-(tert-butyl-diphenyl-silanyloxy)-3-methyl-hept-1-en-4-ol
(2S,3S)-1-(4-methoxybenzyloxy)-2-methylhex-5-en-3-ol
Benzoic acid (2S,3S)-4-((2S,6R)-6-allyl-3,6-dihydro-2H-pyran-2-yl)-3-methoxy-2-methyl-butyl ester
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