百科

(1R,2R,3S,4R,6R)-2,3,4-Tris-benzyloxy-5-methylene-7-oxa-bicyclo[4.1.0]heptane

(1R,2R,3S,4R,6R)-2,3,4-Tris-benzyloxy-5-methylene-7-oxa-bicyclo[4.1.0]heptane

CAS号：157761-57-4

英文名：(1R,2R,3S,4R,6R)-2,3,4-Tris-benzyloxy-5-methylene-7-oxa-bicyclo[4.1.0]heptane

分子式：C28H28O4

分子量：428.52

合成路线

Formic acid (1R,2S,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-2-iodo-6-iodomethyl-cyclohexyl ester

Formic acid (1R,2S,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-2-iodo-6-iodomethyl-cyclohexyl ester

(1R,2R,3S,4R,6R)-2,3,4-Tris-benzyloxy-5-methylene-7-oxa-bicyclo[4.1.0]heptane

(1R,2R,3S,4R,6R)-2,3,4-Tris-benzyloxy-5-methylene-7-oxa-bicyclo[4.1.0]heptane

2-(R)-3-(S)-4-(R)-tribenzyloxy-5-t-butyldimethylsilyloxy-pentanal

2-(R)-3-(S)-4-(R)-tribenzyloxy-5-t-butyldimethylsilyloxy-pentanal

(1R,2R,3S,4R,6R)-2,3,4-Tris-benzyloxy-5-methylene-7-oxa-bicyclo[4.1.0]heptane

(1R,2R,3S,4R,6R)-2,3,4-Tris-benzyloxy-5-methylene-7-oxa-bicyclo[4.1.0]heptane

(3aR,4R,5S,6R,7S,7aR)-4,5,6-Tris-benzyloxy-7-iodo-hexahydro-benzofuran-2-one

(3aR,4R,5S,6R,7S,7aR)-4,5,6-Tris-benzyloxy-7-iodo-hexahydro-benzofuran-2-one

(1R,2R,3S,4R,6R)-2,3,4-Tris-benzyloxy-5-methylene-7-oxa-bicyclo[4.1.0]heptane

(1R,2R,3S,4R,6R)-2,3,4-Tris-benzyloxy-5-methylene-7-oxa-bicyclo[4.1.0]heptane

((1S,4S,5R,6R)-4,5,6-Tris-benzyloxy-cyclohex-2-enyl)-acetic acid methyl ester

((1S,4S,5R,6R)-4,5,6-Tris-benzyloxy-cyclohex-2-enyl)-acetic acid methyl ester

(1R,2R,3S,4R,6R)-2,3,4-Tris-benzyloxy-5-methylene-7-oxa-bicyclo[4.1.0]heptane

(1R,2R,3S,4R,6R)-2,3,4-Tris-benzyloxy-5-methylene-7-oxa-bicyclo[4.1.0]heptane

(3S,4R,5R,6S)-4,5,6-Tris-benzyloxy-3-vinyl-oct-7-enoic acid methyl ester

(3S,4R,5R,6S)-4,5,6-Tris-benzyloxy-3-vinyl-oct-7-enoic acid methyl ester

(1R,2R,3S,4R,6R)-2,3,4-Tris-benzyloxy-5-methylene-7-oxa-bicyclo[4.1.0]heptane

(1R,2R,3S,4R,6R)-2,3,4-Tris-benzyloxy-5-methylene-7-oxa-bicyclo[4.1.0]heptane

tert-Butyl-dimethyl-((2R,3S,4R)-2,3,4-tris-benzyloxy-5,5-bis-ethylsulfanyl-pentyloxy)-silane

tert-Butyl-dimethyl-((2R,3S,4R)-2,3,4-tris-benzyloxy-5,5-bis-ethylsulfanyl-pentyloxy)-silane

(1R,2R,3S,4R,6R)-2,3,4-Tris-benzyloxy-5-methylene-7-oxa-bicyclo[4.1.0]heptane

(1R,2R,3S,4R,6R)-2,3,4-Tris-benzyloxy-5-methylene-7-oxa-bicyclo[4.1.0]heptane

3,4,5-tri-O-benzyl-1,2-dideoxy-D-xylohept-1-enitol

3,4,5-tri-O-benzyl-1,2-dideoxy-D-xylohept-1-enitol

(1R,2R,3S,4R,6R)-2,3,4-Tris-benzyloxy-5-methylene-7-oxa-bicyclo[4.1.0]heptane

(1R,2R,3S,4R,6R)-2,3,4-Tris-benzyloxy-5-methylene-7-oxa-bicyclo[4.1.0]heptane

上游原料

2-(R)-3-(S)-4-(R)-tribenzyloxy-5-t-butyldimethylsilyloxy-pentanal (3aR,4R,5S,6R,7S,7aR)-4,5,6-Tris-benzyloxy-7-iodo-hexahydro-benzofuran-2-one tert-Butyl-dimethyl-((2R,3S,4R)-2,3,4-tris-benzyloxy-5,5-bis-ethylsulfanyl-pentyloxy)-silane 3,4,5-tri-O-benzyl-1,2-dideoxy-D-xylohept-1-enitol Formic acid (1R,2S,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-2-iodo-6-iodomethyl-cyclohexyl ester ((1S,4S,5R,6R)-4,5,6-Tris-benzyloxy-cyclohex-2-enyl)-acetic acid methyl ester (3S,4R,5R,6S)-4,5,6-Tris-benzyloxy-3-vinyl-oct-7-enoic acid methyl ester

下游产品

2,3,4-tri-O-benzyl-5-epi-cyclophellitol