百科

(2E,4E)-(S)-7-(tert-Butyl-dimethyl-silanyloxy)-8-[(2R,6S)-6-((2S,3S)-2-methoxy-3-methyl-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-4-methyl-octa-2,4-dienoic acid methyl ester

(2E,4E)-(S)-7-(tert-Butyl-dimethyl-silanyloxy)-8-[(2R,6S)-6-((2S,3S)-2-methoxy-3-methyl-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-4-methyl-octa-2,4-dienoic acid methyl ester

CAS号：157830-70-1

英文名：(2E,4E)-(S)-7-(tert-Butyl-dimethyl-silanyloxy)-8-[(2R,6S)-6-((2S,3S)-2-methoxy-3-methyl-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-4-methyl-octa-2,4-dienoic acid methyl ester

分子式：C28H48O5Si

分子量：492.763

合成路线

2,2-Dimethyl-propionic acid (2E,4E)-(S)-8-((2R,6S)-6-hydroxymethyl-5,6-dihydro-2H-pyran-2-yl)-4-methyl-7-triisopropylsilanyloxy-octa-2,4-dienyl ester

2,2-Dimethyl-propionic acid (2E,4E)-(S)-8-((2R,6S)-6-hydroxymethyl-5,6-dihydro-2H-pyran-2-yl)-4-methyl-7-triisopropylsilanyloxy-octa-2,4-dienyl ester

(2E,4E)-(S)-7-(tert-Butyl-dimethyl-silanyloxy)-8-[(2R,6S)-6-((2S,3S)-2-methoxy-3-methyl-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-4-methyl-octa-2,4-dienoic acid methyl ester

(2E,4E)-(S)-7-(tert-Butyl-dimethyl-silanyloxy)-8-[(2R,6S)-6-((2S,3S)-2-methoxy-3-methyl-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-4-methyl-octa-2,4-dienoic acid methyl ester

(2E,4E)-(S)-8-[(2R,6S)-6-((2S,3S)-2-Hydroxy-3-methyl-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-4-methyl-7-triisopropylsilanyloxy-octa-2,4-dien-1-ol

(2E,4E)-(S)-8-[(2R,6S)-6-((2S,3S)-2-Hydroxy-3-methyl-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-4-methyl-7-triisopropylsilanyloxy-octa-2,4-dien-1-ol

(2E,4E)-(S)-7-(tert-Butyl-dimethyl-silanyloxy)-8-[(2R,6S)-6-((2S,3S)-2-methoxy-3-methyl-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-4-methyl-octa-2,4-dienoic acid methyl ester

(2E,4E)-(S)-7-(tert-Butyl-dimethyl-silanyloxy)-8-[(2R,6S)-6-((2S,3S)-2-methoxy-3-methyl-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-4-methyl-octa-2,4-dienoic acid methyl ester

上游原料

2,2-Dimethyl-propionic acid (2E,4E)-(S)-8-((2R,6S)-6-hydroxymethyl-5,6-dihydro-2H-pyran-2-yl)-4-methyl-7-triisopropylsilanyloxy-octa-2,4-dienyl ester (2E,4E)-(S)-8-[(2R,6S)-6-((2S,3S)-2-Hydroxy-3-methyl-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-4-methyl-7-triisopropylsilanyloxy-octa-2,4-dien-1-ol

下游产品

(E,E,7S)-methyl-8-<(2R,6S)-6-<(2S,3R,6R,7S,8S,9S,10S,11S)-2-methoxy-3,7,9,11-tetramethyl-6-hydroxy-8,10-di-tert-butylsilylenedioxy-13-((2S,4R,6S)-2-methyl-4-methoxytetrahydropyran-6-yl)-tridecan-4-one-1-yl>-5,6-dihydro-2H-pyran-2-yl>-7-tert-butyl... (2E,4E)-(S)-7-(tert-Butyl-dimethyl-silanyloxy)-8-[(2R,6S)-6-((2S,3R)-2-methoxy-3-methyl-4-trimethylsilanyloxy-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-4-methyl-octa-2,4-dienoic acid methyl ester