百科

1-bromo-7(R)-<(tert-butyldiphenylsilyl)oxy>-3(E),5(E),9(Z)-pentadecatrien-1-yne

1-bromo-7(R)-<(tert-butyldiphenylsilyl)oxy>-3(E),5(E),9(Z)-pentadecatrien-1-yne

CAS号：158719-01-8

英文名：1-bromo-7(R)-<(tert-butyldiphenylsilyl)oxy>-3(E),5(E),9(Z)-pentadecatrien-1-yne

分子式：C31H39BrOSi

分子量：535.63

合成路线

tert-Butyl-[(Z)-(R)-((1E,3E)-1-hexa-1,3-dien-5-ynyl)-non-3-enyloxy]-diphenyl-silane

tert-Butyl-[(Z)-(R)-((1E,3E)-1-hexa-1,3-dien-5-ynyl)-non-3-enyloxy]-diphenyl-silane

1-bromo-7(R)-<(tert-butyldiphenylsilyl)oxy>-3(E),5(E),9(Z)-pentadecatrien-1-yne

1-bromo-7(R)-<(tert-butyldiphenylsilyl)oxy>-3(E),5(E),9(Z)-pentadecatrien-1-yne

(2R,3S)-5-hydroxy-2-((Z)-oct-2-en-1-yl)tetrahydrofuran-3-yl 4-methylbenzenesulfonate

(2R,3S)-5-hydroxy-2-((Z)-oct-2-en-1-yl)tetrahydrofuran-3-yl 4-methylbenzenesulfonate

1-bromo-7(R)-<(tert-butyldiphenylsilyl)oxy>-3(E),5(E),9(Z)-pentadecatrien-1-yne

1-bromo-7(R)-<(tert-butyldiphenylsilyl)oxy>-3(E),5(E),9(Z)-pentadecatrien-1-yne

(3E,5E,9Z)-(R)-Pentadeca-3,5,9-trien-1-yn-7-ol

(3E,5E,9Z)-(R)-Pentadeca-3,5,9-trien-1-yn-7-ol

1-bromo-7(R)-<(tert-butyldiphenylsilyl)oxy>-3(E),5(E),9(Z)-pentadecatrien-1-yne

1-bromo-7(R)-<(tert-butyldiphenylsilyl)oxy>-3(E),5(E),9(Z)-pentadecatrien-1-yne

7(R)-hydroxy-1-(trimethylsilyl)-3(E),5(E),9(Z)-pentadecatrien-1-yne

7(R)-hydroxy-1-(trimethylsilyl)-3(E),5(E),9(Z)-pentadecatrien-1-yne

1-bromo-7(R)-<(tert-butyldiphenylsilyl)oxy>-3(E),5(E),9(Z)-pentadecatrien-1-yne

1-bromo-7(R)-<(tert-butyldiphenylsilyl)oxy>-3(E),5(E),9(Z)-pentadecatrien-1-yne

上游原料

7(R)-hydroxy-1-(trimethylsilyl)-3(E),5(E),9(Z)-pentadecatrien-1-yne tert-Butyl-[(Z)-(R)-((1E,3E)-1-hexa-1,3-dien-5-ynyl)-non-3-enyloxy]-diphenyl-silane (3E,5E,9Z)-(R)-Pentadeca-3,5,9-trien-1-yn-7-ol

下游产品

3(R),12(R)-bis<(tert-butyldiphenylsilyl)oxy>-5(S)-hydroxy-6(Z),8(E),10(E),14(Z)-eicosatetranoic δ-lactone 3(S),12(R)-bis<(tert-butyldiphenylsilyl)oxy>-5(S)-hydroxy-6(Z),8(E),10(E),14(Z)-eicosatetranoic δ-lactone 2(R)-methoxy-4(S)-<(tert-butyldiphenylsilyl)oxy>-6-<7(R)-<(tert-butyldiphenylsilyl)oxy>-3(E),5(E),9(Z)-pentadecatrien-1-ynyl>-2,3-dihydro-4H-pyran (2R,4R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-[(1Z,3E,5E,9Z)-(R)-7-(tert-butyl-diphenyl-silanyloxy)-pentadeca-1,3,5,9-tetraenyl]-2-methoxy-3,4-dihydro-2H-pyran 2(R)-methoxy-4(S)-<(tert-butyldiphenylsilyl)oxy>-6(S)-<7(R)-<(tert-butyldiphenylsilyl)oxy>-1(Z),3(E),5(E),9(Z)-pentadecatetraen-1-yl>tetrahydropyran