(1R,2S,3R,4S,5S,6S) 5-<(t-butyldimethylsilyl)oxy>-2,3,4-tris(benzyloxy)-1-<(trimethylsilyl)oxy>bicyclo<4.1.0>heptane

(1R,2S,3R,4S,5S,6S) 5-<(t-butyldimethylsilyl)oxy>-2,3,4-tris(benzyloxy)-1-<(trimethylsilyl)oxy>bicyclo<4.1.0>heptane

CAS号：159701-15-2

英文名：(1R,2S,3R,4S,5S,6S) 5-<(t-butyldimethylsilyl)oxy>-2,3,4-tris(benzyloxy)-1-<(trimethylsilyl)oxy>bicyclo<4.1.0>heptane

分子式：C37H52O5Si2

分子量：632.977

合成路线

methyl 2,3,4-tri-O-benzyl-α-d-xylo-hex-5-enopyranoside

methyl 2,3,4-tri-O-benzyl-α-d-xylo-hex-5-enopyranoside

(1R,2S,3R,4S,5S,6S) 5-<(t-butyldimethylsilyl)oxy>-2,3,4-tris(benzyloxy)-1-<(trimethylsilyl)oxy>bicyclo<4.1.0>heptane

(1R,2S,3R,4S,5S,6S) 5-<(t-butyldimethylsilyl)oxy>-2,3,4-tris(benzyloxy)-1-<(trimethylsilyl)oxy>bicyclo<4.1.0>heptane

methyl 6-deoxy-6-iodo-2,3-bis-O-(phenylmethyl)-α-D-glucopyranoside

methyl 6-deoxy-6-iodo-2,3-bis-O-(phenylmethyl)-α-D-glucopyranoside

(1R,2S,3R,4S,5S,6S) 5-<(t-butyldimethylsilyl)oxy>-2,3,4-tris(benzyloxy)-1-<(trimethylsilyl)oxy>bicyclo<4.1.0>heptane

(1R,2S,3R,4S,5S,6S) 5-<(t-butyldimethylsilyl)oxy>-2,3,4-tris(benzyloxy)-1-<(trimethylsilyl)oxy>bicyclo<4.1.0>heptane

上游原料

methyl 2,3,4-tri-O-benzyl-α-d-xylo-hex-5-enopyranoside methyl 6-deoxy-6-iodo-2,3-bis-O-(phenylmethyl)-α-D-glucopyranoside

下游产品

(1S,2R,3S,4R,5S) 5-<(t-butyldimethylsilyl)oxy>-2,3,4-tris(benzyloxy) cycloheptane-1-ol (1R,2S,3R,4S,5S) 5-mesyloxy-2,3,4-tris(benzyloxy) cyclohept-6,7-en-1-ol (2S,3R,4S,5S) 5-mesyloxy-2,3,4-tris(benzyloxy) cyclohept-6,7-en-1-one (2S,3R,4S,5S) 5-<(t-butyldimethylsilyl)oxy>-2,3,4-tris(benzyloxy) cycloheptane-1-one (1R,2S,3R,4S,5R) 5-azido-2,3,4-tris(benzyloxy) cyclohept-6,7-en-1-ol (2S,3R,4S,5S) 5-azido-2,3,4-tris(benzyloxy) cyclohept-6,7-en-1-one (2S,3R,4S,5S) 5-hydroxy-2,3,4-tris(benzyloxy) cyclohept-6,7-en-1-one (2S,3R,4S,5S) 5-<(t-butyldimethylsilyl)oxy>-2,3,4-tris(benzyloxy) cyclohept-6,7-en-1-one