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(3aS,4S,6aR)-6-{{[(1,1-dimethylethyl)dimethylsilyl]oxy}methyl}-3a,6a-dihydro-2,2-dimethyl-4H-cyclopenta[d]-1,3-dioxol-4-ol
CAS号:160343-79-3
英文名:(3aS,4S,6aR)-6-{{[(1,1-dimethylethyl)dimethylsilyl]oxy}methyl}-3a,6a-dihydro-2,2-dimethyl-4H-cyclopenta[d]-1,3-dioxol-4-ol
分子式:C15H28O4Si
分子量:300.466
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合成路线
384343-93-5
(3aR,4R,5R,6S,6aS)-ethyl 5-benzylsulfanyl-6-hydroxy-2,2-dimethyltetrahydro-3aH-cyclopenta[1,3]dioxole-4-carboxylate
160343-79-3
(3aS,4S,6aR)-6-{{[(1,1-dimethylethyl)dimethylsilyl]oxy}methyl}-3a,6a-dihydro-2,2-dimethyl-4H-cyclopenta[d]-1,3-dioxol-4-ol
863554-32-9
(3aS,4S,5R,6R,6aR)-6-ethenyl-tetrahydro-2,2-dimethyl-4H-cyclopenta[d]-1,3-dioxole-4,5-diol 5-methanesulfonate
160343-79-3
(3aS,4S,6aR)-6-{{[(1,1-dimethylethyl)dimethylsilyl]oxy}methyl}-3a,6a-dihydro-2,2-dimethyl-4H-cyclopenta[d]-1,3-dioxol-4-ol
384343-96-8
(1R,2R,3S,4R,5R)-ethyl 2-benzylsulfanyl-3,4,5-trihydroxycyclopentanecarboxylate
160343-79-3
(3aS,4S,6aR)-6-{{[(1,1-dimethylethyl)dimethylsilyl]oxy}methyl}-3a,6a-dihydro-2,2-dimethyl-4H-cyclopenta[d]-1,3-dioxol-4-ol
863554-29-4
(3aR,4R,6S,7S,7aR)-tetrahydro-6-methoxy-7-[(4-methoxybenzyl)oxy]-2,2-dimethyl-4H-1,3-dioxolo[4,5-c]pyran-4-methanol
160343-79-3
(3aS,4S,6aR)-6-{{[(1,1-dimethylethyl)dimethylsilyl]oxy}methyl}-3a,6a-dihydro-2,2-dimethyl-4H-cyclopenta[d]-1,3-dioxol-4-ol
863554-40-9
methyl 2-O-allyl 6-O-benzyl-3,4-O-isopropylidene-α-D-altropyranoside
160343-79-3
(3aS,4S,6aR)-6-{{[(1,1-dimethylethyl)dimethylsilyl]oxy}methyl}-3a,6a-dihydro-2,2-dimethyl-4H-cyclopenta[d]-1,3-dioxol-4-ol
95188-91-3
methyl 2-O-allyl-4,6-O-benzylidene-α-D-altropyranoside
160343-79-3
(3aS,4S,6aR)-6-{{[(1,1-dimethylethyl)dimethylsilyl]oxy}methyl}-3a,6a-dihydro-2,2-dimethyl-4H-cyclopenta[d]-1,3-dioxol-4-ol
863554-21-6
methyl 2-O-allyl 6-O-benzyl-α-D-altropyranoside
160343-79-3
(3aS,4S,6aR)-6-{{[(1,1-dimethylethyl)dimethylsilyl]oxy}methyl}-3a,6a-dihydro-2,2-dimethyl-4H-cyclopenta[d]-1,3-dioxol-4-ol
384343-94-6
(3aR,6R,6aS)-ethyl 6-hydroxy-2,2-dimethyl-6,6a-dihydro-3aH-cyclopenta[1,3]dioxole-4-carboxylate
160343-79-3
(3aS,4S,6aR)-6-{{[(1,1-dimethylethyl)dimethylsilyl]oxy}methyl}-3a,6a-dihydro-2,2-dimethyl-4H-cyclopenta[d]-1,3-dioxol-4-ol
384343-86-6
(E)-ethyl (4R,5R)-4,5-dihydroxy-6-(4-methoxybenzyloxy)hex-2-enoate
160343-79-3
(3aS,4S,6aR)-6-{{[(1,1-dimethylethyl)dimethylsilyl]oxy}methyl}-3a,6a-dihydro-2,2-dimethyl-4H-cyclopenta[d]-1,3-dioxol-4-ol
384343-82-2
(E)-ethyl 3-[(4R,5R)-5-(4-methoxybenzyloxymethyl)-2,2-dimethyl-1,3-dioxolan-4-yl]prop-2-enoate
160343-79-3
(3aS,4S,6aR)-6-{{[(1,1-dimethylethyl)dimethylsilyl]oxy}methyl}-3a,6a-dihydro-2,2-dimethyl-4H-cyclopenta[d]-1,3-dioxol-4-ol
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上游原料
(3aR,4R,6S,7S,7aR)-tetrahydro-6-methoxy-7-[(4-methoxybenzyl)oxy]-2,2-dimethyl-4H-1,3-dioxolo[4,5-c]pyran-4-methanol
methyl 6-O-benzyl-3,4-O-isopropylidene-α-D-altropyranoside
(3aR,4R,6S,7S,7aR)-4-[(benzyloxy)methyl]-tetrahydro-6-methoxy-7-[(4-methoxybenzyl)oxy]-2,2-dimethyl-4H-1,3-dioxolo[4,5-c]pyran
methyl 2-O-allyl 6-O-benzyl-3,4-O-isopropylidene-α-D-altropyranoside
(((2S,2aR,2a1R,4S,4aR,4bR,7aS,7bR,8S)-8-bromo-6,6-dimethyloctahydro-4aH-2,4-methanofuro[2',3',4':3,4]pentaleno[1,2-d][1,3]dioxol-4a-yl)methoxy)(tert-butyl)dimethylsilane
methyl 2-O-allyl 6-O-benzyl-α-D-altropyranoside
(E)-ethyl 3-[(4R,5R)-5-(4-methoxybenzyloxymethyl)-2,2-dimethyl-1,3-dioxolan-4-yl]prop-2-enoate
(E)-ethyl (4R,5R)-4,5-bis(tert-butyldimethylsiloxy)-6-(4-methoxybenzyloxy)hex-2-enoate
(E)-ethyl (4R,5R)-4,5-dihydroxy-6-(4-methoxybenzyloxy)hex-2-enoate
(E)-ethyl (4R,5R)-4,5-bis(tert-butyldimethylsiloxy)-6-hydroxyhex-2-enoate
(3aS,4S,6aR)-5-Hydroxymethyl-2,2-dimethyl-4,6a-dihydro-3aH-cyclopenta[1,3]dioxol-4-ol
(3aR,4S,5R,6R,6aR)-4-ethenyl-tetrahydro-4-[(4-methoxybenzyl)oxy]-2,2-dimethyl-4H-cyclopenta[d]-1,3-dioxol-5-ol
(3aS,4S,5R,6R,6aR)-6-ethenyl-tetrahydro-2,2-dimethyl-4H-cyclopenta[d]-1,3-dioxole-4,5-diol 5-methanesulfonate
(3aR,4R,6S,7S,7aR)-4-ethenyl-tetrahydro-6-methoxy-7-[(4-methoxybenzyl)oxy]-2,2-dimethyl-4H-1,3-dioxolo[4,5-c]pyran
(1R,2R,3S,4R,5R)-ethyl 2-benzylsulfanyl-3,5-bis(tert-butyldimethylsiloxy)-4-hydroxycyclopentanecarboxylate
(3aS,4R,6aR)-3a,6a-dihydro-4-[(methoxycarbonyl)oxy]-2,2-dimethyl-4H-cyclopenta[d]-1,3-dioxole-6-methanol
(3aS,4S,6S,7S,7aR)-tetrahydro-6-methoxy-7-[(4-methoxybenzyl)oxy]-2,2-dimethyl-4H-1,3-dioxolo[4,5-c]pyran-4-carboxaldehyde
methyl 2-O-allyl-4,6-O-benzylidene-α-D-altropyranoside
(3aR,4R,5R,6S,6aR)-4-ethenyl-tetrahydro-4-[(4-methoxybenzyl)oxy]-2,2-dimethyl-4H-cyclopenta[d]-1,3-dioxol-5-ol methanesulfonate
(1R,2R,3S,4R,5R)-ethyl 2-benzylsulfanyl-3,4-bis(tert-butyldimethylsiloxy)-5-hydroxycyclopentanecarboxylate
((2S,2aR,2a1R,4S,4aS,6aS,7S)-7-bromo-2,2a,2a1,3,4,6a-hexahydro-4aH-2,4-methanopentaleno[1,6-bc]furan-4a-yl)methanol
(3aS,4R,6aR)-6-{{[(1,1-dimethylethyl)dimethylsilyl]oxy}methyl}-3a,6a-dihydro-2,2-dimethyl-4H-cyclopenta[d]-1,3-dioxol-4-ol methyl carbonate
(3aR,4S,5R,6R,6aR)-6-ethenyl-tetrahydro-2,2-dimethyl-4H-cyclopenta[d]-1,3-dioxole-4,5-diol 5-methanesulfonate 4-(methyl carbonate)
(3aR,6R,6aS)-ethyl 6-hydroxy-2,2-dimethyl-6,6a-dihydro-3aH-cyclopenta[1,3]dioxole-4-carboxylate
(3aR,4R,5R,6S,6aS)-ethyl 5-benzylsulfanyl-6-hydroxy-2,2-dimethyltetrahydro-3aH-cyclopenta[1,3]dioxole-4-carboxylate
(3aS,4R,6aR)-3a,6a-dihydro-4-[(methoxycarbonyl)oxy]-2,2-dimethyl-4H-cyclopenta[d]-1,3-dioxole-6-carboxaldehyde
(1R,2R,3S,4R,5R)-ethyl 2-benzylsulfanyl-3,4,5-trihydroxycyclopentanecarboxylate
(3aR,6aR)-ethyl 2,2-dimethyl-6-oxo-6,6a-dihydro-3aH-cyclopenta[1,3]dioxole-4-carboxylate
(3aR,6aR)-5-(hydroxymethyl)-2,2-dimethyl-3a,6a-dihydrocyclopenta[1,2-d]1,3-dioxalan-4-one
下游产品
(3aR,4R,5S,6R,6aS)-4-Hydroxymethyl-2-((2S,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-ylamino)-4,5,6,6a-tetrahydro-3aH-cyclopentaoxazole-4,5,6-triol
<1R-(1α,2β,3β,4β,5β)>-5-Azido-1-(benzyloxy)-1-<(benzyloxy)methyl>-2,3-(isopropylidenedioxy)-4-<(4-methoxybenzyl)oxy>cyclopentane
瓶型酵母A
(2S,5R)-2-(2-(((3aR,6S,6aR)-6-(tert-butyldimethylsilyloxy)-2,2-dimethyl-6,6a-dihydro-3aH-cyclopenta[d][1,3]dioxol-4-yl)methoxy)ethyl)-3,6-diethoxy-5-isopropyl-2,5-dihydropyrazine
<1R-(1α,2β,3β,4β,5β)>-5-<<(Benzylamino)thiocarbonyl>amino>-1,1':2,3-bis(isopropylidenedioxy)-1-methylcyclopentan-4-ol
<1R-(1α,2β,3β,4β,5β)>-<1-(Benzyloxy)-1-<(benzyloxy)methyl>-2,3,4-trihydroxycyclopent-5-yl>amino (2,3,4,6-tetra-O-benzyl-1-deoxy-α-D-glucopyranos-1-yl)amino thioketone
2-(((3aR,6S,6aR)-6-(tert-butyldimethylsilyloxy)-2,2-dimethyl-6,6a-dihydro-3aH-cyclopenta[d][1,3]dioxol-4-yl)methoxy)ethanol
(3aS,4S,6aR)-6-((2-((2S,5R)-3,6-diethoxy-5-isopropyl-2,5-dihydropyrazin-2-yl)ethoxy)methyl)-2,2-dimethyl-4,6a-dihydro-3aH-cyclopenta[d][1,3]dioxol-4-ol
((3aR,6S,6aR)-6-(tert-butyldimethylsilyloxy)-2,2-dimethyl-6,6a-dihydro-3aH-cyclopenta[d][1,3]dioxol-4-yl)methanol
2-(((3aR,6S,6aR)-6-(tert-butyldimethylsilyloxy)-2,2-dimethyl-6,6a-dihydro-3aH-cyclopenta[d][1,3]dioxol-4-yl)methoxy)ethyl 4-methylbenzenesulfonate
9-((3aS,4R,6aR)-6-((2-((2S,5R)-3,6-diethoxy-5-isopropyl-2,5-dihydropyrazin-2-yl)ethoxy)methyl)-2,2-dimethyl-4,6a-dihydro-3aH-cyclopenta[d][1,3]dioxol-4-yl)-9H-purin-6-bis(tert-butoxylcarbonyl)amine
((3aR,4S,6aR)-6-(allyloxymethyl)-2,2-dimethyl-4,6a-dihydro-3aH-cyclopenta[d][1,3]dioxol-4-yloxy)(tert-butyl)dimethylsilane
<3aR-(3aα,4α,5β,6β,6aα)>-4-(Benzyloxy)-4-<(benzyloxy)methyl>-2-<(2,3,4,6-tetra-O-benzyl-1-deoxy-α-D-glucopyranos-1-yl)amino>-3a,5,6,6a-tetrahydro-4H-cyclopentoxazole-5,6-diol
<1R-(1α,2β,3β,4β,5β)>-<1-<(Benzyloxy)methyl>-1,2,3,4-tetrahydroxycyclopent-5-yl>amino benzylamino thioketone
<3aR-(3aα,4α,5β,6β,6aα)>-4-<(Benzyloxy)methyl>-2-(benzylamino)-3a,5,6,6aα-tetrahydro-4H-cyclopentoxazole-4,5,6-triol
<1R-(1α,2β,3β,4β,5β)>-5-Azido-1-(hydroxymethyl)-2,3-(isopropylidenedioxy)-4-<(4-methoxybenzyl)oxy>cyclopentan-1-ol
<1R-(1α,2β,3β,4β,5β)>-5-Amino-1,1':2,3-bis(isopropylidenedioxy)-1-methylcyclopentan-4-ol
1-((1R,2R,3S,4S,5S)-2,3,4,5-Tetrahydroxy-2-hydroxymethyl-cyclopentyl)-3-((2S,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-thiourea