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methyl 3'-((4R,5R)-5-((5R)-5-((tert-butyldimethylsilyl)oxy)-1-hydroxyhex-2-yn-1-yl)-2,2-dimethyl-1,3-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate

CAS号：1606132-36-8

英文名：methyl 3'-((4R,5R)-5-((5R)-5-((tert-butyldimethylsilyl)oxy)-1-hydroxyhex-2-yn-1-yl)-2,2-dimethyl-1,3-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate

分子式：C34H48O9Si

分子量：628.825

合成路线

1606132-34-6

3-hydroxy-5-methoxy-3'-((4R,5S)-5-(methoxycarbonyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-[1,1'-biphenyl]-2-carboxylic acid

1606132-36-8

methyl 3'-((4R,5R)-5-((5R)-5-((tert-butyldimethylsilyl)oxy)-1-hydroxyhex-2-yn-1-yl)-2,2-dimethyl-1,3-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate

532394-23-3

5-hydroxy-7-methoxy-2,2-dimethyl-benzo[1,3]dioxin-4-one

1606132-36-8

methyl 3'-((4R,5R)-5-((5R)-5-((tert-butyldimethylsilyl)oxy)-1-hydroxyhex-2-yn-1-yl)-2,2-dimethyl-1,3-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate

460348-12-3

(R)-5-(trimethylsilyl)pent-4-yn-2-ol

1606132-36-8

methyl 3'-((4R,5R)-5-((5R)-5-((tert-butyldimethylsilyl)oxy)-1-hydroxyhex-2-yn-1-yl)-2,2-dimethyl-1,3-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate

1606132-26-6

5-(3-(hydroxymethyl)phenyl)-7-methoxy-2,2-dimethyl-4H-benzo[d][1,3]dioxin-4-one

1606132-36-8

methyl 3'-((4R,5R)-5-((5R)-5-((tert-butyldimethylsilyl)oxy)-1-hydroxyhex-2-yn-1-yl)-2,2-dimethyl-1,3-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate

1606132-27-7

1606132-36-8

methyl 3'-((4R,5R)-5-((5R)-5-((tert-butyldimethylsilyl)oxy)-1-hydroxyhex-2-yn-1-yl)-2,2-dimethyl-1,3-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate

1606132-29-9

methyl (2S,3R)-2,3-dihydroxy-3-(3-(7-methoxy-2,2-dimethyl-4-oxo-4H-benzo[d][1,3]dioxin-5-yl)phenyl)propanoate

1606132-36-8

methyl 3'-((4R,5R)-5-((5R)-5-((tert-butyldimethylsilyl)oxy)-1-hydroxyhex-2-yn-1-yl)-2,2-dimethyl-1,3-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate

1606132-30-2

1606132-36-8

methyl 3'-((4R,5R)-5-((5R)-5-((tert-butyldimethylsilyl)oxy)-1-hydroxyhex-2-yn-1-yl)-2,2-dimethyl-1,3-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate

1606132-31-3

1606132-36-8

methyl 3'-((4R,5R)-5-((5R)-5-((tert-butyldimethylsilyl)oxy)-1-hydroxyhex-2-yn-1-yl)-2,2-dimethyl-1,3-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate

1606132-32-4

1606132-36-8

methyl 3'-((4R,5R)-5-((5R)-5-((tert-butyldimethylsilyl)oxy)-1-hydroxyhex-2-yn-1-yl)-2,2-dimethyl-1,3-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate

1606132-33-5

methyl 3'-((4R,5R)-5-(hydroxymethyl)-2,2-dimethyl-1,3-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate

1606132-36-8

methyl 3'-((4R,5R)-5-((5R)-5-((tert-butyldimethylsilyl)oxy)-1-hydroxyhex-2-yn-1-yl)-2,2-dimethyl-1,3-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate

上游原料

methyl (2S,3R)-2,3-dihydroxy-3-(3-(7-methoxy-2,2-dimethyl-4-oxo-4H-benzo[d][1,3]dioxin-5-yl)phenyl)propanoate (E)-methyl 3-(3-(7-methoxy-2,2-dimethyl-4-oxo-4H-benzo[d][1,3]dioxin-5-yl)phenyl)acrylate 5-(3-(hydroxymethyl)phenyl)-7-methoxy-2,2-dimethyl-4H-benzo[d][1,3]dioxin-4-one 3-hydroxy-5-methoxy-3'-((4R,5S)-5-(methoxycarbonyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-[1,1'-biphenyl]-2-carboxylic acid (R)-5-(trimethylsilyl)pent-4-yn-2-ol 5-hydroxy-7-methoxy-2,2-dimethyl-benzo[1,3]dioxin-4-one methyl 3'-((4R,5R)-5-(hydroxymethyl)-2,2-dimethyl-1,3-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate

下游产品

methyl 3'-((4R,5R)-5-((5R,Z)-5-((tert-butyldimethylsilyl)oxy)-1-((4-methoxybenzyl)oxy)hex-2-en-2-yl)-2,2-dimethyl-1,3-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate methyl 3'-((4R,5R)-5-((5R,Z)-5-((tert-butyldimethylsilyl)oxy)-1-hydroxyhex-2-en-1-yl)-2,2-dimethyl-1,3-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate