百科

Acetic acid (2R,3S,4R,5R,6S)-3-acetoxy-2-acetoxymethyl-5-acetylamino-6-((2S,3S,4S,5R,6R)-5-benzyloxy-6-benzyloxymethyl-2,4-dimethoxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yl ester

Acetic acid (2R,3S,4R,5R,6S)-3-acetoxy-2-acetoxymethyl-5-acetylamino-6-((2S,3S,4S,5R,6R)-5-benzyloxy-6-benzyloxymethyl-2,4-dimethoxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yl ester

CAS号：161767-12-0

英文名：Acetic acid (2R,3S,4R,5R,6S)-3-acetoxy-2-acetoxymethyl-5-acetylamino-6-((2S,3S,4S,5R,6R)-5-benzyloxy-6-benzyloxymethyl-2,4-dimethoxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yl ester

分子式：C36H47NO14

分子量：717.757

合成路线

methyl 2,3-O-isopropylidene-4,6-di-O-benzyl-α-D-mannopyranoside

methyl 2,3-O-isopropylidene-4,6-di-O-benzyl-α-D-mannopyranoside

Acetic acid (2R,3S,4R,5R,6S)-3-acetoxy-2-acetoxymethyl-5-acetylamino-6-((2S,3S,4S,5R,6R)-5-benzyloxy-6-benzyloxymethyl-2,4-dimethoxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yl ester

Acetic acid (2R,3S,4R,5R,6S)-3-acetoxy-2-acetoxymethyl-5-acetylamino-6-((2S,3S,4S,5R,6R)-5-benzyloxy-6-benzyloxymethyl-2,4-dimethoxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yl ester

methyl O-(2-phthalimido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranosyl)-(1<*>2)-3-O-methyl-4,6-di-O-benzyl-α-D-mannopyranoside

methyl O-(2-phthalimido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranosyl)-(1<*>2)-3-O-methyl-4,6-di-O-benzyl-α-D-mannopyranoside

Acetic acid (2R,3S,4R,5R,6S)-3-acetoxy-2-acetoxymethyl-5-acetylamino-6-((2S,3S,4S,5R,6R)-5-benzyloxy-6-benzyloxymethyl-2,4-dimethoxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yl ester

Acetic acid (2R,3S,4R,5R,6S)-3-acetoxy-2-acetoxymethyl-5-acetylamino-6-((2S,3S,4S,5R,6R)-5-benzyloxy-6-benzyloxymethyl-2,4-dimethoxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yl ester

上游原料

methyl 2,3-O-isopropylidene-4,6-di-O-benzyl-α-D-mannopyranoside methyl O-(2-phthalimido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranosyl)-(1<*>2)-3-O-methyl-4,6-di-O-benzyl-α-D-mannopyranoside

下游产品

octyl O-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranosyl)-(1<*>2)-O-(3-O-methyl-4,6-di-O-acetyl-β-D-mannopyranosyl)-(1<*>6)-2,3,4-tri-O-acetyl-β-D-glucopyranoside