百科

(2S,3R,4aS,6R,7S,8aR)-3-Benzyloxy-2-(2-benzyloxy-ethyl)-7-(tert-butyl-dimethyl-silanyloxy)-6-[4-(tert-butyl-dimethyl-silanyloxy)-butyl]-2,4a,6-trimethyl-octahydro-pyrano[3,2-b]pyran

CAS号：161984-57-2

英文名：(2S,3R,4aS,6R,7S,8aR)-3-Benzyloxy-2-(2-benzyloxy-ethyl)-7-(tert-butyl-dimethyl-silanyloxy)-6-[4-(tert-butyl-dimethyl-silanyloxy)-butyl]-2,4a,6-trimethyl-octahydro-pyrano[3,2-b]pyran

分子式：C43H72O6Si2

分子量：741.199

合成路线

161984-56-1

(2S,3R,4aS,6R,7S,8aR)-3-Benzyloxy-2-(2-benzyloxy-ethyl)-7-(tert-butyl-dimethyl-silanyloxy)-6-[(Z)-4-(tert-butyl-dimethyl-silanyloxy)-but-1-enyl]-2,4a,6-trimethyl-octahydro-pyrano[3,2-b]pyran

161984-57-2

(2S,3R,4aS,6R,7S,8aR)-3-Benzyloxy-2-(2-benzyloxy-ethyl)-7-(tert-butyl-dimethyl-silanyloxy)-6-[4-(tert-butyl-dimethyl-silanyloxy)-butyl]-2,4a,6-trimethyl-octahydro-pyrano[3,2-b]pyran

131311-18-7

161984-57-2

(2S,3R,4aS,6R,7S,8aR)-3-Benzyloxy-2-(2-benzyloxy-ethyl)-7-(tert-butyl-dimethyl-silanyloxy)-6-[4-(tert-butyl-dimethyl-silanyloxy)-butyl]-2,4a,6-trimethyl-octahydro-pyrano[3,2-b]pyran

上游原料

(2S,3R,4aS,6R,7S,8aR)-3-Benzyloxy-2-(2-benzyloxy-ethyl)-7-(tert-butyl-dimethyl-silanyloxy)-6-[(Z)-4-(tert-butyl-dimethyl-silanyloxy)-but-1-enyl]-2,4a,6-trimethyl-octahydro-pyrano[3,2-b]pyran

下游产品

4-[(2R,3S,4aR,6S,7R,8aS)-7-Benzyloxy-6-(2-benzyloxy-ethyl)-3-(tert-butyl-dimethyl-silanyloxy)-2,6,8a-trimethyl-octahydro-pyrano[3,2-b]pyran-2-yl]-butan-1-ol (2R,3S,4aR,5aS,7aR,8aS,10R,11S,12aR,13aS,14aR,15R,16aS)-10-(benzyloxy)-11-(2-(benzyloxy)ethyl)-3,7a,8a,11,15-pentamethyl-2-(((2S,3S)-3-vinyloxiran-2-yl)methyl)octadecahydro-2H-pyrano[2',3':5,6]pyrano[3,2-b]pyrano[2',3':6,7]oxepino[2,3-f]oxepin-3-ol (2S,3R,4aS,5aR,7aS,12R,12aR,13aS,14aR)-3-(benzyloxy)-2-(2-(benzyloxy)ethyl)-2,4a,5a,12-tetramethyltetradecahydrooxepino[3,2-b]pyrano[2',3':5,6]pyrano[2,3-f]oxepin-9(2H)-one (2S,3R,4aS,5aR,7aS,12S,12aR,13aS,14aR)-3-(benzyloxy)-2-(2-(benzyloxy)ethyl)-2,4a,5a,12-tetramethyltetradecahydrooxepino[3,2-b]pyrano[2',3':5,6]pyrano[2,3-f]oxepin-9(2H)-one 3-((2S,3R,4aS,5aR,7aS,9R,10S,12R,12aR,13aS,14aR)-3-(benzyloxy)-2-(2-(benzyloxy)ethyl)-2,4a,5a,12-tetramethyl-10-((triethylsilyl)oxy)hexadecahydrooxepino[3,2-b]pyrano[2',3':5,6]pyrano[2,3-f]oxepin-9-yl)-2-((tert-butyldimethylsilyl)oxy)-2-methylpropan-1-ol 3-((2S,3R,4aS,5aR,7aS,9R,10S,12R,12aR,13aS,14aR)-3-(benzyloxy)-2-(2-(benzyloxy)ethyl)-10-hydroxy-2,4a,5a,12-tetramethylhexadecahydrooxepino[3,2-b]pyrano[2',3':5,6]pyrano[2,3-f]oxepin-9-yl)-2-((tert-butyldimethylsilyl)oxy)-2-methylpropyl pivalate methyl (E)-5-((2S,3R,4aS,5aR,7aS,9R,10S,12R,12aR,13aS,14aR)-3-(benzyloxy)-2-(2-(benzyloxy)ethyl)-10-hydroxy-2,4a,5a,12-tetramethylhexadecahydrooxepino[3,2-b]pyrano[2',3':5,6]pyrano[2,3-f]oxepin-9-yl)-4-((tert-butyldimethylsilyl)oxy)-4-methylpent-2-enoate (2S,3R,4aS,5aR,7aS,12R,12aR,13aS,14aR)-3-(benzyloxy)-2-(2-(benzyloxy)ethyl)-2,4a,5a,12-tetramethyl-2,3,4,4a,5a,6,7,7a,11,12,12a,13a,14,14a-tetradecahydrooxepino[3,2-b]pyrano[2',3':5,6]pyrano[2,3-f]oxepin-9-yl trifluoromethanesulfonate 3-((2S,3R,4aS,5aR,7aS,9R,10S,12R,12aR,13aS,14aR)-3-(benzyloxy)-2-(2-(benzyloxy)ethyl)-2,4a,5a,12-tetramethyl-10-((triethylsilyl)oxy)hexadecahydrooxepino[3,2-b]pyrano[2',3':5,6]pyrano[2,3-f]oxepin-9-yl)-2-((tert-butyldimethylsilyl)oxy)-2-methylpropanal