百科

(4S,5R,6R,E)-6-(tert-butyldimethylsilyloxy)-5-methoxy-2,4-dimethylhept-2-en-1-ol

(4S,5R,6R,E)-6-(tert-butyldimethylsilyloxy)-5-methoxy-2,4-dimethylhept-2-en-1-ol

CAS号：1621332-24-8

英文名：(4S,5R,6R,E)-6-(tert-butyldimethylsilyloxy)-5-methoxy-2,4-dimethylhept-2-en-1-ol

分子式：C16H34O3Si

分子量：302.525

合成路线

(2R,3R,4R)-4-(tert-butyldimethylsilyloxy)-3-methoxy-2-methylpentanal

(2R,3R,4R)-4-(tert-butyldimethylsilyloxy)-3-methoxy-2-methylpentanal

(4S,5R,6R,E)-6-(tert-butyldimethylsilyloxy)-5-methoxy-2,4-dimethylhept-2-en-1-ol

(4S,5R,6R,E)-6-(tert-butyldimethylsilyloxy)-5-methoxy-2,4-dimethylhept-2-en-1-ol

{(4R,5R)-5-[(S)-1-(benzyloxy)propan-2-yl]-2,2-dimethyl-1,3-dioxolan-4-yl}methyl-4-methylbenzenesulfonate

{(4R,5R)-5-[(S)-1-(benzyloxy)propan-2-yl]-2,2-dimethyl-1,3-dioxolan-4-yl}methyl-4-methylbenzenesulfonate

(4S,5R,6R,E)-6-(tert-butyldimethylsilyloxy)-5-methoxy-2,4-dimethylhept-2-en-1-ol

(4S,5R,6R,E)-6-(tert-butyldimethylsilyloxy)-5-methoxy-2,4-dimethylhept-2-en-1-ol

(1R,2S)-3-(benzyloxy)-2-methyl-1-[(R)-oxiran-2-yl]propan-1-ol

(1R,2S)-3-(benzyloxy)-2-methyl-1-[(R)-oxiran-2-yl]propan-1-ol

(4S,5R,6R,E)-6-(tert-butyldimethylsilyloxy)-5-methoxy-2,4-dimethylhept-2-en-1-ol

(4S,5R,6R,E)-6-(tert-butyldimethylsilyloxy)-5-methoxy-2,4-dimethylhept-2-en-1-ol

ethyl (4R,2E)-5-(benzyloxy)-4-methylpent-2-enoate

ethyl (4R,2E)-5-(benzyloxy)-4-methylpent-2-enoate

(4S,5R,6R,E)-6-(tert-butyldimethylsilyloxy)-5-methoxy-2,4-dimethylhept-2-en-1-ol

(4S,5R,6R,E)-6-(tert-butyldimethylsilyloxy)-5-methoxy-2,4-dimethylhept-2-en-1-ol

上游原料

{(4R,5R)-5-[(S)-1-(benzyloxy)propan-2-yl]-2,2-dimethyl-1,3-dioxolan-4-yl}methyl-4-methylbenzenesulfonate ethyl (4R,2E)-5-(benzyloxy)-4-methylpent-2-enoate (2R,3R,4R)-4-(tert-butyldimethylsilyloxy)-3-methoxy-2-methylpentanal (1R,2S)-3-(benzyloxy)-2-methyl-1-[(R)-oxiran-2-yl]propan-1-ol

下游产品

methyl 2-{(2R,5S,6S)-6-[(2E,4Z,6S,8E,10S,11R,12R)-12-(tert-Butyldimethylsilyloxy)-11-methoxy-6,8,10-trimethyltrideca-2,4,8-trien-2-yl]-5-methyltetrahydro-2H-pyran-2-yl}acetate methyl 2-((2R,5S,6S)-6-((2E,4E,6S,8E,10S,11R,12R)-12-(tert-butyldimethylsilyloxy)-11-methoxy-6,8,10-trimethyltrideca-2,4,8-trien-2-yl)-5-methyltetrahydro-2H-pyran-2-yl)-acetate