百科

(1S,6S,7S,9S,10R)-9-(tert-butyldimethylsiloxy)-6,10-dimethylbicyclo<5.3.0>decan-2-one

(1S,6S,7S,9S,10R)-9-(tert-butyldimethylsiloxy)-6,10-dimethylbicyclo<5.3.0>decan-2-one

CAS号：162211-37-2

英文名：(1S,6S,7S,9S,10R)-9-(tert-butyldimethylsiloxy)-6,10-dimethylbicyclo<5.3.0>decan-2-one

分子式：C18H34O2Si

分子量：310.547

合成路线

(1S,5S,6S,8S,9R)-8-hydroxy-5,9-dimethylbicyclo<4.3.0>non-3-ene-2-one

(1S,5S,6S,8S,9R)-8-hydroxy-5,9-dimethylbicyclo<4.3.0>non-3-ene-2-one

(1S,6S,7S,9S,10R)-9-(tert-butyldimethylsiloxy)-6,10-dimethylbicyclo<5.3.0>decan-2-one

(1S,6S,7S,9S,10R)-9-(tert-butyldimethylsiloxy)-6,10-dimethylbicyclo<5.3.0>decan-2-one

(1S,5S,6S,8R,9R)-8-hydroxy-5,9-dimethylbicyclo<4.3.0>nonan-2-one

(1S,5S,6S,8R,9R)-8-hydroxy-5,9-dimethylbicyclo<4.3.0>nonan-2-one

(1S,6S,7S,9S,10R)-9-(tert-butyldimethylsiloxy)-6,10-dimethylbicyclo<5.3.0>decan-2-one

(1S,6S,7S,9S,10R)-9-(tert-butyldimethylsiloxy)-6,10-dimethylbicyclo<5.3.0>decan-2-one

(1S,5S,6S,8S,9R)-8-hydroxy-5,9-dimethylbicyclo<4.3.0>nonan-2-one

(1S,5S,6S,8S,9R)-8-hydroxy-5,9-dimethylbicyclo<4.3.0>nonan-2-one

(1S,6S,7S,9S,10R)-9-(tert-butyldimethylsiloxy)-6,10-dimethylbicyclo<5.3.0>decan-2-one

(1S,6S,7S,9S,10R)-9-(tert-butyldimethylsiloxy)-6,10-dimethylbicyclo<5.3.0>decan-2-one

(1S,5S,6S,8R,9R)-5,9-dimethyl-2-oxobicyclo<4.3.0>nonan-8-yl benzoate

(1S,5S,6S,8R,9R)-5,9-dimethyl-2-oxobicyclo<4.3.0>nonan-8-yl benzoate

(1S,6S,7S,9S,10R)-9-(tert-butyldimethylsiloxy)-6,10-dimethylbicyclo<5.3.0>decan-2-one

(1S,6S,7S,9S,10R)-9-(tert-butyldimethylsiloxy)-6,10-dimethylbicyclo<5.3.0>decan-2-one

(1S,5S,6S,8S,9R)-5,9-dimethyl-2-oxobicyclo<4.3.0>nonan-8-yl benzoate

(1S,5S,6S,8S,9R)-5,9-dimethyl-2-oxobicyclo<4.3.0>nonan-8-yl benzoate

(1S,6S,7S,9S,10R)-9-(tert-butyldimethylsiloxy)-6,10-dimethylbicyclo<5.3.0>decan-2-one

(1S,6S,7S,9S,10R)-9-(tert-butyldimethylsiloxy)-6,10-dimethylbicyclo<5.3.0>decan-2-one

上游原料

(1S,5S,6S,8S,9R)-5,9-dimethyl-2-oxobicyclo<4.3.0>nonan-8-yl benzoate (1S,5S,6S,8S,9R)-8-hydroxy-5,9-dimethylbicyclo<4.3.0>non-3-ene-2-one (1S,5S,6S,8R,9R)-5,9-dimethyl-2-oxobicyclo<4.3.0>nonan-8-yl benzoate (1S,5S,6S,8R,9R)-8-hydroxy-5,9-dimethylbicyclo<4.3.0>nonan-2-one (1S,5S,6S,8S,9R)-8-hydroxy-5,9-dimethylbicyclo<4.3.0>nonan-2-one

下游产品

(1S,6S,7S,9S,10R)-9-hydroxy-6,10-dimethylbicyclo<5.3.0>decan-2-one (6S,7S)-6,10-dimethylbicyclo[5.3.0]dec-1(10)-en-2-one (6S,7S)-6,10-dimethylbicyclo<5.3.0>dec-1(10)-en-2-one toluene-p-sulfonylhydrazone