百科

4-((R,E)-1-((1S,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)hept-1-en-5-yn-3-yloxy)-4-oxobutyl hept-5-ynoate

4-((R,E)-1-((1S,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)hept-1-en-5-yn-3-yloxy)-4-oxobutyl hept-5-ynoate

CAS号：1623791-23-0

英文名：4-((R,E)-1-((1S,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)hept-1-en-5-yn-3-yloxy)-4-oxobutyl hept-5-ynoate

分子式：C40H68O6Si2

分子量：701.135

合成路线

(R)-((E)-1-((1S,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)hex-1-en-5-yn-3-yloxy)(phenyl)methyl acetate

(R)-((E)-1-((1S,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)hex-1-en-5-yn-3-yloxy)(phenyl)methyl acetate

4-((R,E)-1-((1S,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)hept-1-en-5-yn-3-yloxy)-4-oxobutyl hept-5-ynoate

4-((R,E)-1-((1S,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)hept-1-en-5-yn-3-yloxy)-4-oxobutyl hept-5-ynoate

4-hydroxybutyl hept-5-ynoate

4-hydroxybutyl hept-5-ynoate

4-((R,E)-1-((1S,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)hept-1-en-5-yn-3-yloxy)-4-oxobutyl hept-5-ynoate

4-((R,E)-1-((1S,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)hept-1-en-5-yn-3-yloxy)-4-oxobutyl hept-5-ynoate

(E)-3-((1S,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)acrylaldehyde

(E)-3-((1S,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)acrylaldehyde

4-((R,E)-1-((1S,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)hept-1-en-5-yn-3-yloxy)-4-oxobutyl hept-5-ynoate

4-((R,E)-1-((1S,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)hept-1-en-5-yn-3-yloxy)-4-oxobutyl hept-5-ynoate

((1R,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)methanol

((1R,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)methanol

4-((R,E)-1-((1S,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)hept-1-en-5-yn-3-yloxy)-4-oxobutyl hept-5-ynoate

4-((R,E)-1-((1S,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)hept-1-en-5-yn-3-yloxy)-4-oxobutyl hept-5-ynoate

上游原料

4-hydroxybutyl hept-5-ynoate (R)-((E)-1-((1S,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)hex-1-en-5-yn-3-yloxy)(phenyl)methyl acetate (E)-3-((1S,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)acrylaldehyde ((1R,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)methanol

下游产品

(R,5Z,9E)-10-((1S,2R,3R,5S)-3,5-dihydroxy-2-((Z)-pent-2-en-1-yl)cyclopentyl)-8-hydroxydeca-5,9-dienoic acid