百科

(R,Z)-14-((E)-2-((1S,2R,3R,5S)-3,5-bis((tert-butyldimethylsilyl)oxy)-2-((Z)-pent-2-en-1-yl)cyclopentyl)vinyl)-1,6-dioxacyclotetradec-11-ene-2,7-dione

(R,Z)-14-((E)-2-((1S,2R,3R,5S)-3,5-bis((tert-butyldimethylsilyl)oxy)-2-((Z)-pent-2-en-1-yl)cyclopentyl)vinyl)-1,6-dioxacyclotetradec-11-ene-2,7-dione

CAS号：1623791-32-1

英文名：(R,Z)-14-((E)-2-((1S,2R,3R,5S)-3,5-bis((tert-butyldimethylsilyl)oxy)-2-((Z)-pent-2-en-1-yl)cyclopentyl)vinyl)-1,6-dioxacyclotetradec-11-ene-2,7-dione

分子式：C36H64O6Si2

分子量：649.061

合成路线

(R)-((E)-1-((1S,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)hex-1-en-5-yn-3-yloxy)(phenyl)methyl acetate

(R)-((E)-1-((1S,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)hex-1-en-5-yn-3-yloxy)(phenyl)methyl acetate

(R,Z)-14-((E)-2-((1S,2R,3R,5S)-3,5-bis((tert-butyldimethylsilyl)oxy)-2-((Z)-pent-2-en-1-yl)cyclopentyl)vinyl)-1,6-dioxacyclotetradec-11-ene-2,7-dione

(R,Z)-14-((E)-2-((1S,2R,3R,5S)-3,5-bis((tert-butyldimethylsilyl)oxy)-2-((Z)-pent-2-en-1-yl)cyclopentyl)vinyl)-1,6-dioxacyclotetradec-11-ene-2,7-dione

4-hydroxybutyl hept-5-ynoate

4-hydroxybutyl hept-5-ynoate

(R,Z)-14-((E)-2-((1S,2R,3R,5S)-3,5-bis((tert-butyldimethylsilyl)oxy)-2-((Z)-pent-2-en-1-yl)cyclopentyl)vinyl)-1,6-dioxacyclotetradec-11-ene-2,7-dione

(R,Z)-14-((E)-2-((1S,2R,3R,5S)-3,5-bis((tert-butyldimethylsilyl)oxy)-2-((Z)-pent-2-en-1-yl)cyclopentyl)vinyl)-1,6-dioxacyclotetradec-11-ene-2,7-dione

(E)-3-((1S,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)acrylaldehyde

(E)-3-((1S,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)acrylaldehyde

(R,Z)-14-((E)-2-((1S,2R,3R,5S)-3,5-bis((tert-butyldimethylsilyl)oxy)-2-((Z)-pent-2-en-1-yl)cyclopentyl)vinyl)-1,6-dioxacyclotetradec-11-ene-2,7-dione

(R,Z)-14-((E)-2-((1S,2R,3R,5S)-3,5-bis((tert-butyldimethylsilyl)oxy)-2-((Z)-pent-2-en-1-yl)cyclopentyl)vinyl)-1,6-dioxacyclotetradec-11-ene-2,7-dione

((1R,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)methanol

((1R,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)methanol

(R,Z)-14-((E)-2-((1S,2R,3R,5S)-3,5-bis((tert-butyldimethylsilyl)oxy)-2-((Z)-pent-2-en-1-yl)cyclopentyl)vinyl)-1,6-dioxacyclotetradec-11-ene-2,7-dione

(R,Z)-14-((E)-2-((1S,2R,3R,5S)-3,5-bis((tert-butyldimethylsilyl)oxy)-2-((Z)-pent-2-en-1-yl)cyclopentyl)vinyl)-1,6-dioxacyclotetradec-11-ene-2,7-dione

上游原料

4-hydroxybutyl hept-5-ynoate (R)-((E)-1-((1S,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)hex-1-en-5-yn-3-yloxy)(phenyl)methyl acetate (E)-3-((1S,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)acrylaldehyde ((1R,2R,3R,5S)-3,5-bis(tert-butyldimethylsilyloxy)-2-((Z)-pent-2-enyl)cyclopentyl)methanol

下游产品

(R,5Z,9E)-10-((1S,2R,3R,5S)-3,5-dihydroxy-2-((Z)-pent-2-en-1-yl)cyclopentyl)-8-hydroxydeca-5,9-dienoic acid