百科

(1R,2S,6S,7R,8R)-7-((2S,3R,4S,5S,6R)-4-Allyloxy-3,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-4-phenyl-3,5,10,11-tetraoxa-tricyclo[6.2.1.02,6]undecane

(1R,2S,6S,7R,8R)-7-((2S,3R,4S,5S,6R)-4-Allyloxy-3,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-4-phenyl-3,5,10,11-tetraoxa-tricyclo[6.2.1.02,6]undecane

CAS号：162710-67-0

英文名：(1R,2S,6S,7R,8R)-7-((2S,3R,4S,5S,6R)-4-Allyloxy-3,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-4-phenyl-3,5,10,11-tetraoxa-tricyclo[6.2.1.02,6]undecane

分子式：C43H46O10

分子量：722.819

合成路线

O-(β-D-Galactopyranosyl)-(1->4)-1,6-anhydro-2,3-O-endo/exo-benzylidene-β-D-mannopyranose

O-(β-D-Galactopyranosyl)-(1->4)-1,6-anhydro-2,3-O-endo/exo-benzylidene-β-D-mannopyranose

(1R,2S,6S,7R,8R)-7-((2S,3R,4S,5S,6R)-4-Allyloxy-3,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-4-phenyl-3,5,10,11-tetraoxa-tricyclo[6.2.1.02,6]undecane

(1R,2S,6S,7R,8R)-7-((2S,3R,4S,5S,6R)-4-Allyloxy-3,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-4-phenyl-3,5,10,11-tetraoxa-tricyclo[6.2.1.02,6]undecane

2,3,4,6-tetra-O-benzoyl-α,b-D-galactopyranosyl trichloroacetimidate

2,3,4,6-tetra-O-benzoyl-α,b-D-galactopyranosyl trichloroacetimidate

(1R,2S,6S,7R,8R)-7-((2S,3R,4S,5S,6R)-4-Allyloxy-3,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-4-phenyl-3,5,10,11-tetraoxa-tricyclo[6.2.1.02,6]undecane

(1R,2S,6S,7R,8R)-7-((2S,3R,4S,5S,6R)-4-Allyloxy-3,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-4-phenyl-3,5,10,11-tetraoxa-tricyclo[6.2.1.02,6]undecane

O-(2,3,4,6-Tetra-O-benzoyl-β-D-galactopyranosyl)-(1->4)-1,6-anhydro-2,3-O-endo/exo-benzylidene-β-D-mannopyranose

O-(2,3,4,6-Tetra-O-benzoyl-β-D-galactopyranosyl)-(1->4)-1,6-anhydro-2,3-O-endo/exo-benzylidene-β-D-mannopyranose

(1R,2S,6S,7R,8R)-7-((2S,3R,4S,5S,6R)-4-Allyloxy-3,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-4-phenyl-3,5,10,11-tetraoxa-tricyclo[6.2.1.02,6]undecane

(1R,2S,6S,7R,8R)-7-((2S,3R,4S,5S,6R)-4-Allyloxy-3,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-4-phenyl-3,5,10,11-tetraoxa-tricyclo[6.2.1.02,6]undecane

上游原料

O-(β-D-Galactopyranosyl)-(1->4)-1,6-anhydro-2,3-O-endo/exo-benzylidene-β-D-mannopyranose O-(2,3,4,6-Tetra-O-benzoyl-β-D-galactopyranosyl)-(1->4)-1,6-anhydro-2,3-O-endo/exo-benzylidene-β-D-mannopyranose 2,3,4,6-tetra-O-benzoyl-α,b-D-galactopyranosyl trichloroacetimidate

下游产品

O-(3-O-Allyl-2,4,6-tri-O-benzyl-β-D-galactopyranosyl)-(1->4)-1,6-anhydro-2-azido-2-deoxy-β-D-glucopyranose O-(2,3,4-Tri-O-benzyl-α-L-fucopyranosyl)-(1->3)-<O-(3-O-allyl-2,4,6-tri-O-benzyl-β-D-galactopyranosyl)-(1->4)>-1,6-anhydro-2-azido-2-deoxy-β-D-glucopyranose Trifluoro-methanesulfonic acid (1R,2S,3S,4S,5R)-2-((2S,3R,4S,5S,6R)-4-allyloxy-3,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-3-hydroxy-6,8-dioxa-bicyclo[3.2.1]oct-4-yl ester